(Z)-1,3-Dichlorpropen

Bezeichnung:(Z)-1,3-Dichlorpropen

CAS-Nr10061-01-5

Englisch Name:CIS-1,3-DICHLOROPROPENE

CBNumberCB9680157

SummenformelC3H4Cl2

Molgewicht110.97

MOL-Datei10061-01-5.mol

Synonyma

(Z)-1,3-Dichlorpropen

(Z)-1,3-Dichlorpropen physikalisch-chemischer Eigenschaften

Schmelzpunkt	-50 °C
Siedepunkt	104 °C(lit.)
Dichte	1.225 g/mL at 25 °C(lit.)
Dampfdruck	111.6 at 50 °C, 687.8 at 100 °C (Wilding et al., 2002)
Brechungsindex	n20/D 1.4675(lit.)
Flammpunkt	75 °F
storage temp.	0-6°C
Löslichkeit	Chloroform (Soluble), Methanol (Slightly)
Aggregatzustand	Oil
Farbe	Colourless
Wasserlöslichkeit	1.071g/L(30 ºC)
Merck	14,3075
Henry's Law Constant	1.23 x 10^-3 atm?m³/molat 20 °C, 2.77 at 40 °C (static headspace-GC, Kim et al., 2003)
Expositionsgrenzwerte	ACGIH TLV: TWA 1 ppm for cis and trans isomers (adopted).
Stabilität	Stable. Flammable. Incompatible with strong oxidizing agents, aluminium and its alloys, active metals, halogens, some metal salts. May be light sensitive.
LogP	1.82 at 20℃ and pH5.83-7.78
Oberflächenspannung	69.6mN/m at 976.8mg/L and 20.2℃
CAS Datenbank	10061-01-5(CAS DataBase Reference)
NIST chemische Informationen	1-Propene, 1,3-dichloro-, (Z)-(10061-01-5)
EPA chemische Informationen	cis-1,3-Dichloropropene (10061-01-5)

Sicherheit

Kennzeichnung gefährlicher	T,N,F
R-Sätze:	10-20/21-25-36/37/38-43-50/53-52/53-39/23/24/25-23/24/25-11-65-24/25-20
S-Sätze:	36/37-45-60-61-16-7
RIDADR	UN 2047 3/PG 2
WGK Germany	3
RTECS-Nr.	UC8325000
HazardClass	3.2
PackingGroup	III
Giftige Stoffe Daten	10061-01-5(Hazardous Substances Data)
Toxizität	LC50 (96-hour) for bluegill sunfish 7.1 mg/L and rainbow trout 7.1 mg/L (Worthing and Hance, 1991); acute oral LD50 of the isomeric mixture for male and female rats is 713 and 470 mg/kg, respectively (Verschueren, 1983).

Gefahreninformationscode (GHS)

CIS-1,3-DICHLOROPROPENE Chemische Eigenschaften,Einsatz,Produktion Methoden

R-Sätze Betriebsanweisung:
R10:Entzündlich.
R20/21:Gesundheitsschädlich beim Einatmen und bei Berührung mit der Haut.
R25:Giftig beim Verschlucken.
R36/37/38:Reizt die Augen, die Atmungsorgane und die Haut.
R43:Sensibilisierung durch Hautkontakt möglich.
R50/53:Sehr giftig für Wasserorganismen, kann in Gewässern längerfristig schädliche Wirkungen haben.
R52/53:Schädlich für Wasserorganismen, kann in Gewässern längerfristig schädliche Wirkungen haben.
R39/23/24/25:Giftig: ernste Gefahr irreversiblen Schadens durch Einatmen, Berührung mit der Haut und durch Verschlucken.
R23/24/25:Giftig beim Einatmen, Verschlucken und Berührung mit der Haut.
R11:Leichtentzündlich.
S-Sätze Betriebsanweisung:
S36/37:Bei der Arbeit geeignete Schutzhandschuhe und Schutzkleidung tragen.
S45:Bei Unfall oder Unwohlsein sofort Arzt zuziehen (wenn möglich, dieses Etikett vorzeigen).
S60:Dieses Produkt und sein Behälter sind als gefährlicher Abfall zu entsorgen.
S61:Freisetzung in die Umwelt vermeiden. Besondere Anweisungen einholen/Sicherheitsdatenblatt zu Rate ziehen.
S16:Von Zündquellen fernhalten - Nicht rauchen.
S7:Behälter dicht geschlossen halten.
Chemische Eigenschaften
1,3-Dichloropropene is a colorless to strawcolored liquid. Sharp, sweet, irritating, chloroform-like odor.
Chemische Eigenschaften
colourless to amber liquid
Physikalische Eigenschaften
Clear, colorless to amber-colored liquid with a pungent and irritating, chloroform-like odor. Evaporates quickly when spilled. The average least detectable odor threshold concentration in water at 60 °C for mixed isomers of 1,3-dichloropropylene was 0.12 mg/L (Alexander et al., 1982).
Verwenden
The isomeric mixture is used as a soil fumigant and a nematocide.
Definition
ChEBI: The (Z)-isomer of 1,3-dichloropropene.
Allgemeine Beschreibung
Colorless to amber liquid with a sweetish odor.
Air & Water Reaktionen
Highly flammable. Insoluble in water.
Reaktivität anzeigen
CIS-1,3-DICHLOROPROPENE may be sensitive to light. Reacts with aluminum, aluminum alloys, other active metals and some metal salts and halogens. Can react vigorously with oxidizing materials.
Brandgefahr
Flash point data for CIS-1,3-DICHLOROPROPENE are not available, however literature sources indicate that CIS-1,3-DICHLOROPROPENE is flammable.
Sicherheitsprofil
Confirmed carcinogen with experimental neoplastigenic data. Human mutation data reported. A dangerous fire hazard when exposed to heat, flame, or oxidzers. When heated to decomposition it emits toxic fumes of Cl-. See also CHLORINATED HYDROCARBONS , ALIPHATIC .
mögliche Exposition
Used as a soil fumigant prior to planting crops, such as cotton, sugar beet, potatoes; used in combinations with dichloropropanes as a soil fumigant. Workers engaged in manufacture, formulation and application of this soil fumigant and nematocide.
Environmental Fate
Biological. cis-1,3-Dichloropropylene was reported to hydrolyze to 3-chloro-2-propen- 1-ol and can be biologically oxidized to 3-chloropropenoic acid, which is further oxidized to formylacetic acid. Decarboxylation of this compound yields carbon dioxide (Connors et al., 1990). The isomeric mixture showed significant degradation with gradual adaptation in a static-culture flask-screening test (settled domestic wastewater inoculum) conducted at 25°C. At concentrations of 5 and 10 mg/L, percent losses after 4 weeks of incubation were 85 and 84, respectively. Ten days into the incubation study, 7–19% was lost due to volatilization (Tabak et al., 1981).
Soil. Hydrolyzes in wet soil forming cis-3-chloroallyl alcohol (Castro and Belser, 1966).
Chemical/Physical. Hydrolyzes in distilled water at 25°C forming 2-chloro-3-propenol and hydrochloric acid. The half-life was 1 day (Milano et al., 1988; Kollig, 1993). Chloroacetaldehyde, formyl chloride and chloroacetic acid were formed from the ozonation of dichloropropylene at about 23°C and 730 mmHg. Chloroacetaldehyde and formyl chloride also formed from the reaction of dichloropropylene with hydroxyl radicals (Tuazon et al., 1984).
The evaporation half-life of cis-1,3-dichloropropylene (1 mg/L) from water at 25°C using a shallow-pitch propeller stirrer at 200 rpm at an average depth of 6.5 cm is 29.6 minutes (Dilling, 1977).
Emits chlorinated acids when incinerated. Incomplete combustion may release toxic phosgene (Sittig, 1985).
Solubility in organics
Miscible with acetone, benzene, carbon tetrachloride, heptane, methanol (Worthing and Hance, 1991), methylene chloride, chloroform, 1,1,2,2-tetrachloroethane, 1,1,1,2-tetrachloroethane, tetrachloroethylene, and trichloroethylene.
Solubility in water
Miscible with acetone, benzene, carbon tetrachloride, heptane, methanol (Worthing and Hance, 1991), methylene chloride, chloroform, 1,1,2,2-tetrachloroethane, 1,1,1,2-tetrachloroethane, tetrachloroethylene, and trichloroethylene.
Versand/Shipping
UN2047 Dichloropropene, Hazard Class: 3; Labels: 3-Flammable liquid.
Inkompatibilitäten
Vapor may form explosive mixture with air. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, and epoxides. May accumulate static electrical charges, and may cause ignition of its vapors. Incompatible with strong acids; oxidizers, aluminum or magnesium compounds; aliphatic amines; alkanolamines, alkaline materials; halogens, or corrosives. Note: Epichlorohydrin may be added as a stabilizer.
Waste disposal
Incineration, preferably after mixing with another combustible fuel. Care must be exercised to assure complete combustion to prevent the formation of phosgene. An acid scrubber is necessary to remove the halo acids produced. In accordance with 40CFR165, follow recommendations for the disposal of pesticides and pesticide containers. Must be disposed properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office. Consult with environmental regulatory agencies for guidance on acceptable disposal practices. Generators of waste containing this contaminant (≧100 kg/mo) must conform with EPA regulations governing storage, transportation, treatment, and waste disposal.

CIS-1,3-DICHLOROPROPENE Upstream-Materialien And Downstream Produkte

(Z)-1,3-Dichlorpropen Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

10061-01-5, CIS-1,3-DICHLOROPROPENE Verwandte Suche:

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