Карбоксин
- английское имяCarboxin
- CAS №5234-68-4
- CBNumberCB9267538
- ФормулаC12H13NO2S
- мольный вес235.3
- EINECS226-031-1
- номер MDLMFCD00055403
- файл Mol5234-68-4.mol
химическое свойство
| Температура плавления | 91.1-91.7°C |
| Температура кипения | 420.6±45.0 °C(Predicted) |
| плотность | 1.45 |
| давление пара | 2.5 x 10-5 Pa (25 °C) |
| показатель преломления | 1.6000 (estimate) |
| Fp | 100 °C |
| температура хранения | Sealed in dry,2-8°C |
| растворимость | Chloroform (Slightly), Methanol (Slightly) |
| пка | 14.31±0.70(Predicted) |
| форма | Crystals |
| цвет | White |
| Растворимость в воде | 10.095 g/100 mL |
| Мерк | 13,1837 |
| БРН | 983249 |
| LogP | 2.140 |
| Рейтинг продуктов питания EWG | 1 |
| FDA UNII | 5A8K850HDE |
| Справочник по химии NIST | Carboxin(5234-68-4) |
| Система регистрации веществ EPA | Carboxin (5234-68-4) |
| UNSPSC Code | 41116107 |
| NACRES | NA.24 |
больше
| Коды опасности | Xi,Xn | |||||||||
| Заявления о рисках | 21/22-36/37/38-20/21/22 | |||||||||
| Заявления о безопасности | 36-26 | |||||||||
| РИДАДР | UN2588 (Pesticide, solid, poisonous, n.o.s.); UN2902 (Pesticide, liquid, poisonous, n.o.s.) | |||||||||
| WGK Германия | 3 | |||||||||
| RTECS | RP4550000 | |||||||||
| кода HS | 29349990 | |||||||||
| Банк данных об опасных веществах | 5234-68-4(Hazardous Substances Data) | |||||||||
| Токсичность | LD50 in rats, mice (mg/kg): 430, 3200 orally (Dyadicheva) | |||||||||
| NFPA 704: |
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рисовальное письмо(GHS)
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рисовальное письмо(GHS)
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сигнальный язык
предупреждение
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вредная бумага
H302：Вредно при проглатывании.
H317：При контакте с кожей может вызывать аллергическую реакцию.
H410：Чрезвычайно токсично для водных организмов с долгосрочными последствиями.
H373：Может поражать органы (Нервная система) в результате многократного или продолжительного воздействия при вдыхании.
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оператор предупредительных мер
P260：Не вдыхать газ/ пары/ пыль/ аэрозоли/ дым/ туман.
P273：Избегать попадания в окружающую среду.
P280：Использовать перчатки/ средства защиты глаз/ лица.
P301+P312：ПРИ ПРОГЛАТЫВАНИИ: Обратиться за медицинской помощью при плохом самочувствии.
P302+P352：ПРИ ПОПАДАНИИ НА КОЖУ: Промыть большим количеством воды.
P314：В случае плохого самочувствия обратиться к врачу.
Карбоксин химические свойства, назначение, производство
Химические свойства
Carboxin is a white crystalline solidИспользование
Carboxine is an fungicide used for the control of fruit rot of custard apple.Определение
ChEBI: An anilide obtained by formal condensation of the amino group of aniline with the carboxy group of 2-methyl-5,6-dihydro-1,4-oxathiine-3-carboxylic acid. A fungicide for control of bunts and smuts normally that is normally used as a seed treatment.Общее описание
Off-white crystals. Systemic fungicide and seed protectant.Сельскохозяйственное использование
Fungicide: Carboxin is a General Use Pesticide (GUP) and is used as a seed protectant. It is often used in combination with other fungicides such as thiram or captan. Carboxin is a systemic anilide fungicide. It is used as a seed treatment for control of smut, rot, and blight on barley, oats, rice, cotton, vegetables, corn and wheat. It is also used to control fairy rings on turf grass. Carboxin may be used to prevent the formation of these diseases or may be used to cure existing plant diseases. Also used as a wood preservative.Торговое название
CADAN®; CARBOXIN OXATHION PESTICIDE®; CASWELL No. 165 A®; D-735®; F-735®; FLO PRO V SEED PROTECTANT®[C]; KEMIKAR®; OXALIN®; PADAN®; SANVEX®; THIOBEL®; VEGETOX®; VITAFLO®; VITAVAX® 200FF; V 4X®Профиль безопасности
Poison by ingestion. Moderately toxic by skin contact and possibly other routes. Mutation data reported. When heated to decomposition it emits very toxic fumes of NOx and SOx.Возможный контакт
A potential danger to those involved in the production, Formulation and application of this systemic fungicide, seed protectant and wood preservativeЭкологическая судьба
Biological. The sulfoxidation of carboxin to carboxin sulfoxide by the fungus Ustilago maydis was reported by Bollag and Liu (1990).Soil. Carboxin oxidized in soil forming carboxin sulfoxide. The half-life in soil was reported to be 24 hours (Worthing and Hance, 1991).
Plant. In plants (barley, cotton and wheat) and water, carboxin oxidizes to the corresponding sulfoxide (Worthing and Hance, 1991).
Метаболический путь
Carboxin is a systemic fungicide which is very stable to hydrolysis but is readily oxidised at sulfur to a sulfoxide and a sulfone. The latter, oxycarboxin, is itself a commercial fungicide. Metabolism is mainly by oxidation at sulfur in soil, plants and animals but hydroxylation of the phenyl ring is also important in animals. Hydrolysis has been convincingly demonstrated only in plants (peanut).Перевозки
UN2588 Pesticides, solid, toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required.Несовместимости
Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides. Avoid heat and humidity. Thermal decomposition products may include cyanide gas and cyanide salts.Утилизация отходов
Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. All federal, state, and local environmental regulations must be observed.Карбоксин запасные части и сырье
Карбоксин поставщик
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