aladdin 阿拉丁 C284031 1,3-双(2,6-二异丙基苯基)咪唑-2-亚甲基氯化金(I) 852445-83-1 99.95% metals basis

中文名：1,3-双(2,6-二异丙基苯基)咪唑-2-亚甲基氯化金(I)

英文名：Chloro[1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene]gold(I)

纯度：≥99.95% metals basis

货号：C284031

Cas号：852445-83-1

存储温度：2-8°C储存

运输条件：低温运输

产品介绍：

Product class

M-C, Homogeneous Catalysts, N-Heterocyclic Carbene Ligands

Reaction type

CH-Activation, Carboxylation, Cyclization, Cyclopropanation, Hydration, Hydroamination, Isomerization

Chemical properties

Applications & references

Rearrangement of allylic acetates.

Reference: Org. Lett. 2007, 9, 2653 (DOI: 10.1021/ol070843w); Organomet. 2011, 30, 5463 (DOI: 10.1021/om200705y)

Olefin cyclopropanation.

Reference: Tetrah. 2009, 65, 1790 (DOI: 10.1016/j.tet.2008.10.114)

Alkane C-H-bond functionalization.

Reference: Organomet. 2006, 25, 2237 (DOI: 10.1021/om0507474)

Carboxylation of C-H bonds.

Reference: J. Am. Chem. Soc. 2010, 132, 8858 (DOI: 10.1021/ja103429q)

Hydration of alkynes.

Reference: J. Am. Chem. Soc. 2009, 131, 448 (DOI: 10.1021/ja809403e)

Hydroarylation-aromatization of arenes-diynes.

Reference: Organomet. 2012, 31, 644 (DOI: 10.1021/om200946m)

Cyclization of aryl-substituted propargylamides.

Reference: Eur. J. Org. Chem. 2011, 4595 (DOI: 10.1002/ejoc.201100342)

Cycloisomerization of enyl etsters and allenyl esters.

Reference: Chem. Eur. J. 2009, 15, 3243 (DOI: 10.1002/chem.200801387)

Tandem hydroamination-hydroarylation reaction.

Reference: Org. Lett. 2007, 9, 2645 (DOI: 10.1021/ol070814l)

Tandem 1,2-indole migration and aura-Nazarov cyclization reaction of 3-propargylindoles.

Reference: Beilstein J. Org. Chem. 2011, 7, 786 (DOI:10.3762/bjoc.7.89)

Cascade insertion and cyclization of water with substituted phenyldiazoacetates.

Reference: Beilstein J. Org. Chem. 2011, 7, 631 (DOI:10.3762/bjoc.7.74)

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