aladdin 阿拉丁 F339065 5-氟-1,3-二甲基尿嘧啶 3013-92-1 98%

中文名：5-氟-1,3-二甲基尿嘧啶

英文名：5-Fluoro-1,3-dimethyluracil

纯度：≥98%

货号：F339065

Cas号：3013-92-1

运输条件：常规运输

产品介绍：

Oxidation of 5-fluoro-1,3-dimethyluracil (5-FDMU) with m-chloroperbenzoic acid has been described. It is reported as antineoplastic drug. On photoirradiation, 5-fluoro-1,3-dimethyluracil yields the trans-anti cyclobutane dimer and the cis-syn cyclobutane dimer. UV irradiation of 5-FDMU and naphthalene in a protic medium affords 5-(1-naphthyl)uracil, while in aprotic media it undergoes stereoselective 1,4-cycloaddition reaction to give a barrelene derivative. The thermochemical parameters of 5-FDMU has been determined. It reacts with substituted benzenes in the presence of trifluoroacetic acid to generate 5-aryl-1,3-dimethyluracils via photosubstitution.

Application：

Regioselective synthesis of tetrahydronaphthocyclobuta[1,2-d]pyrimidinediones；To synthesize 5-bis(ethoxycarbonyl)methyl-1,3-dimethyluracil；To synthesize new highly conjugated propenylidene derivatives via aromatic Paterno-Buchi type cycloaddition with 1-methoxynaphthalene

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