aladdin 阿拉丁 A284063 烯丙基氯[1,3-双(2,6-二异丙基苯基)-4,5-二氢咪唑-2-亚甲基]钯(II) 478980-01-7 99.95% metals basis

中文名：烯丙基氯[1,3-双(2,6-二异丙基苯基)-4,5-二氢咪唑-2-亚甲基]钯(II)

英文名：Allyl[1,3-bis(2,6-diisopropylphenyl)-2-imidazolidinylidene]chloropalladium(II)

纯度：≥99.95% metals basis

货号：A284063

Cas号：478980-01-7

存储温度：2-8°C储存,充氩

运输条件：低温运输

产品介绍：

Product class
M-P, Homogeneous Catalysts, N-Heterocyclic Carbene Ligands, M-C, Allyl Ligands, SIPr, Bidentate Ligands

Reaction type
Cross Coupling Reactions with Arenes, Amination, Buchwald-Hartwig Aminaton, Alpha Arylation, Suzuki-Miyaura Coupling Reaction

Chemical properties

Applications & references

α-Arylation of ketones.

Reference: Org. Lett. 2002, 4, 4053 (DOI: 10.1021/ol026745m); Adv. Synth. Catal. 2012, 354, 377 (DOI: 10.1002/adsc.201100669)

Intramolecular arylamination step in the synthetic approach of cryptocarya alkaloids.

Reference: Synlett 2003, 12, 1871 (DOI: 10.1021/jo035834p)

Suzuki-Miyaura coupling reaction.

Reference: J. Org. Chem. 2004, 69, 3173

Buchwald-Hartwig coupling reactions.

Reference: J. Am. Chem. Soc. 2006, 128, 4101 (DOI: 10.1021/ja057704z)

α-Heteroarylation of ketone enolates.

Reference: J. Org. Chem. 2010, 75, 5316 (DOI: 10.1021/jo100623d)

Palladium catalyzed anaerobic oxidation of secondary alcohols under mild reaction conditions.

Reference: J. Org. Chem. 2011, 76, 1390. (DOI: 10.1021/jo102385u)

Palladium catalyzed Buchwald-Hartwig- Reaction at room temperature.

Reference: J. Am. Chem. Soc. 2006, 128, 4101. (DOI: 10.10217ja057704z)

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