aladdin 阿拉丁 S294487 [(S)-(-)-2,2'-双(二苯基膦)-1,1'-联萘基](对伞花烃)氯化钌(II)氯化物 130004-33-0 99.95% metals basis

中文名：[(S)-(-)-2,2'-双(二苯基膦)-1,1'-联萘基](对伞花烃)氯化钌(II)氯化物

英文名：(S)-RuCl[(p-cymene(BINAP)]Cl

纯度：≥98%

货号：S138141

Cas号：130004-33-0

存储温度：2-8°C储存,充氩

运输条件：低温运输

产品介绍：

Product class
M-P, Homogeneous Catalysts, M-C, Arene/Aryl Ligands, Phosphorus Ligands - Chiral

Reaction type
Hydrogenation, Asymmetric Reactions, Asymmetric Hydrogenation, Transfer Hydrogenation

Chemical properties

Applications & references

Synthesis of (R)- or (S)-4-halo-3-hydroxybuyrate ester by asymmetric hydrogenation of 4-halo-3-oxobutanoate ester; this reaction can be applied in the Producteion of L-carnitine.

Reference: EP2386536

Enantioselective hydrogenation of functionalized ketones.

Reference: EP0366390

Asymmetric hydrogenation of halogenated acetophenones to enantiomerically pure halogenated phenyl ethanol derivatives.

Reference: Cat. Lett. 1996, 41, 111 (DOI: 10.1007/BF00811721)

Highly enantioselective catalytic hydrogenation of methyl-N-tertbutyl-3-oxoglutarate as a key step in the total synthesis of rovastatin.

Reference: Tetrah. Lett. 2008, 49, 4836 (DOI: 10.1016/j.tetlet.2008.06.018)

Enantioselective hydrogenation of 4-(hydroxymethyl)furan-2(5H)-one derivatives.

Reference: J. Mol. Cat. A: Chem. 2006, 259, 103 (DOI: 10.1016/j.molcata.2006.05.066)

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