(<I> S,S </I>)-(+)-<I> N,N′</I>-双（3,5-二-<I> 叔 </I>-丁基水杨醛）-1,2-环己烷二氨基锰 (III) 氯化物,135620-04-1

一般描述

(S,S)-(+)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride is a metal-salen complex that can catalyze a variety of asymmetric transformations.

应用

Reactant involved in:
Studies of intercalative binding with ct-DNA and radical scavenging antioxidant activityImmobilization on phenoxy-modified zirconium poly(styrenephenylvinylphosphonate) Synthesis of derivatvies for studies of conformational models of enantioselective reactions
Catalyst involved in:
Asymmetric epoxidation of olefinsImmobilization on ionic liquid modified mesoporous silica for oxidative kinetic resolution of racemic secondary alcohols?Immobilization on diamine modified zirconium olig-styrenyl phosphonate hydrogen phosphate for epoxidation of styrene 非官能化烯烃类的 Salen (Mn)-催化不对称环氧化反应。获得各种底物（特别是顺式-烯烃）的高对映立体选择性和产量。一些用途包括合成紫杉醇侧链和顺式-1-氨基-2-茚醇。Jacobsen 催化剂还用于硅烯醇醚的不对称 α-羟基化。用于各种烯烃不对称环氧化反应的催化剂。