ANKOR 1126
Hard chromium electrolyte
-------------------ANKOR 1126 硬铬电解液
CHARACTERISTICS【简介】
Hard chromium electrolyte with high cathodic current efficiency and good throwing power for the deposition of micro-cracked deposits with a hardness of approximately 1050 HV 0,1. ANKOR 1126 combines the good properties of conventional sulphuric acid electrolytes, i.e. only slight attack of iron and iron alloys and cathodic current efficiencies which are usually only achieved with catalysts on the basis of complexed fluorides. ANKOR 1126 is free of fluorides.硬质铬电解液具有较高的阴极电流效率和良好的抛掷能力,可沉积硬度约为1050 HV 0,1的微裂纹沉积。ANKOR 1126结合了传统硫酸电解质的良好性能,即只有轻微的铁和铁合金的攻击和阴极电流效率,这通常只有催化剂在配合氟化物的基础上实现。ANKOR 1126不含氟化物。
MAKE-UP【组成】
Make up quantities(100 l) 30.00kg Make-up salt ANKOR 1126
5.00 l Make-up solution ANKOR 1126
EQUPMENT【设备】
See Instruction Sheet MB0020"Technical equipment for Chromium electrolytes".
参见说明书MB0020“铬电解质技术设备”
OPERATING CONDITIONS【操作参数】
Density (20℃) 密度(20℃)
1.215g/cm3
25,5°Be
Temperature 温度
55-60℃
Current density 电流密度
20-60 A/dm2
Anodic current density 阳极电流密度
15-25 A/dm2
Anode material 阳极材料
The service life of the lead alloy anodes is shorter compared to the service life in chrome plating solutions based on sulphuric acid or mixed and is dependent upon the individual operating conditions. New anodes have to be worked in as described in the Instruction Sheet MB0021 Furthermore platinized titanium anodes are recommended . Care has to be taken that they are completely covered with a lead dioxide film(brown-black layer). Only under this condition is Cr 3+oxidised to Cr6+.The lead dioxide film is obtained using one or more PbSn anodes together with the platinized titanium anodes or by addition of ANKOR Addition Solution PTA (see Technical Data Sheet).与基于硫酸或混合镀铬溶液的使用寿命相比,铅合金阳极的使用寿命较短,并取决于个人的操作条件。新的阳极必须按照说明书MB0021中的描述进行加工。此外,建议使用镀铂钛阳极。必须当心,它们完全覆盖了一层二氧化铅薄膜(棕黑色层)。只有在此条件下,Cr3+才被氧化为Cr6+。使用一个或多个PbSn阳极和镀铂钛阳极或通过添加ANKOR添加溶液PTA(见技术数据表)获得二氧化铅薄膜。
Voltage 电压
The required rectifier voltage depends on various factors, e.g. current density, concentration, temperature, type of electrode and electrode spacing. Average value: 6 - 12V.所需的整流电压取决于各种因素,如电流密度、浓度、温度、电极类型和电极间距。平均值:6 - 12V。
Rectifiers整流器
Usually 12 volt units; for high outputs 15 volt units. 通常是12伏单位;高输出15伏单位。
Rectifiers have to be adjusted until the residual ripple is less than 5 % within the total current range. 整流器必须调整,直到剩余纹波在总电流范围内小于5%。
Deposition rate 沉积率
At 50 A/dm2 approx.1,0 um/min chrome is deposited.
MAINTENANCE【维护】
Nominal values Minimum and maximum values
Chromic acid 铬酸 280g/l - 320g/l
Sulphuric acid 硫酸 1.1 % - 1.4 %
(related to the chromic acid content)与铬酸含量有关
Reinforcement【补充】
For regeneration the electrolyte is maintained with Reinforcement Salt ANKOR 1126/2 and
Addition Solution ANKOR 1126/3 being added to the electrolyte ANKOR 1126 in the ratio 10 kg : 1 l.
为了使电解质再生,将强化盐ANKOR 1126/2和 添加液ANKOR 1126/3按10 kg: 1 l的比例添加到电解质ANKOR 1126中。
To increase the density by 1° Be, add approx. 要增加1°Be的密度,添加约。
1.5 kg/100l Reinforcement Salt ANKOR 1126/2 as well as 0.15 l/100 I Addition Solution ANKOR 1126/3. 1.5 kg/100l强化盐ANKOR 1126/2以及0.15 l/ 100i添加液ANKOR 1126/3。
EFFECT OF THE ADDITION SOLUTION ANKOR 1126/3添加溶液ANKOR 1126/3的效果
Too low concentrations result in milky, dull deposition. Excessive concentrations reduce the maximum applicable current density and result in dull and nodular deposition in the highest current density range. 浓度过低会导致乳白色、暗淡的沉积。过量的浓度降低了适用电流密度,并导致在最高电流密度范围内的钝状和结节状沉积。
An excess of Addition Solution ANKOR 1126/3 can only be "removed" by diluting the electrolyte.
We recommend to add the solution always according to the standard value of 10 kg : 1 l. However the ratio of addition can be influenced by drag-out and recycling. After adding approximately 15 kg/100 IReinforcement Salt ANKOR 1126/2, we recommend to send us an electrolyte sample of 1 litre for analysis and adjustment.过量的添加溶液ANKOR 1126/3只能通过稀释电解质来“去除”。我们建议始终按照10kg: 1l的标准值添加溶液,但添加比例会受到拖出和回收的影响。在加入大约15公斤/100IReinforcement Salt ANKOR 1126/2后,我们建议寄给我们1升的电解质样品进行分析和调整。
FOR MAKE UP AND MAINTENANCE THE FOLLOWING CHEMICAL ARE REQUIRED对于维护和保养需要以下化学品
Designation: 名称: Article Number:商品编码:
MAKE-UP SALT ANKOR 1126 1316110
MAKE-UP SOLUTION ANKOR1126 1316120
REINFORCEMENT SALT ANKOR 1126/2 1316150
ADDITION SOLUTION ANKOR 1126/3 1316160
ANKOR ADDITION SOLUTION PTA 1316310*
BARIUM CARBONATE 4018Y*
Caution: 注意事项
Addition of chemicals other than indicated in our Technical Data Sheet may have a negative influence on the electrolyte and the quality of the deposits. 添加除我们技术数据表中所示以外的化学物质可能会对电解液和镀层质量产生负面影响。
EFFLUENT TREATMENT 【废水处理】
The electrolyte contains hexavalent chromium compounds and therefore heavy metals, such as iron and copper as impurities. 电解液含有六价铬化合物,因此重金属,如铁和铜作为杂质。
Rinse waters and exhausted concentrates have to be disposed of in compliance with the legal regulations. 漂洗水和耗尽的浓缩物必须按照法律规定处理。
HANDLING AND SAFETY INSTRUCTIONS【操作安和全说明】
For detailed information consult the material safety data sheets for this product. 有关详细信息,请参阅本产品的材料安全数据表.
Please read material safety data sheets carefully before using this product.使用本产品前,请仔细阅读材料安全数据表。
DISCLAIMER【特别声明】
All recommendations and suggestions in this bulletin concerning the use of our products are based upon tests and data believed to be reliable. Since the actual use by others is beyond our control, no guarantee expressed or implied, is made by our company , as to the effects of such use or results to be obtained, nor is any information to be construed as a recommendation to infringe any patent.
此说明书内所有提议或建议,是以本公司信赖的实验及资料为基础。因不能控制其他从业者的实际操作,故本公司不能保证及负责任何不良后果。此说明书内的所有资料也不能用为侵犯版权的证据。