硼化钐

Samarium Boride, also called Samarium Hexaboride, is one of the rare earth borides, the molecular formula is SmB₆. SmB₆ is an intermediate-valence compound where samarium is present both as Sm2+ and Sm3+ ions at the ratio 3:7. It belongs to a class of Kondo insulators. At temperatures above 50 K its properties are typical of a Kondo metal, with metallic electrical conductivity characterized by strong electron scattering, whereas at low temperatures, it behaves as a non-magnetic insulator with a narrow band gap of about 4–14 meV. The cooling-induced metal-insulator transition in SmB₆ is accompanied by a sharp increase in thermal conductivity, peaking at about 15 K. The reason for this increase is that electrons do not contribute to thermal conductivity at low temperatures, which is instead dominated by phonons. The decrease in electron concentration reduced the rate of electron-phonon scattering.
Samarium Boride, also called Samarium Hexaboride, is one of the rare earth borides, the molecular formula is SmB₆.