降冰片

Mass

MS-NW-8749          
exo-norboneol
C7H12O              (Mass of molecular ion:    112)

   Source Temperature: 270 °C
   Sample Temperature: 140 °C
   Reservoir, 75 eV

      15.0       1.4
      18.0       1.8
      26.0       1.3
      27.0      16.5
      28.0       3.8
      29.0      14.8
      31.0       5.1
      38.0       1.8
      39.0      25.5
      40.0       7.5
      41.0      36.1
      42.0       8.5
      43.0      14.7
      44.0       6.4
      45.0       7.6
      50.0       1.6
      51.0       3.7
      52.0       1.6
      53.0      16.2
      54.0       6.6
      55.0      27.6
      56.0      13.4
      57.0      34.7
      58.0       9.1
      63.0       1.1
      65.0       6.8
      66.0      68.5
      67.0      95.4
      68.0      78.1
      69.0      10.9
      70.0      16.9
      71.0       8.3
      77.0       6.7
      78.0       2.4
      79.0     100.0
      80.0       7.9
      81.0      16.4
      82.0       2.2
      83.0      24.5
      84.0       7.3
      91.0       2.7
      93.0       7.2
      94.0      93.5
      95.0      10.9
      97.0       7.1
     111.0       1.4
     112.0       1.3

Assign. Shift(ppm) A 3.741 B 2.242 C 2.17 D 2.135 E 1.641 F 1.572 G 1.46 J 1.40 K 1.289 L 1.109 M *1 1.03 N *1 0.99 ASSIGNED BY C-H AND H-H COSY. J(A,E)=6.8HZ J(E,B)=2.4HZ J(E,K)=-13.1HZ J(F,L)=-9.8HZ

     Hz     ppm     Int.

   1498.54   3.750    451
   1491.70   3.733    446
    899.66   2.252    361
    896.24   2.243    569
    895.75   2.242    572
    880.37   2.203     65
    879.88   2.202     66
    878.42   2.198     64
    868.04   2.173   1000
    860.47   2.154    103
    855.10   2.140    572
    851.20   2.130    528
    667.72   1.671    272
    665.41   1.665    293
    660.89   1.654    277
    658.57   1.648    298
    654.66   1.639    327
    652.34   1.633    347
    647.83   1.621    324
    645.51   1.616    338
    637.33   1.595    149
    635.50   1.591    331
    633.67   1.586    461
    631.96   1.582    364
    627.69   1.571    167
    625.61   1.566    354
    623.90   1.562    495
    622.07   1.557    387
    608.15   1.522     58
    603.15   1.510     66
    599.73   1.501    134
    594.97   1.489    151
    593.26   1.485    145
    591.55   1.481    176
    589.23   1.475    232
    587.77   1.471    291
    584.47   1.463    227
    583.13   1.460    274
    579.22   1.450    394
    574.58   1.438    374
    572.27   1.432    186
    570.80   1.429    261
    569.82   1.426    226
    567.87   1.421    333
    566.89   1.419    271
    565.80   1.416    223
    563.72   1.411    304
    560.79   1.404    279
    559.69   1.401    252
    556.88   1.394    286
    554.44   1.388    195
    551.64   1.381    156
    550.54   1.378    126
    548.71   1.373    139
    547.61   1.371    122
    544.68   1.363    110
    542.72   1.358     66
    539.67   1.351     66
    538.57   1.348     66
    535.52   1.340     68
    525.51   1.315    188
    523.07   1.309    297
    521.36   1.305    319
    519.17   1.300    299
    516.97   1.294    195
    515.99   1.292    177
    512.45   1.283    162
    510.01   1.277    246
    508.30   1.272    260
    506.23   1.267    242
    503.78   1.261    149
    502.93   1.259    130
    451.29   1.130    190
    449.95   1.126    394
    448.49   1.123    494
    447.51   1.120    515
    446.04   1.117    433
    444.70   1.113    237
    441.53   1.105    180
    440.19   1.102    354
    438.72   1.098    446
    437.62   1.096    461
    436.28   1.092    388
    434.94   1.089    204
    418.46   1.048    164
    416.50   1.043    228
    414.79   1.038    170
    410.64   1.028    346
    408.81   1.023    633
    407.47   1.020    740
    406.86   1.019    746
    405.52   1.015    698
    402.83   1.008    403
    400.39   1.002    643
    398.07   0.997    637
    395.63   0.990    294
    389.65   0.975    121
    387.70   0.971     95