图谱信息 供应商 相关产品
网站主页CAS数据库列表 1133-80-8更多图谱2-溴芴(1133-80-8)Raman光谱

2-溴芴

产品名称 2-溴芴

CAS号1133-80-8

分子式C13H9Br

分子量245.11

展开


  • Mass

    MS-NW-6232          
    2-bromofluorene
    C13H9Br             (Mass of molecular ion:    244)
    

       Source Temperature: 240 °C
       Sample Temperature: 190 °C
       Reservoir, 75 eV
    

          18.0       1.1
          39.0       1.2
          50.0       1.2
          62.0       1.7
          63.0       2.9
          69.0       1.2
          69.5       4.4
          74.0       1.8
          75.0       1.3
          81.0       3.2
          81.5       8.1
          82.0       7.2
          82.5      18.6
          83.0       2.9
          86.0       1.5
          87.0       2.0
          89.0       1.2
         115.0       2.0
         122.0       1.5
         123.0       1.6
         137.0       1.1
         138.0       1.2
         139.0       2.8
         162.0       1.9
         163.0      14.0
         164.0      11.1
         165.0     100.0
         166.0      17.2
         167.0       1.5
         243.0       1.4
         244.0      32.7
         245.0       6.1
         246.0      31.3
         247.0       5.0
    

parameter in CDCl3

400 MHz in CDCl3

parameter in DMSO-d6


  • 1H NMR 300 MHz
    C13 H9 Br in CDCl3
    2-bromofluorene
    ChemicalStructure
        Parameter     ppm  Hz
    D(A) 7.520 D(B) 7.380 D(C) 7.460 J(A,B) 1.75 J(A,C) 0.50 J(B,C) 8.35 D(D) 7.600 D(E) 7.260 D(F) 7.235 D(G) 7.405 J(D,E) 7.35 J(D,F) 1.26 J(D,G) 0.70 J(E,F) 7.45 J(E,G) 1.20 J(F,G) 7.60 D(H) 3.755 MATHIEU,A. ET AL. BULL.SOC.CHIM.FR. 1974, 299

         Hz     ppm     Int.
    

       2284.78   7.616     73
       2284.12   7.614     75
       2282.19   7.607    104
       2278.96   7.597     65
       2277.28   7.591     79
       2276.19   7.587     91
       2275.54   7.585     88
       2256.69   7.522    185
       2255.42   7.518    190
       2255.02   7.517    188
       2243.09   7.477    115
       2242.72   7.476    115
       2234.76   7.449    230
       2226.50   7.422     70
       2225.88   7.420     72
       2224.72   7.416     68
       2223.01   7.410     61
       2219.73   7.399    128
       2218.32   7.394    220
       2216.68   7.389    211
       2212.31   7.374     15
       2209.95   7.366     93
       2208.28   7.361     87
       2187.43   7.291     21
       2185.58   7.285     40
       2180.01   7.267    129
       2178.16   7.261    113
       2176.81   7.256    137
       2174.12   7.247    251
       2171.32   7.238    106
       2169.86   7.233    102
       2168.08   7.227     99
       2162.40   7.208     29
       2160.66   7.202     18
       1126.50   3.755   1000
    


  • 1H NMR 399.65 MHz
    C13 H9 Br 0.039 g : 0.5 ml CDCl3
    2-bromofluorene
    ChemicalStructure
        Assign.     Shift(ppm)
    A 7.710 B 7.630 C 7.582 D 7.496 E 7.463 F 7.351 G 7.303 J 3.823 ASSIGNED BY C-H COSY

         Hz     ppm     Int.
    

       3084.96   7.720    263
       3078.00   7.702    302
       3050.17   7.633    426
       3049.07   7.630    420
       3048.46   7.628    373
       3035.16   7.595    403
       3026.98   7.575    557
       3001.10   7.510    194
       3000.00   7.507    244
       2999.02   7.505    195
       2992.55   7.488    288
       2991.70   7.486    228
       2987.06   7.475    321
       2986.21   7.473    253
       2985.23   7.470    307
       2978.88   7.454    230
       2978.15   7.452    182
       2977.05   7.450    223
       2947.14   7.375    105
       2946.53   7.373    107
       2945.92   7.372    113
       2939.70   7.356    275
       2939.21   7.355    270
       2938.48   7.353    267
       2932.37   7.338    207
       2931.76   7.336    193
       2931.03   7.334    179
       2925.42   7.320    297
       2924.07   7.317    329
       2918.09   7.302    391
       2916.75   7.299    365
       2910.64   7.283    147
       2909.42   7.280    133
       1528.08   3.824   1000
    


  • 1H NMR 300 MHz
    C13 H9 Br in DMSO-d6
    2-bromofluorene
    ChemicalStructure
        Parameter     ppm  Hz
    D(A) 7.730 D(B) 7.540 D(C) 7.800 J(A,B) 1.70 J(A,C) 0.50 J(B,C) 8.00 D(D) 7.865 D(E) 7.385 D(F) 7.345 D(G) 7.560 J(D,E) 7.50 J(D,F) 1.10 J(D,G) 0.70 J(E,F) 7.65 J(E,G) 1.15 J(F,G) 7.50 D(H) 3.890 MATHIEU,A. ET AL. BULL.SOC.CHIM.FR. 1974, 299

         Hz     ppm     Int.
    

       2363.63   7.879     96
       2362.28   7.874    125
       2357.50   7.858     82
       2356.30   7.854    107
       2355.70   7.852    115
       2344.19   7.814    183
       2336.18   7.787    224
       2319.79   7.733    213
       2318.29   7.728    231
       2272.23   7.574     94
       2271.44   7.571     90
       2270.24   7.567     76
       2266.59   7.555    192
       2265.01   7.550    225
       2258.62   7.529    128
       2256.97   7.523    122
       2224.67   7.416     36
       2223.17   7.411     47
       2217.04   7.390    123
       2215.57   7.385    117
       2210.31   7.368    236
       2208.39   7.361    222
       2203.09   7.344    109
       2201.77   7.339    107
       2195.53   7.318     38
       2194.14   7.314     31
       1167.01   3.890   1000
    

in CDCl3



KBr disc



nujol mull