Supplier Product Identification Physical and Chemical Properties First Aid Measures Handling and Storage Hazards Identification Exposure Controls/Personal Protection Fire Fighting Measures Accidental Release Measures Stability and Reactivity Transport Information
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Benzylaniline(103-32-2)

Supplier Product Identification Physical and Chemical Properties First Aid Measures Handling and Storage Hazards Identification Exposure Controls/Personal Protection Fire Fighting Measures Accidental Release Measures Stability and Reactivity Transport Information

Product Identification

Product Name
Benzylaniline
Synonyms
N-(Phenylmethyl)aniline
N-Benzyl-N-phenylamine
N-Benzylphenylamine
N-Phenylbenzenemethanamine
N-Phenylbenzylamine
CAS
103-32-2
Formula
C13H13N
Molecular Weight
183.26
EINECS
203-100-4
Merck
12,1161
Beilstein/Gmelin
1867229
Beilstein Reference
4-12-00-02172

Physical and Chemical Properties

Appearance
Colorless to pale yellow crystalline powder.
Solubility in water
Insoluble
Melting Point
33 - 36
Boiling Point
306 - 307
Vapor Pressure
0.0007 (25 C)
Density
1.06 g/cm3
pKa/pKb
10.11 (pKb)
Partition Coefficient
3.13
Heat Of Vaporization
54.8 kJ/mol
Heat Of Combustion
-7075 kJ/mol
Refractive Index
1.615 (20 C)

First Aid Measures

Ingestion
Get medical aid. Wash mouth out with water.
Inhalation
Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Skin
Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.
Eyes
Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.

Handling and Storage

Storage
Store in a cool, dry place. Store in a tightly closed container.
Handling
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.

Hazards Identification

Ingestion
The toxicological properties of this substance have not been fully investigated.
Inhalation
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
Skin
May cause skin irritation.
Eyes
May cause eye irritation. Contact may cause transient irritation.
UN (DOT)
3143

Exposure Controls/Personal Protection

Personal Protection
Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators
Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.

Fire Fighting Measures

Flash Point
118
Fire Fighting
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. To extinguish fire use water spray, dry chemical, carbon dioxide, or chemical foam.

Accidental Release Measures

Small spills/leaks
Vacuum or sweep up material and place into a suitable disposal container.

Stability and Reactivity

Disposal Code
3
Stability
Stable under normal temperatures and pressures.
Incompatibilities
Strong oxidizing agents, acids, acid chlorides, acid anhydrides.
Decomposition
Nitrogen oxides, carbon monoxide, carbon dioxide.

Transport Information

UN Number
3143
HS Code
2921 49 80
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