Supplier Product Identification Physical and Chemical Properties First Aid Measures Handling and Storage Hazards Identification Exposure Controls/Personal Protection Fire Fighting Measures Accidental Release Measures Stability and Reactivity Transport Information
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1,4,7,10,13-Pentaazatridecane(112-57-2)

Supplier Product Identification Physical and Chemical Properties First Aid Measures Handling and Storage Hazards Identification Exposure Controls/Personal Protection Fire Fighting Measures Accidental Release Measures Stability and Reactivity Transport Information

Product Identification

Product Name
1,4,7,10,13-Pentaazatridecane
Synonyms
1,4,7,10,13-Pentaazatridecane
3,6,9-Triazaundecamethylenediamine
N'-(2-Aminoethyl)-N-[2-(2-aminoethylamino)ethyl]ethane-1,2-diamine
Tetren
CAS
112-57-2
Formula
C8H23N5
Molecular Weight
189.3
EINECS
203-986-2
RTECS
KH8585000
RTECS Class
Mutagen; Primary Irritant
Beilstein/Gmelin
506966
Beilstein Reference
4-04-00-01244
EC Index Number
612-060-00-0
EC Class
Harmful; Corrosive; Sensitising; Dangerous for the Environment

Physical and Chemical Properties

Appearance
A viscous, yellow liquid with a penetrating, ammonia-like odor.
Solubility in water
Soluble
Melting Point
-40
Boiling Point
340
Vapor Pressure
8E-7 (25 C)
Density
0.9994 g/cm3 (20 C)
pKa/pKb
4.32 (pKb)
Partition Coefficient
1.503
Heat Of Vaporization
63.3 kJ/mol
Usage
Solvent for sulfur, acid gases, various resins & dyes, saponifying agent for acidic materials.
Vapor Density
6.53
Refractive Index
1.505 (20 C)

First Aid Measures

Ingestion
Never give anything by mouth to an unconscious person. Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation
Get medical aid immediately. Remove from exposure to fresh air immediately. If breathing is difficult, give oxygen. DO NOT use mouth-to-mouth respiration. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
Skin
Get medical aid immediately. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Eyes
Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Do NOT allow victim to rub or keep eyes closed. Extensive irrigation is required (at least 30 minutes).

Handling and Storage

Storage
Keep container closed when not in use. Store in a cool, dry, well-ventilated area away from incompatible substances. Corrosives area.
Handling
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Do not get in eyes, on skin, or on clothing. Keep container tightly closed. Do not ingest or inhale. Use with adequate ventilation. Discard contaminated shoes.

Hazards Identification

Ingestion
May cause severe and permanent damage to the digestive tract. Causes gastrointestinal tract burns.
Inhalation
Causes chemical burns to the respiratory tract.
Skin
Causes skin burns.
Eyes
Causes eye burns.
Hazards
When heated, vapors may form explosive mixtures with air: indoors, outdoors, and sewers explosion hazards.
EC Risk Phrase
R 21/22 34 43 51/53
EC Safety Phrase
S 26 36/37/39 45 61
UN (DOT)
2320

Exposure Controls/Personal Protection

Personal Protection
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators
Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
Poison Class
3

Fire Fighting Measures

Flash Point
139
Autoignition
321
Fire Fighting
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Extinguishing media: Use agent most appropriate to extinguish fire.
Upper exp. limit
15
Lower exp. limit
.1
Fire Potential
Slightly flammable. Combustion requires preheating. Moderate hazard.

Accidental Release Measures

Small spills/leaks
Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Clean up spills immediately, using the appropriate protective equipment. Provide ventilation.

Stability and Reactivity

Incompatibilities
Moisture, strong oxidants.
Stability
Stable under normal temperatures and pressures.
Decomposition
Nitrogen oxides, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, nitrogen.
Combustion Products
Ammonia and toxic oxides of nitrogen may form in fires.

Transport Information

UN Number
2320
Hazard Class
8
Packing Group
III
HS Code
2921 29 00
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