Supplier Product Identification Physical and Chemical Properties Hazards Identification Exposure Controls/Personal Protection Fire Fighting Measures Accidental Release Measures
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Ethyl 2-isopropylacetoacetate(1522-46-9)

Supplier Product Identification Physical and Chemical Properties Hazards Identification Exposure Controls/Personal Protection Fire Fighting Measures Accidental Release Measures

Product Identification

Product Name
Ethyl 2-isopropylacetoacetate
Synonyms
2-Acetyl-3-methylbutyric acid ethyl ester
2-Isopropyl-3-oxobutanoic acid ethyl ester
Acetoacetic acid, 2-isopropyl-, ethyl ester
Butanoic acid, 2-acetyl-3-methyl-, ethyl ester
Ethyl 2-isopropylacetoacetate
Ethyl a-isopropylacetoacetate
CAS
1522-46-9
Formula
C9H16O3
Molecular Weight
172.22
EINECS
216-192-6
Beilstein/Gmelin
636360

Physical and Chemical Properties

Appearance
Clear, colorless liquid.
Solubility in water
3.9 g/L (25 C)
Melting Point
-20
Boiling Point
201
Vapor Pressure
0.03 (25 C)
Density
0.962 g/cm3 (20 C)
pKa/pKb
12.28 (pKa)
Partition Coefficient
1.94
Heat Of Vaporization
44.34 kJ/mol
Refractive Index
1.425 (20 C)

Hazards Identification

Inhalation
If inhaled, remove to fresh air. If not breathing give artificial respiration. If breathing is difficult, give oxygen.
Skin
In case of contact, immediately wash skin with soap and copious amounts of water. Remove contaminated clothing and shoes. Call a physician.
Eyes
In case of contact with eyes, flush with copious amounts of water for at least 15 minutes. Assure adequate flushing by separating the eyelids with fingers. Call a physician.
Ingestion
If swallowed, wash out mouth with water provided person is conscious. Call a physician.
Hazards
Emits toxic fumes under fire conditions.
EC Safety Phrase
23 24/25

Exposure Controls/Personal Protection

Personal Protection
Compatible chemical-resistant gloves. Chemical safety goggles. Protective clothing.

Fire Fighting Measures

Flash Point
76
Fire Fighting
For small (incipient) fires, use media such as 'alcohol' foam, dry chemical, or carbon dioxide. For large fires, apply water from as far as possible. Use very large quantities (flooding) of water applied as a mist or spray; solid streams of water may be ineffective. Cool all affected containers with flooding quantities of water. Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes.

Accidental Release Measures

Small spills/leaks
Ventilate area and wash spill site after material pickup is complete. Absorb on sand or vermiculite and place in closed containers for disposal. Wash spill site with soap solution. Flush spill area with copious amounts of water.
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