Supplier Product Identification Physical and Chemical Properties First Aid Measures Handling and Storage Hazards Identification Exposure Controls/Personal Protection Fire Fighting Measures Accidental Release Measures Stability and Reactivity Transport Information
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2,4-Dichlorobenzoylchloride(94-99-5)

Supplier Product Identification Physical and Chemical Properties First Aid Measures Handling and Storage Hazards Identification Exposure Controls/Personal Protection Fire Fighting Measures Accidental Release Measures Stability and Reactivity Transport Information

Product Identification

Product Name
2,4-Dichlorobenzoylchloride
Synonyms
2,4-Dichloro-1-(chloromethyl)benzene
2,4-Dichlorobenzyl chloride
CAS
94-99-5
Formula
C7H5Cl3
Molecular Weight
195.18
EINECS
202-381-0
Beilstein/Gmelin
387220
Beilstein Reference
4-05-00-00819
EC Class
corrosive

Physical and Chemical Properties

Appearance
Viscous, light yellow liquid.
Solubility in water
Insoluble
Melting Point
-2.7
Boiling Point
248
Vapor Pressure
0.04 (25 C)
Density
1.406 g/cm3 (20 C)
Partition Coefficient
2.69
Heat Of Vaporization
46.6 kJ/mol
Vapor Density
6.74
Refractive Index
1.5819 (20 C)

First Aid Measures

Ingestion
Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation
Get medical aid immediately. Remove from exposure to fresh air immediately. If breathing is difficult, give oxygen. DO NOT use mouth-to-mouth respiration. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
Skin
Get medical aid immediately. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Eyes
Get medical aid immediately. Do NOT allow victim to rub or keep eyes closed. Extensive irrigation is required (at least 30 minutes).

Handling and Storage

Storage
Keep container closed when not in use. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Corrosives area. Store protected from moisture.
Handling
Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Keep container tightly closed. Do not ingest or inhale. Do not allow contact with water. Use only in a chemical fume hood. Discard contaminated shoes. Keep from contact with moist air and steam.

Hazards Identification

Ingestion
May cause severe and permanent damage to the digestive tract. Causes gastrointestinal tract burns. The toxicological properties of this substance have not been fully investigated.
Inhalation
Causes chemical burns to the respiratory tract. The toxicological properties of this substance have not been fully investigated.
Skin
Causes skin irritation and burns.
Eyes
Lachrymator. Causes eye irritation and burns.
Hazards
When heated, vapors may form explosive mixtures with air: indoors, outdoors, and sewers explosion hazards.
EC Risk Phrase
R 34 36
EC Safety Phrase
S 26 36/37/39 45
UN (DOT)
3265

Exposure Controls/Personal Protection

Personal Protection
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use.

Fire Fighting Measures

Flash Point
158
Autoignition
>500
Fire Fighting
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Extinguishing media: Use foam, dry chemical, or carbon dioxide. Use extinguishing media most appropriate for the surrounding fire. Do NOT get water inside containers.
Fire Potential
Combustible material: may burn but does not ignite readily.

Accidental Release Measures

Small spills/leaks
Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Clean up spills immediately, using the appropriate protective equipment. Provide ventilation. Do not get water inside containers.

Stability and Reactivity

Incompatibilities
Moisture, strong oxidizing agents, strong bases.
Stability
Stable under normal temperatures and pressures.
Decomposition
Hydrogen chloride, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
Combustion Products
Fire may produce irritating, corrosive and/or toxic gases.

Transport Information

UN Number
3265
Hazard Class
8
Packing Group
I; II; III
HS Code
2903 69 90
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