Supplier Product Identification Physical and Chemical Properties First Aid Measures Handling and Storage Hazards Identification Exposure Controls/Personal Protection Fire Fighting Measures Accidental Release Measures Stability and Reactivity Transport Information
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Butyl benzoate(136-60-7)

Supplier Product Identification Physical and Chemical Properties First Aid Measures Handling and Storage Hazards Identification Exposure Controls/Personal Protection Fire Fighting Measures Accidental Release Measures Stability and Reactivity Transport Information

Product Identification

Product Name
Butyl benzoate
Synonyms
n-Butyl benzoate
CAS
136-60-7
Formula
C11H14O2
Molecular Weight
178.23
EINECS
205-252-7
RTECS
DG4925000
RTECS Class
Primary Irritant
Merck
13,1551
Beilstein/Gmelin
1867073
Beilstein Reference
4-09-00-00290
EC Class
harmful, irritant

Physical and Chemical Properties

Appearance
Thick, oily liquid. Mild odor.
Solubility in water
Insoluble
Melting Point
-22
Boiling Point
249 - 251
Vapor Pressure
0.022 (25 C)
Density
1.0235 g/cm3 (0 C)
Partition Coefficient
3.79
Heat Of Vaporization
54.8 kJ/mol
Usage
Used in the lacquer industry to a slight extent, as a plasticizer.
Vapor Density
6.15
Refractive Index
1.49473 (12.5 C)

First Aid Measures

Ingestion
If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation
Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Skin
Get medical aid immediately. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.
Eyes
Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.

Handling and Storage

Storage
Store in a cool, dry place. Store in a tightly closed container.
Handling
Wash thoroughly after handling. Use only in a well ventilated area. Avoid contact with eyes, skin, and clothing. Avoid ingestion and inhalation.

Hazards Identification

Inhalation
May cause respiratory tract irritation.
Skin
Causes severe skin irritation. Causes redness and pain.
Eyes
May cause eye irritation. Causes redness and pain.
Ingestion
May cause gastrointestinal irritation with nausea, vomiting and diarrhea. May be harmful if swallowed.
EC Risk Phrase
R 36/38
EC Safety Phrase
S 26 36

Exposure Controls/Personal Protection

Personal Protection
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators
Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
Exposure Effects
Seizures have been reported to occur in animals receiving lethal doses.
Poison Class
-

Fire Fighting Measures

Flash Point
106
Autoignition
440
Fire Fighting
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. To extinguish fire, use water fog, dry chemical, carbon dioxide, or regular foam.
Upper exp. limit
5.4
Lower exp. limit
.8
Fire Potential
Low fire hazard, when exposed to heat or flame.

Accidental Release Measures

Small spills/leaks
Sweep up or absorb material, then place into a suitable clean, dry, closed container for disposal.

Stability and Reactivity

Disposal Code
1
Stability
Stable under normal temperatures and pressures.
Incompatibilities
Strong oxidizing agents, strong bases.
Decomposition
Carbon monoxide, carbon dioxide.

Transport Information

HS Code
2916 31 00
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