Supplier Product Identification Physical and Chemical Properties First Aid Measures Handling and Storage Hazards Identification Exposure Controls/Personal Protection Fire Fighting Measures Accidental Release Measures Stability and Reactivity Transport Information
Home > 4H-3,1-Benzoxazine-2,4(1H)-dione > 4H-3,1-Benzoxazine-2,4(1H)-dione(118-48-9)

4H-3,1-Benzoxazine-2,4(1H)-dione(118-48-9)

Supplier Product Identification Physical and Chemical Properties First Aid Measures Handling and Storage Hazards Identification Exposure Controls/Personal Protection Fire Fighting Measures Accidental Release Measures Stability and Reactivity Transport Information

Product Identification

Product Name
4H-3,1-Benzoxazine-2,4(1H)-dione
Synonyms
1H-3,1-Benzoxazine-2,4-dione
Isato acid anhydride
N-Carboxyanthranilic anhydride
CAS
118-48-9
Formula
C8H5NO3
Molecular Weight
163.13
EINECS
204-255-0
RTECS
DM3100000
RTECS Class
Reproductive Effector
Beilstein/Gmelin
136786
Beilstein Reference
4-27-00-03330
EC Index Number
607-250-00-5
EC Class
Irritant; Sensitising

Physical and Chemical Properties

Appearance
Prism from alcohol or glacial acetic acid; crystals from alcohol or dioxane.
Solubility in water
Slightly soluble
Melting Point
164
Boiling Point
385
Density
1.55 g/cm3
pKa/pKb
8.91 (pKa)
Partition Coefficient
.91
Usage
Intermediate for polymer curing agents, anthranilic esters, heterocyclic compd, & benzyne.
Vapor Density
5.6

First Aid Measures

Ingestion
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation
Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Skin
Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Eyes
Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.

Handling and Storage

Storage
Keep container closed when not in use. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Store protected from moisture.
Handling
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use with adequate ventilation. Do not allow contact with water. Wash clothing before reuse. Keep from contact with moist air and steam.

Hazards Identification

Inhalation
Causes respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
Skin
Causes skin irritation.
Eyes
Causes eye irritation.
Ingestion
Causes gastrointestinal irritation with nausea, vomiting and diarrhea. The toxicological properties of this substance have not been fully investigated.
EC Risk Phrase
R 36 43
EC Safety Phrase
S 24 26 37
UN (DOT)
3335

Exposure Controls/Personal Protection

Personal Protection
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate gloves to prevent skin exposure. Clothing: Wear appropriate clothing to prevent skin exposure.
Respirators
Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
Exposure Effects
Irritating to eyes, respiratory system and skin. The toxicological properties of this material have not been investigated.
Poison Class
5

Fire Fighting Measures

Autoignition
> 600
Fire Fighting
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Extinguishing media: Use agent most appropriate to extinguish fire. Do NOT get water inside containers. In case of fire use water spray, dry chemical, carbon dioxide, or appropriate foam.

Accidental Release Measures

Small spills/leaks
Clean up spills immediately, using the appropriate protective equipment. Sweep up, then place into a suitable container for disposal. Avoid generating dusty conditions. Provide ventilation. Do not get water inside containers.

Stability and Reactivity

Disposal Code
4
Incompatibilities
Oxidizing agents.
Stability
Stable at room temperature in closed containers under normal storage and handling conditions.
Decomposition
Nitrogen oxides, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, nitrogen.

Transport Information

UN Number
3335
HS Code
2934 99 90
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