Home > 2-Amino-5-fluorotoluene > 2-Amino-5-fluorotoluene(452-71-1)
2-Amino-5-fluorotoluene(452-71-1)
Supplier Product Identification
Physical and Chemical Properties
First Aid Measures
Handling and Storage
Hazards Identification
Exposure Controls/Personal Protection
Fire Fighting Measures
Accidental Release Measures
Stability and Reactivity
Transport Information
Product Identification
Product Name
2-Amino-5-fluorotoluene
2-Amino-5-fluorotoluene
Synonyms
2-Amino-5-fluorotoluene
2-Fluoro-o-toluidine
2-Methyl-4-fluoroaniline
6-Amino-3-fluorotoluene
Benzenamine, 4-fluoro-2-methyl-
2-Amino-5-fluorotoluene
2-Fluoro-o-toluidine
2-Methyl-4-fluoroaniline
6-Amino-3-fluorotoluene
Benzenamine, 4-fluoro-2-methyl-
CAS
452-71-1
452-71-1
Formula
C7H8FN
C7H8FN
Molecular Weight
125.14
125.14
EINECS
207-208-2
207-208-2
RTECS
CY0500000
CY0500000
RTECS Class
Mutagen
Mutagen
Beilstein/Gmelin
1931798
1931798
Beilstein Reference
4-12-00-01786
4-12-00-01786
Physical and Chemical Properties
Appearance
Clear pink - red liquid.
Clear pink - red liquid.
Solubility in water
Slightly soluble
Slightly soluble
Melting Point
14
14
Boiling Point
207
207
Vapor Pressure
0.23 (25 C)
0.23 (25 C)
Density
1.1263 g/cm3 (18 C)
1.1263 g/cm3 (18 C)
pKa/pKb
4.51 (pKa)
4.51 (pKa)
Partition Coefficient
1.61
1.61
Heat Of Vaporization
44.3 kJ/mol
44.3 kJ/mol
Vapor Density
4.32
4.32
Refractive Index
1.5308 (18 C)
1.5308 (18 C)
First Aid Measures
Ingestion
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation
Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. DO NOT use mouth-to-mouth respiration.
Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. DO NOT use mouth-to-mouth respiration.
Skin
Get medical aid. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Get medical aid. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Eyes
Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Handling and Storage
Storage
Keep away from heat, sparks, and flame. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
Keep away from heat, sparks, and flame. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
Handling
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use only in a well ventilated area. Do not get in eyes, on skin, or on clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Avoid contact with heat, sparks and flame. Do not ingest or inhale. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use only in a well ventilated area. Do not get in eyes, on skin, or on clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Avoid contact with heat, sparks and flame. Do not ingest or inhale. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Hazards Identification
Inhalation
Aspiration may lead to pulmonary edema. Methemoglobinemia is characterized by dizziness, drowsiness, headache, breath shortness, cyanosis with bluish skin, rapid heart rate and chocolate-brown blood. Inhalation of aniline causes anoxia due to the formation of methemoglobinemia. Inhalation at high concentrations may cause CNS depression and asphixiation.
Aspiration may lead to pulmonary edema. Methemoglobinemia is characterized by dizziness, drowsiness, headache, breath shortness, cyanosis with bluish skin, rapid heart rate and chocolate-brown blood. Inhalation of aniline causes anoxia due to the formation of methemoglobinemia. Inhalation at high concentrations may cause CNS depression and asphixiation.
Skin
Absorption into the body may cause cyanosis. May cause irritation and dermatitis. May cause cyanosis of the extremities.
Absorption into the body may cause cyanosis. May cause irritation and dermatitis. May cause cyanosis of the extremities.
Eyes
May cause chemical conjunctivitis and corneal damage.
May cause chemical conjunctivitis and corneal damage.
Ingestion
May cause gastrointestinal irritation with nausea, vomiting and diarrhea. Methemoglobinemia is characterized by dizziness, drowsiness, headache, breath shortness, cyanosis with bluish skin, rapid heart rate and chocolate-brown colored blood. Overexposure may cause methemoglobinemia.
May cause gastrointestinal irritation with nausea, vomiting and diarrhea. Methemoglobinemia is characterized by dizziness, drowsiness, headache, breath shortness, cyanosis with bluish skin, rapid heart rate and chocolate-brown colored blood. Overexposure may cause methemoglobinemia.
Hazards
When heated, vapors may form explosive mixtures with air: indoors, outdoors, and sewers explosion hazards.
When heated, vapors may form explosive mixtures with air: indoors, outdoors, and sewers explosion hazards.
EC Risk Phrase
R 20/21/22 33 36/38
R 20/21/22 33 36/38
EC Safety Phrase
S 26 36/37/39
S 26 36/37/39
UN (DOT)
2810
2810
Exposure Controls/Personal Protection
Personal Protection
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use.
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use.
Exposure Effects
May cause methemoglobinemia, which is characterized by chocolate-brown colored blood, headache, weakness, dizziness, breath shortness, cyanosis, rapid heart rate, unconsciousness and possible death. Effects may be delayed.
May cause methemoglobinemia, which is characterized by chocolate-brown colored blood, headache, weakness, dizziness, breath shortness, cyanosis, rapid heart rate, unconsciousness and possible death. Effects may be delayed.
Fire Fighting Measures
Flash Point
87
87
Fire Fighting
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. Combustible Liquid. Containers may explode when heated. To extinguish fire, use water, dry chemical, chemical foam, or alcohol-resistant foam. Use water spray to cool fire-exposed containers.
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. Combustible Liquid. Containers may explode when heated. To extinguish fire, use water, dry chemical, chemical foam, or alcohol-resistant foam. Use water spray to cool fire-exposed containers.
Fire Potential
Combustible material: may burn but does not ignite readily.
Combustible material: may burn but does not ignite readily.
Accidental Release Measures
Small spills/leaks
Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Avoid runoff into storm sewers and ditches which lead to waterways. Remove all sources of ignition. Use a spark-proof tool.
Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Avoid runoff into storm sewers and ditches which lead to waterways. Remove all sources of ignition. Use a spark-proof tool.
Stability and Reactivity
Stability
Stable under normal temperatures and pressures.
Stable under normal temperatures and pressures.
Incompatibilities
Strong oxidizing agents, acids, acid chlorides, acid anhydrides, chloroformates.
Strong oxidizing agents, acids, acid chlorides, acid anhydrides, chloroformates.
Decomposition
Nitrogen oxides, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, hydrogen fluoride.
Nitrogen oxides, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, hydrogen fluoride.
Combustion Products
Fire may produce irritating, corrosive and/or toxic gases.
Fire may produce irritating, corrosive and/or toxic gases.
Transport Information
UN Number
2810
2810
Hazard Class
6.1
6.1
Packing Group
I; II; III
I; II; III
Contact
More
- Company Name:Shanghai Boyle Chemical Co., Ltd.
- Tel: 021-50182298 021-50180596
- Fax:+86-21-57758967
- WebSite:http://www.boylechem.com
- Company Name:J & K SCIENTIFIC LTD.
- Tel:010-82848833 400-666-7788
- Fax:86-10-82849933
- WebSite:http://www.jkchemical.com
- Company Name:Meryer (Shanghai) Chemical Technology Co., Ltd.
- Tel:021-61259108 18621169109
- Fax:86-21-61259102
- WebSite:https://www.meryer.com/cn/index/
- Company Name:Liaoning Tianhua Chemical Co., Ltd.
- Tel:0418-6530555 2855550
- Fax:+86-418-6502885
- WebSite:https://www.chemicalbook.com/ShowSupplierProductsList6177/0.htm
- Company Name:Alfa Aesar
- Tel:400-6106006
- Fax:021-67582001/03/05
- WebSite:http://chemicals.thermofisher.cn