Supplier Product Identification Physical and Chemical Properties First Aid Measures Handling and Storage Hazards Identification Exposure Controls/Personal Protection Fire Fighting Measures Accidental Release Measures Stability and Reactivity
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Thianaphthene-2-carboxylic acid(6314-28-9)

Supplier Product Identification Physical and Chemical Properties First Aid Measures Handling and Storage Hazards Identification Exposure Controls/Personal Protection Fire Fighting Measures Accidental Release Measures Stability and Reactivity

Product Identification

Product Name
Thianaphthene-2-carboxylic acid
Synonyms
1-Benzothiophene-2-carboxylic acid
Benzo[b]thiophene-2-carboxylic acid
Benzothiofuran-2-carboxylic acid
Benzothiophene-2-carboxylic acid
BL 5583
Thionaphthene-2-carboxylic acid
CAS
6314-28-9
Formula
C9H6O2S
Molecular Weight
178.2
Merck
12,9481
Beilstein/Gmelin
124613
Beilstein Reference
5-18-06-00427

Physical and Chemical Properties

Appearance
White solid. With a stench.
Melting Point
242 - 243
pKa/pKb
3.48 (pKa)

First Aid Measures

Ingestion
Get medical aid. Wash mouth out with water.
Inhalation
Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Skin
Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.
Eyes
Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.

Handling and Storage

Storage
Store in a cool, dry place. Store in a tightly closed container.
Handling
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Use only in a chemical fume hood.

Hazards Identification

Ingestion
May cause irritation of the digestive tract.
Inhalation
Causes respiratory tract irritation. May cause headache. May cause nausea and possible vomiting.
Skin
Causes skin irritation.
Eyes
Causes eye irritation.
EC Risk Phrase
R 36/37/38
EC Safety Phrase
S 26 36

Exposure Controls/Personal Protection

Personal Protection
Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators
Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.

Fire Fighting Measures

Fire Fighting
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. To extinguish fire use water spray, dry chemical, carbon dioxide, or chemical foam.

Accidental Release Measures

Small spills/leaks
Vacuum or sweep up material and place into a suitable disposal container.

Stability and Reactivity

Stability
Stable under normal temperatures and pressures.
Incompatibilities
Strong oxidizing agents.
Decomposition
Carbon monoxide, oxides of sulfur, carbon dioxide.
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