Supplier Product Identification Physical and Chemical Properties First Aid Measures Handling and Storage Hazards Identification Exposure Controls/Personal Protection Fire Fighting Measures Accidental Release Measures Stability and Reactivity
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Metaphosphoric acid sodium salt(10361-03-2)

Supplier Product Identification Physical and Chemical Properties First Aid Measures Handling and Storage Hazards Identification Exposure Controls/Personal Protection Fire Fighting Measures Accidental Release Measures Stability and Reactivity

Product Identification

Product Name
Metaphosphoric acid sodium salt
Synonyms
Graham's salt
Kurrol's salt
Maddrell's salt
Metafos
Metaphosphoric acid, sodium salt
Poly(sodium metaphosphate)
CAS
10361-03-2
Formula
NaO3P
Molecular Weight
101.96
EINECS
233-782-9
RTECS
OY3750000
RTECS Class
Other
Beilstein/Gmelin
32882 (G)

Physical and Chemical Properties

Solubility in water
Very soluble
Melting Point
625
Density
2.54 g/cm3
Heat Of Vaporization
Usage
Used in toothpaste formulations as an abrasive.

First Aid Measures

Ingestion
Immediately dilute with 4 to 8 ounces (120 to 240 ml) of milk or water (not to exceed 4 ounces/120 ml in a child). Spontaneous vomiting frequently occurs following ingestion. If spontaneous vomiting does not occur then significant ingestion is unlikely. Administration of activated charcoal is unnecessary. Observe patients with ingestion carefully for the possible development of esophageal or gastrointestinal tract irritation or burns. If signs or symptoms of esophageal irritation or burns are present, consider endoscopy to determine the extent of injury. Patient should be evaluated for burns to the mouth and esophagus following ingestion of low phosphate detergents which are generally more alkaline.
Inhalation
Move patient to fresh air. Monitor for respiratory distress. If cough or difficulty breathing develops, evaluate for respiratory tract irritation, bronchitis, or pneumonitis. Administer oxygen and assist ventilation as required. Treat bronchospasm with beta2 agonist and corticosteroid aerosols.
Skin
Remove contaminated clothing, wash exposed area with copious amounts of water. A physician should examine the area if irritation or pain persists.
Eyes
Irrigate exposed eyes with copious amounts of tepid water for at least 15 minutes. If irritation, pain, swelling, lacrimation, or photophobia persist, the patient should be seen in a health care facility.

Handling and Storage

Storage
Keep in a cool, dry, dark location in a tightly sealed container or cylinder. Keep away from incompatible materials, ignition sources and untrained individuals. Secure and label area. Protect containers/cylinders from physical damage.
Handling
All chemicals should be considered hazardous. Avoid direct physical contact. Use appropriate, approved safety equipment. Untrained individuals should not handle this chemical or its container. Handling should occur in a chemical fume hood.

Hazards Identification

Ingestion
Nausea, vomiting, and diarrhea are common. Oral, pharyngeal and esophageal burns may occur following ingestion of low phosphate detergents which are generally more alkaline. Colitis, esophageal stricture, and irritation of mucous membranes have also been reported.
Inhalation
Occupational asthma has been reported. Aspiration may result in upper airway edema and significant respiratory distress. Difficulty in breathing has been described in animals inhaling high concentrations of anionic surfactants.
Skin
Skin irritation has been reported after prolonged occupational dermal contact. Skin dryness, irritation, and contact dermatitis have been reported following varying degrees of exposure to detergents.

Exposure Controls/Personal Protection

Personal Protection
Chemical splash goggles in compliance with OSHA regulations are advised; however, OSHA regulations also permit other type safety glasses. Whre chemical resistant gloves. To prevent repeated or prolonged skin contact, wear impervious clothing and boots.
Respirators
Use NIOSH/MSHA approved respirator appropriate for exposure of concern.
Poison Class
5

Fire Fighting Measures

Fire Fighting
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use agent most appropriate to extinguish fire.

Accidental Release Measures

Small spills/leaks
Evacuate area and ventilate. Wear protective equipment. If required, use an inert absrobent. Sweep up and place in an appropriate container for disposal. Wash contaminated surfaces.

Stability and Reactivity

Stability
No data.
Incompatibilities
Strong oxidizing agents.
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