Home > 3-Nitrophenylamine > 3-Nitrophenylamine(99-09-2)
3-Nitrophenylamine(99-09-2)
Product Identification
Physical and Chemical Properties
First Aid Measures
Handling and Storage
Hazards Identification
Exposure Controls/Personal Protection
Fire Fighting Measures
Accidental Release Measures
Stability and Reactivity
Transport Information
Product Identification
Product Name
3-Nitrophenylamine
3-Nitrophenylamine
Synonyms
1-Amino-3-nitrobenzene
Amarthol Fast Orange R Base
Azobase MNA
C.I. 37030
m-Nitroaniline
Orange Base Irga I
1-Amino-3-nitrobenzene
Amarthol Fast Orange R Base
Azobase MNA
C.I. 37030
m-Nitroaniline
Orange Base Irga I
CAS
99-09-2
99-09-2
Formula
C6H6N2O2
C6H6N2O2
Molecular Weight
138.13
138.13
EINECS
202-729-1
202-729-1
RTECS
BY6825000
BY6825000
RTECS Class
Mutagen
Mutagen
Merck
12,6679
12,6679
Beilstein/Gmelin
636962
636962
Beilstein Reference
4-12-00-01589
4-12-00-01589
EC Index Number
612-012-00-9
612-012-00-9
EC Class
Toxic; Danger of cumulative effects; Dangerous for the Environment
Toxic; Danger of cumulative effects; Dangerous for the Environment
Physical and Chemical Properties
Appearance
Yellow needle-like crystals, burning, sweet odor.
Yellow needle-like crystals, burning, sweet odor.
Solubility in water
Insoluble
Insoluble
Melting Point
109 - 112
109 - 112
Boiling Point
306
306
Vapor Pressure
0.2 (100 C)
0.2 (100 C)
Density
1.492 g/cm3 (-163.15 C)
1.492 g/cm3 (-163.15 C)
pKa/pKb
11.53 (pKb)
11.53 (pKb)
Partition Coefficient
1.37
1.37
Heat Of Vaporization
108 kj/mol
108 kj/mol
Heat Of Combustion
-3184 kJ/mol
-3184 kJ/mol
Usage
Stabilizer of ammonium dinitramide melt.
Stabilizer of ammonium dinitramide melt.
Saturation Concentration
Nearly zero at 25 C
Nearly zero at 25 C
Refractive Index
1.595 (111 C)
1.595 (111 C)
First Aid Measures
Ingestion
If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately. Induce vomiting by giving one teaspoon of Syrup of Ipecac.
If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately. Induce vomiting by giving one teaspoon of Syrup of Ipecac.
Inhalation
Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Skin
Get medical aid immediately. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Get medical aid immediately. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Eyes
Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Handling and Storage
Storage
Keep away from sources of ignition. Store in a cool, dry, well-ventilated area away from incompatible substances.
Keep away from sources of ignition. Store in a cool, dry, well-ventilated area away from incompatible substances.
Handling
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Ground and bond containers when transferring material. Use spark-proof tools and explosion proof equipment. Keep container tightly closed. Do not get on skin or in eyes. Do not ingest or inhale.
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Ground and bond containers when transferring material. Use spark-proof tools and explosion proof equipment. Keep container tightly closed. Do not get on skin or in eyes. Do not ingest or inhale.
Hazards Identification
Inhalation
May cause respiratory tract irritation. May cause effects similar to those described for ingestion. Inhalation of aniline causes anoxia due to the formation of methemoglobinemia.
May cause respiratory tract irritation. May cause effects similar to those described for ingestion. Inhalation of aniline causes anoxia due to the formation of methemoglobinemia.
Skin
May cause skin irritation. Substance is rapidly absorbed through the skin. If absorbed, may cause symptoms similar to those for ingestion.
May cause skin irritation. Substance is rapidly absorbed through the skin. If absorbed, may cause symptoms similar to those for ingestion.
Eyes
May cause eye irritation. Vapors may cause eye irritation. May cause eye injury.
May cause eye irritation. Vapors may cause eye irritation. May cause eye injury.
Ingestion
May cause methemoglobinemia, cyanosis, convulsions, and death. Effects may be delayed 2 to 4 hours. Methemoglobinemia is characterized by dizziness, drowsiness, headache, breath shortness, cyanosis with bluish skin, rapid heart rate and chocolate-brown colored blood. May be harmful if swallowed. Alcohol can intensify effects.
May cause methemoglobinemia, cyanosis, convulsions, and death. Effects may be delayed 2 to 4 hours. Methemoglobinemia is characterized by dizziness, drowsiness, headache, breath shortness, cyanosis with bluish skin, rapid heart rate and chocolate-brown colored blood. May be harmful if swallowed. Alcohol can intensify effects.
Hazards
When heated, vapors may form explosive mixtures with air: indoors, outdoors, and sewers explosion hazards.
When heated, vapors may form explosive mixtures with air: indoors, outdoors, and sewers explosion hazards.
EC Risk Phrase
R 23/24/25 33 52/53
R 23/24/25 33 52/53
EC Safety Phrase
S 28 36/37 45 61
S 28 36/37 45 61
UN (DOT)
1661
1661
Exposure Controls/Personal Protection
Personal Protection
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators
Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
Exposure Effects
May cause liver and kidney damage. May cause bone marrow abnormalities with damage to blood forming tissues. May cause anemia and other blood cell abnormalities. Repeated exposure may cause central nervous system damage. Reproductive effects have been reported in animals.
May cause liver and kidney damage. May cause bone marrow abnormalities with damage to blood forming tissues. May cause anemia and other blood cell abnormalities. Repeated exposure may cause central nervous system damage. Reproductive effects have been reported in animals.
Exposure limit(s)
NIOSH: Potential Occupational Carcinogen.
NIOSH: Potential Occupational Carcinogen.
Fire Fighting Measures
Flash Point
196
196
Autoignition
521
521
Fire Fighting
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. To extinguish fire, use water, dry chemical, chemical foam, or alcohol-resistant foam. Use agent most appropriate to extinguish fire.
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. To extinguish fire, use water, dry chemical, chemical foam, or alcohol-resistant foam. Use agent most appropriate to extinguish fire.
Upper exp. limit
9.8
9.8
Lower exp. limit
1.7
1.7
Fire Potential
This material is probably combustible.
This material is probably combustible.
Accidental Release Measures
Small spills/leaks
Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, using the appropriate protective equipment. Wear a self contained breathing apparatus and appropriate Personal protection. (See Exposure Controls, Personal Protection section). Avoid generating dusty conditions. Remove all sources of ignition. Provide ventilation.
Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, using the appropriate protective equipment. Wear a self contained breathing apparatus and appropriate Personal protection. (See Exposure Controls, Personal Protection section). Avoid generating dusty conditions. Remove all sources of ignition. Provide ventilation.
Stability and Reactivity
Disposal Code
9
9
Stability
Stable at room temperature in closed containers under normal storage and handling conditions.
Stable at room temperature in closed containers under normal storage and handling conditions.
Incompatibilities
Strong acids, strong oxidizing agents, strong reducing agents.
Strong acids, strong oxidizing agents, strong reducing agents.
Decomposition
Nitrogen oxides, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, nitrogen.
Nitrogen oxides, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, nitrogen.
Combustion Products
Toxic oxides of nitrogen may form in fire.
Toxic oxides of nitrogen may form in fire.
Transport Information
UN Number
1661
1661
Hazard Class
6.1
6.1
Packing Group
II
II
HS Code
2921 42 10
2921 42 10