Supplier Product Identification Physical and Chemical Properties First Aid Measures Handling and Storage Hazards Identification Exposure Controls/Personal Protection Fire Fighting Measures Accidental Release Measures Stability and Reactivity Transport Information
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1-Piperazineethanol(103-76-4)

Supplier Product Identification Physical and Chemical Properties First Aid Measures Handling and Storage Hazards Identification Exposure Controls/Personal Protection Fire Fighting Measures Accidental Release Measures Stability and Reactivity Transport Information

Product Identification

Product Name
1-Piperazineethanol
Synonyms
2-Piperazin-1-ylethanol
Benzoxazolium, 3-hexyl-2-[3-(3-hexyl-2(3H)-benzoxazolylidene)-1-propenyl]-, iodide
N-(2-Hydroxyethyl)piperazine
CAS
53213-82-4
CAS
103-76-4
Formula
C29H37IN2O2
Formula
C6H14N2O
Molecular Weight
130.19
Molecular Weight
572.52
EINECS
203-142-3
RTECS
TL6825000
RTECS Class
Primary Irritant
Beilstein/Gmelin
NA
Beilstein/Gmelin
104361
Beilstein Reference
5-23-01-00406
EC Class
irritant

Physical and Chemical Properties

Appearance
Clear, light yellow liquid.
Appearance
Red powder.
Solubility in water
Very soluble
Melting Point
215-221
Melting Point
-38
Boiling Point
246
Vapor Pressure
0.005 (25 C)
Density
1.0595 g/cm3 (20 C)
pKa/pKb
4.73 (pKb)
Partition Coefficient
-.45
Heat Of Vaporization
56.0 kJ/mol
Vapor Density
4.5
Refractive Index
1.5058 (20 C)

First Aid Measures

Ingestion
Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Ingestion
If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid.
Ingestion
May cause gastrointestinal irritation with nausea, vomiting and diarrhea. The toxicological properties of this substance have not been fully investigated. Chronic ingestion of iodides during pregnancy has resulted in fetal death, severe goiter, and cretinoid appearance of the newborn.
Inhalation
Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Inhalation
Causes respiratory tract irritation. May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated. Can produce delayed pulmonary edema.
Skin
Causes skin irritation.
Skin
Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Eyes
Causes eye irritation. May cause chemical conjunctivitis.
Eyes
Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Eyes
Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.

Handling and Storage

Storage
Keep container closed when not in use. Store in a cool, dry, well-ventilated area away from incompatible substances.
Storage
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Store protected from light.
Handling
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use only in a well ventilated area. Avoid contact with eyes, skin, and clothing. Avoid ingestion and inhalation.
Handling
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Store protected from light.

Hazards Identification

Inhalation
May cause respiratory tract irritation.
Skin
Causes skin irritation.
Eyes
Causes eye irritation.
Ingestion
Ingestion of large amounts may cause gastrointestinal irritation. May cause gastrointestinal irritation with nausea, vomiting and diarrhea.
EC Risk Phrase
R 38 41
EC Safety Phrase
S 26 37/39

Exposure Controls/Personal Protection

Personal Protection
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators
Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
Respirators
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use.
Exposure Effects
Effects may be delayed. Chronic ingestion of iodides during pregnancy has resulted in fetal death, severe goiter and cretinoid appearance of the newborn.. Prolonged exposure to iodides may produce iodism in sensitive individuals. Exposure will include: skin rash, running nose and headache.
Exposure Effects
The toxicological properties of this substance have not been fully investigated.
Poison Class
4

Fire Fighting Measures

Flash Point
102
Autoignition
280
Fire Fighting
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Extinguishing media: Use agent most appropriate to extinguish fire. In case of fire use water spray, dry chemical, carbon dioxide, or appropriate foam.
Fire Fighting
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. To extinguish fire, use water, dry chemical, chemical foam, or alcohol-resistant foam.
Upper exp. limit
8.9
Lower exp. limit
1.4

Accidental Release Measures

Small spills/leaks
Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Clean up spills immediately, using the appropriate protective equipment. Provide ventilation.
Small spills/leaks
Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, using the appropriate protective equipment. Avoid generating dusty conditions. Provide ventilation.

Stability and Reactivity

Incompatibilities
Oxidizing agents.
Stability
Stable at room temperature in closed containers under normal storage and handling conditions.
Stability
Stable under normal temperatures and pressures.
Incompatibilities
Strong oxidizing agents, acids, chlorinated solvents, copper, copper alloys.
Disposal Code
5
Decomposition
Carbon monoxide, oxides of nitrogen, irritating and toxic fumes and gases, carbon dioxide, oxides of iodine.
Decomposition
Nitrogen oxides, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, nitrogen.

Transport Information

HS Code
2933 59 95
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