Home > 1-Bromopropane > 1-Bromopropane(106-94-5)
1-Bromopropane(106-94-5)
Supplier Product Identification
Physical and Chemical Properties
First Aid Measures
Handling and Storage
Hazards Identification
Exposure Controls/Personal Protection
Fire Fighting Measures
Accidental Release Measures
Stability and Reactivity
Transport Information
Product Identification
Product Name
1-Bromopropane
1-Bromopropane
Synonyms
Propyl bromide
Propyl bromide
CAS
106-94-5
106-94-5
Formula
C3H7Br
C3H7Br
Molecular Weight
123
123
EINECS
203-445-0
203-445-0
RTECS
TX4110000
TX4110000
RTECS Class
Tumorigen; Reproductive Effector
Tumorigen; Reproductive Effector
Merck
12,8030
12,8030
Beilstein/Gmelin
505936
505936
Beilstein Reference
4-01-00-00205
4-01-00-00205
EC Index Number
602-019-00-5
602-019-00-5
EC Class
Flammable; Harmful
Flammable; Harmful
Physical and Chemical Properties
Appearance
Colorless liquid.
Colorless liquid.
Solubility in water
2.5 g/L
2.5 g/L
Melting Point
-108
-108
Boiling Point
71
71
Vapor Pressure
111 (25 C)
111 (25 C)
Density
1.354 g/cm3 (20 C)
1.354 g/cm3 (20 C)
Partition Coefficient
2.1
2.1
Heat Of Vaporization
29.9 kJ/mol
29.9 kJ/mol
Heat Of Combustion
-2090 kJ/mol
-2090 kJ/mol
Usage
Use is as a solvent, generally for fats, waxes, or resins, or as an intermediate in the synthesis of other compounds.
Use is as a solvent, generally for fats, waxes, or resins, or as an intermediate in the synthesis of other compounds.
Vapor Density
4.25
4.25
Saturation Concentration
145800 ppm (14.58%) at 20 C; 188200 ppm (18.8%) at 25 C (calcualted)
145800 ppm (14.58%) at 20 C; 188200 ppm (18.8%) at 25 C (calcualted)
Refractive Index
1.4341 (20 C)
1.4341 (20 C)
First Aid Measures
Ingestion
If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation
Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Skin
Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Remove contaminated clothing and shoes.
Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Remove contaminated clothing and shoes.
Eyes
Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Handling and Storage
Storage
Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
Handling
Wash thoroughly after handling. Use with adequate ventilation. Ground and bond containers when transferring material. Use spark-proof tools and explosion proof equipment. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Avoid contact with heat, sparks and flame. Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Wash thoroughly after handling. Use with adequate ventilation. Ground and bond containers when transferring material. Use spark-proof tools and explosion proof equipment. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Avoid contact with heat, sparks and flame. Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Hazards Identification
Inhalation
Inhalation of high concentrations may cause central nervous system effects characterized by headache, dizziness, unconsciousness and coma. May cause liver and kidney damage. Vapors may cause dizziness or suffocation. Exposure may cause bone marrow changes. Exposure may cause blood abnormalities Causes respiratory tract irritation with possible burns.
Inhalation of high concentrations may cause central nervous system effects characterized by headache, dizziness, unconsciousness and coma. May cause liver and kidney damage. Vapors may cause dizziness or suffocation. Exposure may cause bone marrow changes. Exposure may cause blood abnormalities Causes respiratory tract irritation with possible burns.
Skin
Causes skin irritation and possible burns.
Causes skin irritation and possible burns.
Eyes
Causes eye irritation and possible burns.
Causes eye irritation and possible burns.
Ingestion
May cause irritation of the digestive tract.
May cause irritation of the digestive tract.
Hazards
Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers.
Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers.
EC Risk Phrase
R 10 20
R 10 20
EC Safety Phrase
S 9 24
S 9 24
UN (DOT)
2344
2344
Exposure Controls/Personal Protection
Personal Protection
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators
Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
Exposure Effects
Chronic inhalation and ingestion may cause effects similar to those of acute inhalation and ingestion.
Chronic inhalation and ingestion may cause effects similar to those of acute inhalation and ingestion.
Poison Class
3
3
Fire Fighting Measures
Flash Point
24
24
Autoignition
490
490
Fire Fighting
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Use water spray to keep fire-exposed containers cool. Containers may explode in the heat of a fire. May polymerize explosively when involved in a fire. Extinguishing media: For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam. For large fires, use water spray, fog, or alcohol-resistant foam. Use water spray to cool fire-exposed containers. Water may be ineffective. Do NOT get water inside containers. Do NOT use straight streams of water.
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Use water spray to keep fire-exposed containers cool. Containers may explode in the heat of a fire. May polymerize explosively when involved in a fire. Extinguishing media: For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam. For large fires, use water spray, fog, or alcohol-resistant foam. Use water spray to cool fire-exposed containers. Water may be ineffective. Do NOT get water inside containers. Do NOT use straight streams of water.
Upper exp. limit
13.8
13.8
Lower exp. limit
4.6
4.6
Fire Potential
Dangerous, when heated or exposed to flame or oxidizers.
Dangerous, when heated or exposed to flame or oxidizers.
Accidental Release Measures
Small spills/leaks
Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Clean up spills immediately, using the appropriate protective equipment. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation. A vapor suppressing foam may be used to reduce vapors.
Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Clean up spills immediately, using the appropriate protective equipment. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation. A vapor suppressing foam may be used to reduce vapors.
Stability and Reactivity
Disposal Code
9
9
Stability
Stable under normal temperatures and pressures.
Stable under normal temperatures and pressures.
Incompatibilities
Strong oxidizing agents.
Strong oxidizing agents.
Decomposition
Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, hydrogen bromide.
Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, hydrogen bromide.
Combustion Products
Fire will produce irritating, corrosive and/or toxic gases.
Fire will produce irritating, corrosive and/or toxic gases.
Transport Information
UN Number
2344
2344
Hazard Class
3
3
Packing Group
II; III
II; III
HS Code
2903 30 36
2903 30 36
Contact
More
- Company Name:Shouguang Nuomeng Chemical Co Ltd.
- Tel:536-5399456 13869682027
- Fax:0536-5399456
- WebSite:http://www.nuomengchem.com
- Company Name:SHANGHAI BANGCHENG CHEMICAL Co.,Ltd.
- Tel:021-69106960 13701823733
- Fax:021-69106780
- WebSite:http://www.bangchengchem.com/
- Company Name:Yancheng Longshen Chemical Co.,Ltd.
- Tel:0515-0515-88718898 18352070236
- Fax:0515-88718898
- WebSite:https://www.longshenchem.com/
- Company Name:Yonghua Chemical Co., Ltd.
- Tel:0512-52549999-873 13706235395
- Fax:+86-52546337
- WebSite:https://www.yonghuachem.com
- Company Name:Meryer (Shanghai) Chemical Technology Co., Ltd.
- Tel:021-61259108 18621169109
- Fax:86-21-61259102
- WebSite:https://www.meryer.com/cn/index/