Supplier Product Identification Physical and Chemical Properties First Aid Measures Handling and Storage Hazards Identification Exposure Controls/Personal Protection Fire Fighting Measures Accidental Release Measures Stability and Reactivity Transport Information
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2,6-Dimethylaniline(87-62-7)

Supplier Product Identification Physical and Chemical Properties First Aid Measures Handling and Storage Hazards Identification Exposure Controls/Personal Protection Fire Fighting Measures Accidental Release Measures Stability and Reactivity Transport Information

Product Identification

Product Name
2,6-Dimethylaniline
Synonyms
2,6-Dimethylaniline
Xylylamine
CAS
87-62-7
Formula
C8H11N
Molecular Weight
121.18
EINECS
201-758-7
RTECS
JE9275000
RTECS Class
Tumorigen; Mutagen; Natural Product
Merck
12,10217
Beilstein/Gmelin
636332
Beilstein Reference
4-12-00-02521
EC Index Number
612-161-00-X
EC Class
Carcinogenic Category 3; Harmful; Irritant; Dangerous for the Environment

Physical and Chemical Properties

Appearance
Yellow liquid.
Solubility in water
Slightly soluble
Melting Point
10 - 12
Boiling Point
214
Vapor Pressure
.1
Density
0.9846 g/cm3 (14 C)
pKa/pKb
3.89(at 25℃) (pKa)
Partition Coefficient
1.84
Heat Of Vaporization
59.64 kJ/mol
Heat Of Combustion
-4679 kJ/mol
Usage
Chemical intermediate for dyes.
Vapor Density
4.17
Odor threshold
0.0240 mg/m3
Refractive Index
1.5579 (14 C)

First Aid Measures

Ingestion
If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation
Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Skin
Get medical aid immediately. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.
Eyes
Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.

Handling and Storage

Storage
Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
Handling
Wash thoroughly after handling. Use only in a well ventilated area. Avoid contact with eyes, skin, and clothing. Avoid ingestion and inhalation.

Hazards Identification

Inhalation
May cause respiratory tract irritation. May cause methemoglobinemia, cyanosis, convulsions, tachycardia, dyspnea, and death. Methemoglobinemia is characterized by dizziness, drowsiness, headache, breath shortness, cyanosis with bluish skin, rapid heart rate and chocolate-brown blood.
Skin
May cause skin irritation.
Eyes
May cause eye irritation.
Ingestion
Causes gastrointestinal irritation with nausea, vomiting and diarrhea. May cause methemoglobinemia, cyanosis, convulsions, and death. Methemoglobinemia is characterized by dizziness, drowsiness, headache, breath shortness, cyanosis with bluish skin, rapid heart rate and chocolate-brown colored blood. May be harmful if swallowed.
Hazards
When heated, vapors may form explosive mixtures with air: indoors, outdoors, and sewers explosion hazards.
EC Risk Phrase
R 20/21/22 37/38 40 51/53
EC Safety Phrase
S 23 25 36/37 61
UN (DOT)
1711

Exposure Controls/Personal Protection

Personal Protection
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators
Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
Exposure Effects
Effects may be delayed.
Poison Class
3 (Strong toxins)

Fire Fighting Measures

Flash Point
92
Autoignition
490
Fire Fighting
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. To extinguish fire, use water fog, dry chemical, carbon dioxide, or regular foam. Do NOT get water inside containers.
Upper exp. limit
6.9
Lower exp. limit
1.3
Fire Potential
Combustible material: may burn but does not ignite readily.

Accidental Release Measures

Small spills/leaks
Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container.

Stability and Reactivity

Disposal Code
9
Stability
Stable under normal temperatures and pressures.
Incompatibilities
Strong oxidizing agents, acids, acid chlorides, halogens, acid anhydrides, hypochlorite, chloroformates.
Decomposition
Nitrogen oxides, carbon monoxide, carbon dioxide.
Combustion Products
Container explosion may occur under fire conditions.

Transport Information

UN Number
1711
Hazard Class
6.1
Packing Group
II
HS Code
2921 49 10
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