Supplier Product Identification Physical and Chemical Properties First Aid Measures Handling and Storage Hazards Identification Exposure Controls/Personal Protection Fire Fighting Measures Accidental Release Measures Stability and Reactivity Transport Information
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Titanium tetrapropanolate(3087-37-4)

Supplier Product Identification Physical and Chemical Properties First Aid Measures Handling and Storage Hazards Identification Exposure Controls/Personal Protection Fire Fighting Measures Accidental Release Measures Stability and Reactivity Transport Information

Product Identification

Product Name
Titanium tetrapropanolate
Synonyms
Tetraisopropyl titanate
Titanium tetrapropanolate
Titanium(IV) isopropoxide
CAS
3087-37-4
Formula
C12H28O4Ti
Molecular Weight
284.25
EINECS
221-411-3
Beilstein/Gmelin
4146685
EC Class
flammable, irritant

Physical and Chemical Properties

Appearance
A clear yellow liquid with a mild fruity odor.
Solubility in water
Decomposes
Boiling Point
137 (7 hPa)
Density
1.033 g/cm3 (20 C)
Refractive Index
1.4982 (20 C)

First Aid Measures

Ingestion
Wash mouth out with water if person is conscious.
Inhalation
Move to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Skin
Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Eyes
Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.

Handling and Storage

Storage
Store in a cool, dry location, away from heat and open flame. Keep container tightly closed.
Handling
All chemicals should be considered hazardous. Avoid direct physical contact. Use appropriate, approved safety equipment. Untrained individuals should not handle this chemical or its container. Handling should occur in a chemical fume hood.

Hazards Identification

Inhalation
Causes irritation.
Skin
Causes irritation.
Eyes
Causes irritation.
Hazards
Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. May polymerize explosively when heated or involved in a fire. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water. Substance may be transported hot.
EC Risk Phrase
R 10 36/38
EC Safety Phrase
S 26 36
UN (DOT)
2413

Exposure Controls/Personal Protection

Personal Protection
Wear protective gloves and clothing and safety goggles.
Respirators
Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
Exposure Effects
The toxological properties of this substance have not been fully investigated.

Fire Fighting Measures

Flash Point
38
Fire Fighting
Use water in flooding quantities as fog. Use alcohol foam, dry chemical or carbon dioxide. Keep run-off water out of sewers and water sources.
Fire Potential
HIGHLY FLAMMABLE.

Accidental Release Measures

Small spills/leaks
Keep sparks, flames, and other sources of ignition away. Keep material out of water sources and sewers. Build dikes to contain flow as necessary. Do not use water. Apply water spray or mist to knock down vapors. Land spill: Dig a pit, pond, lagoon, holding area to contain liquid or solid material. Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete. Absorb bulk liquid with fly ash, cement powder, or commercial sorbents. Water spill: Use natural barriers or oil spill control booms to limit spill travel. Remove trapped material with suction hoses.

Stability and Reactivity

Disposal Code
28
Incompatibilities
Incompatible with acids and bases Incompatible with oxidizing agents.
Stability
No data.
Combustion Products
Emits toxic fumes under fire conditions.

Transport Information

UN Number
2413
Hazard Class
3
Packing Group
III
HS Code
2905 19 00
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