Supplier Product Identification Physical and Chemical Properties First Aid Measures Handling and Storage Hazards Identification Exposure Controls/Personal Protection Fire Fighting Measures Accidental Release Measures Stability and Reactivity Transport Information
Home > Methyl amyl ketone > Methyl amyl ketone(110-43-0)

Methyl amyl ketone(110-43-0)

Supplier Product Identification Physical and Chemical Properties First Aid Measures Handling and Storage Hazards Identification Exposure Controls/Personal Protection Fire Fighting Measures Accidental Release Measures Stability and Reactivity Transport Information

Product Identification

Product Name
Methyl amyl ketone
Synonyms
2-Heptanone
Butylacetone
Heptan-2-one
Methyl amyl ketone
CAS
110-43-0
Formula
C7H14O
Molecular Weight
114.19
EINECS
203-767-1
RTECS
MJ5075000
RTECS Class
Primary Irritant
Merck
13,4683
Beilstein/Gmelin
1699063
Beilstein Reference
4-01-00-03318
EC Index Number
606-024-00-3
EC Class
Flammable; Harmful

Physical and Chemical Properties

Appearance
Water-white liquid with a penetrating fruity odor.
Solubility in water
0.43 g/100 mL.
Melting Point
-35
Boiling Point
150
Vapor Pressure
3
Density
0.8111 g/cm3
Partition Coefficient
1.98
Heat Of Vaporization
46.10 kJ/mol
Usage
Industrial solvent, solvent for synthetic resin finishes, fragrance ingredient in creams, lotions, perfumes, soaps & detergents, flavor ingredient in foods, inert reaction medium.
Vapor Density
3.9
Saturation Concentration
2,100 ppm at 25 C; 2,760 ppm at 25 C (calculated)
Odor threshold
About 0.020 ppm
Refractive Index
1.40935 (15 C)

First Aid Measures

Ingestion
If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation
Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Skin
Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Remove contaminated clothing and shoes.
Eyes
Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.

Handling and Storage

Storage
Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Flammables-area.
Handling
Wash thoroughly after handling. Use only in a well ventilated area. Ground and bond containers when transferring material. Use spark-proof tools and explosion proof equipment. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Avoid contact with heat, sparks and flame. Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.

Hazards Identification

Inhalation
May cause respiratory tract irritation. Vapors may cause dizziness or suffocation.
Skin
May cause skin irritation.
Eyes
May cause eye irritation.
Ingestion
Ingestion of large amounts may cause gastrointestinal irritation.
Hazards
Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers.
EC Risk Phrase
R 10 20/22
EC Safety Phrase
S 24/25
UN (DOT)
1110

Exposure Controls/Personal Protection

Personal Protection
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators
Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
Exposure Effects
Limited studies have generally documented little or no effect of ketones on reproduction in experimental animals. Human data is lacking. 2,5-Hexanedione has an effect on spermatogenesis in male experimental animals.
Exposure limit(s)
TLV: 50 ppm; 233 mg/m3 (ACGIH 1995-1996). OSHA PEL: TWA 100 ppm (465 mg/m3) NIOSH REL: TWA 100 ppm (465 mg/m3) NIOSH IDLH: 800 ppm
Poison Class
4

Fire Fighting Measures

Flash Point
49
Autoignition
532
Fire Fighting
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Will burn if involved in a fire. Use water spray to keep fire-exposed containers cool. Containers may explode in the heat of a fire. Extinguishing media: For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam. For large fires, use water spray, fog, or alcohol-resistant foam. In case of fire, use water, dry chemical, chemical foam, or alcohol-resistant foam. Use water spray to cool fire-exposed containers. Water may be ineffective. Use agent most appropriate to extinguish fire. Do NOT use straight streams of water.
Upper exp. limit
5.5
Lower exp. limit
1
Fire Potential
Moderate when exposed to heat or flame

Accidental Release Measures

Small spills/leaks
Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Clean up spills immediately, using the appropriate protective equipment. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation. A vapor suppressing foam may be used to reduce vapors.

Stability and Reactivity

Disposal Code
1
Stability
Stable under normal temperatures and pressures.
Incompatibilities
Strong oxidizing agents, strong acids, bases.
Decomposition
Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
Combustion Products
Irritating vapors and toxic gases, such as carbon dioxide and carbon monoxide, may be formed when involved in fire.

Transport Information

UN Number
1110
Hazard Class
3
Packing Group
III
HS Code
2914 19 90
Contact More