Supplier Product Identification Physical and Chemical Properties First Aid Measures Handling and Storage Hazards Identification Exposure Controls/Personal Protection Fire Fighting Measures Accidental Release Measures Stability and Reactivity Transport Information
Home > 2-(6-Hydroxy-3-oxo-(3H)-xanthen-9-yl)benzoic acid > 2-(6-Hydroxy-3-oxo-(3H)-xanthen-9-yl)benzoic acid(2321-07-5)

2-(6-Hydroxy-3-oxo-(3H)-xanthen-9-yl)benzoic acid(2321-07-5)

Supplier Product Identification Physical and Chemical Properties First Aid Measures Handling and Storage Hazards Identification Exposure Controls/Personal Protection Fire Fighting Measures Accidental Release Measures Stability and Reactivity Transport Information

Product Identification

Product Name
2-(6-Hydroxy-3-oxo-(3H)-xanthen-9-yl)benzoic acid
Synonyms
(1R)-Fenchone
1,3,3-Trimethylnorbornan-2-one
1R,4S)-1,3,3-Trimethylbicyclo[2.2.1]heptan-2-one
3,6-Fluorandiol
9-(o-Carboxyphenyl)-6-hydroxy-3-isoxanthenone
Bicyclo[2.2.1]heptan-2-one, 1,3,3-trimethyl-, (1R)-
Bicyclo[2.2.1]heptan-2-one, 1,3,3-trimethyl-, (1R,4S)-
Dihydroxyfluorane
CAS
2321-07-5
CAS
7787-20-4
Formula
C10H16O
Formula
C20H12O5
Molecular Weight
332.31
Molecular Weight
152.22999999999999
EINECS
219-031-8
EINECS
232-107-5
RTECS
LM5075000
RTECS
RB7875000
RTECS Class
Mutagen; Human Data; Primary Irritant
Merck
13,4185
Beilstein/Gmelin
2042710
Beilstein/Gmelin
94324
Beilstein Reference
4-07-00-00212
Beilstein Reference
5-19-06-00456

Physical and Chemical Properties

Appearance
Clear, colorless liquid.
Appearance
Latter have greenish-yellow fluorescence by reflected light. Very dilute alkaline solutions exhibit intense, greenish-yellow fluorescence by reflected light.
Solubility in water
Insoluble
Melting Point
314-316
Melting Point
8.5
Boiling Point
192
Density
0.962 g/cm3 (0 C)
pKa/pKb
2.2, 4.4, 6.7(at 25℃) (pKa)
Heat Of Vaporization
51.1 kJ/mol
Usage
Used as a flavor in foods and in perfumery.
Usage
Yellow dye for cosmetics, cleansers & other household products, tracing agent for water leaks, dye to detect water pollution sources, adsorption indicator, stic agent in ophthalmology (sodium salt), chemical intermediate for dyes.
Refractive Index
1.46355

First Aid Measures

Ingestion
If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Ingestion
If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated. Vapors may cause dizziness or suffocation.
Inhalation
Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Inhalation
Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Skin
May cause skin irritation. The toxicological properties of this material have not been fully investigated.
Skin
Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists.
Skin
Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Eyes
May cause eye irritation. The toxicological properties of this material have not been fully investigated.
Eyes
Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Eyes
Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.

Handling and Storage

Storage
Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Flammables-area.
Storage
Store in a cool, dry place. Keep container closed when not in use.
Handling
Wash thoroughly after handling. Use with adequate ventilation. Ground and bond containers when transferring material. Use spark-proof tools and explosion proof equipment. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Avoid contact with heat, sparks and flame. Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Handling
Wash thoroughly after handling. Wash hands before eating. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Avoid ingestion and inhalation.

Hazards Identification

Ingestion
May cause gastrointestinal irritation with nausea, vomiting and diarrhea. The toxicological properties of this substance have not been fully investigated.
Inhalation
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
Skin
May cause skin irritation. Prolonged and/or repeated contact may cause irritation and/or dermatitis.
Eyes
May cause eye irritation. This product contains an anionic dye. Similar dyes have not caused injury to the cornea or conjunctiva in documented exposure cases with human or rabbit eyes.
Hazards
Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers.
EC Risk Phrase
R 10
EC Safety Phrase
S 22 24/25
EC Safety Phrase
S 24/25
UN (DOT)
1224

Exposure Controls/Personal Protection

Personal Protection
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators
Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
Poison Class
4

Fire Fighting Measures

Flash Point
52
Fire Fighting
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. To extinguish fire, use water, dry chemical, chemical foam, or alcohol-resistant foam.
Fire Fighting
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Will burn if involved in a fire. Use water spray to keep fire-exposed containers cool. Containers may explode in the heat of a fire. Extinguishing media: For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam. For large fires, use water spray, fog, or alcohol-resistant foam. Use water spray to cool fire-exposed containers. Water may be ineffective. Do NOT use straight streams of water.
Fire Potential
HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames.
Fire Potential
Slight fire hazard.

Accidental Release Measures

Small spills/leaks
Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Clean up spills immediately, using the appropriate protective equipment. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation. A vapor suppressing foam may be used to reduce vapors.
Small spills/leaks
Vacuum or sweep up material and place into a suitable disposal container. Reduce airborne dust and prevent scattering by moistening with water. Clean up spills immediately, using the appropriate protective equipment.

Stability and Reactivity

Incompatibilities
Oxidizing agents.
Stability
Stable under normal temperatures and pressures.
Incompatibilities
Strong oxidizing agents.
Decomposition
Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
Combustion Products
Fire may produce irritating, corrosive and/or toxic gases.

Transport Information

UN Number
1224
Hazard Class
3
Packing Group
I; II; III
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