Supplier Product Identification Physical and Chemical Properties First Aid Measures Handling and Storage Hazards Identification Exposure Controls/Personal Protection Fire Fighting Measures Accidental Release Measures Stability and Reactivity Transport Information
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FMOC-Chloride(28920-43-6)

Supplier Product Identification Physical and Chemical Properties First Aid Measures Handling and Storage Hazards Identification Exposure Controls/Personal Protection Fire Fighting Measures Accidental Release Measures Stability and Reactivity Transport Information

Product Identification

Product Name
FMOC-Chloride
Synonyms
9-Fluorenylmethoxycarbonyl chloride
9-Fluorenylmethyl chlorocarbonate
AminoTag
Carbonochloridic acid, 9H-fluoren-9-ylmethyl ester
FMOC chloride
Formic acid, chloro, fluoren-9-ylmethyl ester
CAS
28920-43-6
Formula
C15H11ClO2
Molecular Weight
258.70999999999998
EINECS
249-313-6
RTECS
LQ6250000
RTECS Class
Mutagen
Beilstein/Gmelin
2279177
EC Class
corrosive

Physical and Chemical Properties

Appearance
White solid.
Solubility in water
Insoluble
Melting Point
60 - 63

First Aid Measures

Ingestion
May cause methemoglobinemia, cyanosis, convulsions, and death. Get medical aid if irritation or symptoms occur.
Inhalation
Get medical aid immediately. Remove from exposure to fresh air immediately.
Skin
Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.
Eyes
Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.

Handling and Storage

Storage
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Refrigerator (approx 4 C).
Handling
Wash thoroughly after handling. Use with adequate ventilation. Do not get in eyes, on skin, or on clothing. Do not ingest or inhale.

Hazards Identification

Ingestion
May cause severe gastrointestinal tract irritation with nausea, vomiting and possible burns.
Inhalation
May cause severe irritation of the respiratory tract with sore throat, coughing, shortness of breath and delayed lung edema. Causes chemical burns to the respiratory tract.
Skin
May cause severe irritation and possible burns.
Eyes
Contact with eyes may cause severe irritation, and possible eye burns.
Hazards
Contact with metals may evolve flammable hydrogen gas.
EC Risk Phrase
R 20/22 34
EC Safety Phrase
S 26 36/37/39 45
UN (DOT)
1759

Exposure Controls/Personal Protection

Personal Protection
Eyes: Wear safety glasses and chemical goggles if splashing is possible. Skin: Wear appropriate protective gloves and clothing to prevent skin exposure. Clothing: Wear appropriate protective clothing to minimize contact with skin.
Respirators
Wear a NIOSH/MSHA or European Standard EN 149 approved full-facepiece airline respirator in the positive pressure mode with emergency escape provisions.

Fire Fighting Measures

Fire Fighting
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing media: Do NOT use water directly on fire. Use foam, dry chemical, or carbon dioxide.
Fire Potential
Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes.

Accidental Release Measures

Small spills/leaks
Sweep up, then place into a suitable container for disposal.

Stability and Reactivity

Disposal Code
11
Incompatibilities
Acids - strong bases - alcohols - amines - moist air or water.
Stability
Stable under normal temperatures and pressures.
Decomposition
Hydrogen chloride, phosgene, carbon monoxide, carbon dioxide.
Combustion Products
Fire may produce irritating, corrosive and/or toxic gases.

Transport Information

UN Number
1759
Hazard Class
8
Packing Group
I; II; III
HS Code
2915 90 20
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