Supplier Product Identification Physical and Chemical Properties First Aid Measures Handling and Storage Hazards Identification Exposure Controls/Personal Protection Fire Fighting Measures Accidental Release Measures Stability and Reactivity Transport Information
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2,6-Dibromo-4-nitroaniline(827-94-1)

Supplier Product Identification Physical and Chemical Properties First Aid Measures Handling and Storage Hazards Identification Exposure Controls/Personal Protection Fire Fighting Measures Accidental Release Measures Stability and Reactivity Transport Information

Product Identification

Product Name
2,6-Dibromo-4-nitroaniline
Synonyms
2,6-Dibromo-p-nitroaniline
Benzenamine, 2,6-dibromo-4-nitro-
CAS
827-94-1
Formula
C6H4Br2N2O2
Molecular Weight
295.92
EINECS
212-577-8
RTECS
BX2599000
RTECS Class
Other
Beilstein/Gmelin
2110915
Beilstein Reference
3-12-00-01678

Physical and Chemical Properties

Appearance
Yellow needles from alcohol or acetic acid.
Solubility in water
Insoluble
Melting Point
204-209
Partition Coefficient
2.79

First Aid Measures

Ingestion
Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation
Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid if cough or other symptoms appear.
Skin
Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists.
Eyes
Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.

Handling and Storage

Storage
Store in a cool, dry place. Store in a tightly closed container.
Handling
Wash thoroughly after handling. Wash hands before eating. Use with adequate ventilation. Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Avoid ingestion and inhalation.

Hazards Identification

Inhalation
Causes respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
Skin
Causes skin irritation.
Eyes
Causes eye irritation.
Ingestion
May cause gastrointestinal irritation with nausea, vomiting and diarrhea. The toxicological properties of this substance have not been fully investigated.
Hazards
Contact with metals may evolve flammable hydrogen gas.
EC Risk Phrase
R 20/21/22 33
EC Safety Phrase
S 22 36/37
UN (DOT)
2811

Exposure Controls/Personal Protection

Personal Protection
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators
Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
Exposure Effects
CNS effects include headache, dizziness, altered mental status, confusion (lethargy progressing coma), seizures, syncope; occur secondary to CNS hypoxia, usually with levels > 20%.
Exposure limit(s)
NIOSH: Potential Occupational Carcinogen.

Fire Fighting Measures

Fire Fighting
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. To extinguish fire use water spray, dry chemical, carbon dioxide, or chemical foam.
Fire Potential
Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes.

Accidental Release Measures

Small spills/leaks
Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, using the appropriate protective equipment.

Stability and Reactivity

Incompatibilities
Acids, acid chlorides, chloroformates, and strong oxidizing agents.
Stability
Stable under normal temperatures and pressures.
Decomposition
Carbon monoxide, oxides of nitrogen, carbon dioxide, hydrogen bromide.
Combustion Products
Fire may produce irritating, corrosive and/or toxic gases.

Transport Information

UN Number
2811
Hazard Class
6.1
Packing Group
I; II; III
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