Product Identification Physical and Chemical Properties First Aid Measures Handling and Storage Hazards Identification Exposure Controls/Personal Protection Fire Fighting Measures Accidental Release Measures Stability and Reactivity Transport Information
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1,1,1-Trifluoroethane(420-46-2)

Product Identification Physical and Chemical Properties First Aid Measures Handling and Storage Hazards Identification Exposure Controls/Personal Protection Fire Fighting Measures Accidental Release Measures Stability and Reactivity Transport Information

Product Identification

Product Name
1,1,1-Trifluoroethane
Synonyms
Freon 143a
Methylfluoroform
CAS
420-46-2
Formula
C2H3F3
Molecular Weight
84.05
EINECS
206-996-5
RTECS
KJ4110000
RTECS Class
Mutagen; Reproductive Effector
Beilstein/Gmelin
1731552
Beilstein Reference
4-01-00-00122

Physical and Chemical Properties

Appearance
Clear, colorless liquid or vapor with a faint ether odor.
Solubility in water
Insoluble
Melting Point
-111.34
Boiling Point
-50
Vapor Pressure
2400
Density
0.942 g/cm3 (20 C)
Heat Of Vaporization
15.93 kJ/mol
Usage
Refrigerant gas.
Vapor Density
2.92

First Aid Measures

Ingestion
Seek medical assistance.
Inhalation
Move victim to fresh air. Apply artificial respiration if victim is not breathing. Administer oxygen if breathing is difficult.
Skin
Remove and isolate contaminated clothing and shoes. Clothing frozen to the skin should be thawed before being removed. In case of contact with liquefied gas, thaw frosted parts with lukewarm water
Eyes
Flush with running water for at least 20 minutes.

Handling and Storage

Storage
Store in a clean, dry place. Keep cool.
Handling
Should not be used for any purpose above atmospheric pressure. Use with sufficient ventilation. Do not mix with air.

Hazards Identification

Inhalation
Vapors may cause dizziness or asphyxiation without warning. Some may be irritating if inhaled at high concentrations.
Skin
Contact with gas or liquefied gas may cause burns, severe injury and/or frostbite.
Eyes
May cause irritation.
Ingestion
Unlikely route of exposure.
Hazards
Vapors from liquefied gas are initially heavier than air and spread along ground. Vapors may travel to source of ignition and flash back. Containers may explode when heated. Ruptured cylinders may rocket.
EC Risk Phrase
R 11
EC Safety Phrase
S 16 33
UN (DOT)
2035

Exposure Controls/Personal Protection

Personal Protection
Wear appropriate protective gloves, clothing and goggles. Always wear thermal protective clothing when handling refrigerated/cryogenic liquids.
Respirators
Wear positive pressure self-contained breathing apparatus (SCBA).
Exposure Effects
The toxological properties of this substance have not been fully investigated.
Poison Class
-

Fire Fighting Measures

Fire Fighting
Do not extinguish fire unless flow can be stopped. Use water in flooding quantities as fog. Solid streams of water may be ineffective. Cool all affected containers with flooding quantities of water. Apply water from as far a distance as possible.
Upper exp. limit
20.5
Fire Potential
EXTREMELY FLAMMABLE.

Accidental Release Measures

Small spills/leaks
Keep sparks, flames, and other sources of ignition away. Keep material out of water sources and sewers. Attempt to stop leak if without undue personnel hazard. Use water spray to knock-down vapors.

Stability and Reactivity

Incompatibilities
Can react with some metals to form dangerous products Incompatible with strong oxidizing and reducing agents Incompatible with many amines, nitrides, azo/diazo compounds, alkali metals, and epoxides.
Stability
Stable at normal temperatures and pressures.
Decomposition
Oxides of carbon, hydrogen fluoride.

Transport Information

UN Number
2035
Hazard Class
2.1