Supplier Product Identification Physical and Chemical Properties First Aid Measures Handling and Storage Hazards Identification Exposure Controls/Personal Protection Fire Fighting Measures Accidental Release Measures Stability and Reactivity Transport Information
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Bromoacetic acid ethyl ester(105-36-2)

Supplier Product Identification Physical and Chemical Properties First Aid Measures Handling and Storage Hazards Identification Exposure Controls/Personal Protection Fire Fighting Measures Accidental Release Measures Stability and Reactivity Transport Information

Product Identification

Product Name
Bromoacetic acid ethyl ester
Synonyms
(Ethoxycarbonyl)methyl bromide
3-Methylbenzenesulfonic acid
Acetic acid, bromo-, ethyl ester
Antol
Ethyl 2-bromoethanoate
Ethyl bromoethanoate
m-Methylbenzenesulfonic acid
thyl monobromoacetate
CAS
105-36-2
CAS
617-97-0
Formula
C4H7BrO2
Formula
C7H8O3S
Molecular Weight
167.01
Molecular Weight
172.2
EINECS
203-290-9
RTECS
AF6000000
RTECS Class
Tumorigen
Beilstein/Gmelin
506456
Beilstein/Gmelin
2208421
Beilstein Reference
4-02-00-00527
Beilstein Reference
4-11-00-00237
EC Index Number
607-069-00-1
EC Class
Very toxic

Physical and Chemical Properties

Appearance
Clear, colorless liquid, pungent, irritating odor, lachrymator.
Solubility in water
Insoluble
Solubility in water
Very soluble
Melting Point
-38
Boiling Point
159
Boiling Point
160 - 170 (0.1 torr)
Vapor Pressure
2.6
Density
1.5282 g/cm3 (4 C)
Partition Coefficient
.93
Partition Coefficient
1.12
Heat Of Vaporization
Usage
Has been employed as tear gas.
Vapor Density
5.8
Saturation Concentration
3422 ppm (0.34%) at 25 C (calculated)
Refractive Index
1.4516 (13 C)
Refractive Index
1.53 (20 C)

First Aid Measures

Ingestion
If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Ingestion
Seek medical assistance.
Inhalation
TOXIC; inhalation, ingestion, or skin contact with material may cause severe injury or death. Effects of contact or inhalation may be delayed.
Inhalation
Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Inhalation
Move victim to fresh air. Apply artificial respiration if victim is not breathing. Do not use mouth-to-mouth method if victim ingested or inhaled the substance; induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Administer oxygen if breathing is difficult.
Skin
Get medical aid immediately. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Skin
Remove and isolate contaminated clothing and shoes. Immediately flush with running water for at least 20 minutes. For minor skin contact, avoid spreading material on unaffected skin.
Skin
Contact with molten substance may cause severe burns to skin and eyes. See Inhalation.
Eyes
Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Eyes
See Inhalation.
Eyes
Immediately flush with running water for at least 20 minutes.

Handling and Storage

Storage
Keep away from heat, sparks, and flame. Keep away from sources of ignition. Keep container closed when not in use. Store in a cool, dry, well-ventilated area away from incompatible substances. Flammables-area.
Handling
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use only in a well ventilated area. Ground and bond containers when transferring material. Use spark-proof tools and explosion proof equipment. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.

Hazards Identification

Ingestion
See Inhalation.
Inhalation
May cause respiratory tract irritation. Vapors may cause dizziness or suffocation.
Skin
Causes severe skin irritation. May be absorbed through the skin.
Eyes
Causes severe eye irritation. May cause opacity and scarring. Lachrymator.
Ingestion
Causes gastrointestinal irritation with nausea, vomiting and diarrhea.
Hazards
Vapors form explosive mixtures with air: indoors, outdoors, and sewers explosion hazards. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapors may travel to source of ignition and flash back. Substance will react with water (some violently) releasing flammable, toxic or corrosive gases and runoff. Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated or if contaminated with water.
Hazards
When heated, vapors may form explosive mixtures with air: indoors, outdoors, and sewers explosion hazards.
EC Risk Phrase
R 26/27/28
EC Risk Phrase
R 34
EC Safety Phrase
S 26 36/37/39 45
EC Safety Phrase
S 7/9 26 45
UN (DOT)
1603
UN (DOT)
2586

Exposure Controls/Personal Protection

Personal Protection
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
Personal Protection
Wear appropriate protective gloves, clothing and goggles.
Respirators
Wear positive pressure self-contained breathing apparatus (SCBA).
Respirators
Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
Exposure Effects
Agitation and syncope, both attributed to panic, have been reported.
Poison Class
1

Fire Fighting Measures

Flash Point
50
Fire Fighting
Small Fires: Dry chemical, carbon dioxide or water spray. Large Fires: Dry chemical, carbon dioxide, alcohol-resistant foam or water spray.
Fire Fighting
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. To extinguish fire use water fog, dry chemical, carbon dioxide or alcohol type foam.
Fire Potential
Combustible material: may burn but does not ignite readily.
Fire Potential
HIGHLY FLAMMABLE.

Accidental Release Measures

Small spills/leaks
Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation.
Small spills/leaks
ELIMINATE all ignition sources. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Stop leak if you can do it without risk. Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. DO NOT GET WATER INSIDE CONTAINERS.

Stability and Reactivity

Disposal Code
9
Incompatibilities
Oxidizing agents, reducing agents, acids, bases.
Stability
Stable under normal temperatures and pressures.
Decomposition
Carbon monoxide, carbon dioxide, hydrogen bromide.
Combustion Products
Fire may produce irritating, corrosive and/or toxic gases.
Combustion Products
Fire will produce irritating, corrosive and/or toxic gases.

Transport Information

UN Number
1603
UN Number
2586
Hazard Class
6.1
Packing Group
II
HS Code
2915 90 80
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