Supplier Product Identification Physical and Chemical Properties First Aid Measures Hazards Identification Exposure Controls/Personal Protection Fire Fighting Measures Accidental Release Measures Stability and Reactivity Transport Information
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DEAD(1972-28-7)

Supplier Product Identification Physical and Chemical Properties First Aid Measures Hazards Identification Exposure Controls/Personal Protection Fire Fighting Measures Accidental Release Measures Stability and Reactivity Transport Information

Product Identification

Product Name
DEAD
Synonyms
DAD
DEAD
Diethyl azidoformate
Ethyl (NE)-N-ethoxycarbonyliminocarbamate
CAS
1972-28-7
Formula
C6H10N2O4
Molecular Weight
174.16
EINECS
217-821-7
Beilstein/Gmelin
908662
Beilstein Reference
3-03-00-00233

Physical and Chemical Properties

Appearance
Red orange liquid
Boiling Point
106
Density
1.11 g/cm3 (19.2 C)
Usage
An efficient component in diels-alder reactions.
Refractive Index
1.42 (20 C)

First Aid Measures

Ingestion
Seek medical assistance.
Inhalation
Move victim to fresh air. Apply artificial respiration if victim is not breathing. Do not use mouth-to-mouth method if victim ingested or inhaled the substance; induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Administer oxygen if breathing is difficult.
Skin
Remove and isolate contaminated clothing and shoes. Immediately flush with running water for at least 20 minutes. For minor skin contact, avoid spreading material on unaffected skin.
Eyes
Immediately flush with running water for at least 20 minutes.

Hazards Identification

Ingestion
See Inhalation.
Inhalation
TOXIC; inhalation, ingestion, or skin contact with material may cause severe injury or death. Effects of contact or inhalation may be delayed.
Skin
Contact with molten substance may cause severe burns to skin and eyes. See Inhalation.
Eyes
See Inhalation.
Hazards
When heated, vapors may form explosive mixtures with air: indoors, outdoors, and sewers explosion hazards.
EC Risk Phrase
R 5 20 36/37/38
EC Safety Phrase
S 15 26 36
UN (DOT)
2810

Exposure Controls/Personal Protection

Personal Protection
Wear appropriate protective gloves, clothing and goggles.
Respirators
Wear positive pressure self-contained breathing apparatus (SCBA).

Fire Fighting Measures

Flash Point
85
Fire Fighting
Small Fires: Dry chemical, carbon dioxide or water spray. Large Fires: Dry chemical, carbon dioxide, alcohol-resistant foam or water spray.
Fire Potential
Combustible material: may burn but does not ignite readily.

Accidental Release Measures

Small spills/leaks
ELIMINATE all ignition sources. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Stop leak if you can do it without risk. Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. DO NOT GET WATER INSIDE CONTAINERS.

Stability and Reactivity

Stability
DEAD is toxic, shock sensitive, and thermally unstable.
Combustion Products
Fire may produce irritating, corrosive and/or toxic gases.

Transport Information

UN Number
2810
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