Home > Ethyl trifluoroacetate > Ethyl trifluoroacetate(383-63-1)
Ethyl trifluoroacetate(383-63-1)
Supplier Product Identification
Physical and Chemical Properties
First Aid Measures
Handling and Storage
Hazards Identification
Exposure Controls/Personal Protection
Fire Fighting Measures
Accidental Release Measures
Stability and Reactivity
Transport Information
Product Identification
Product Name
Ethyl trifluoroacetate
Ethyl trifluoroacetate
Synonyms
Acetic acid, trifluoro-, ethyl ester
Ethyl 2,2,2-trifluoroacetate
Ethyl perfluoroacetate
Trifluoroacetic acid ethyl ester
Acetic acid, trifluoro-, ethyl ester
Ethyl 2,2,2-trifluoroacetate
Ethyl perfluoroacetate
Trifluoroacetic acid ethyl ester
CAS
383-63-1
383-63-1
Formula
C4H5F3O2
C4H5F3O2
Molecular Weight
142.08000000000001
142.08000000000001
EINECS
206-851-6
206-851-6
Beilstein/Gmelin
1761411
1761411
Beilstein Reference
4-02-00-00463
4-02-00-00463
EC Class
highly flammable, corrosive
highly flammable, corrosive
Physical and Chemical Properties
Appearance
Clear, colorless liquid.
Clear, colorless liquid.
Solubility in water
Slightly soluble
Slightly soluble
Melting Point
-78
-78
Boiling Point
61
61
Vapor Pressure
185 (25 C)
185 (25 C)
Density
1.1953 g/cm3 (16.7 C)
1.1953 g/cm3 (16.7 C)
Partition Coefficient
1.03
1.03
Heat Of Vaporization
30.4 kJ/mol
30.4 kJ/mol
Vapor Density
4.9
4.9
Refractive Index
1.308 (20 C)
1.308 (20 C)
First Aid Measures
Ingestion
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation
Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Skin
Get medical aid. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Get medical aid. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Eyes
Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Handling and Storage
Storage
Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Flammables-area.
Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Flammables-area.
Handling
Wash thoroughly after handling. Use with adequate ventilation. Ground and bond containers when transferring material. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Avoid contact with heat, sparks and flame. Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Wash thoroughly after handling. Use with adequate ventilation. Ground and bond containers when transferring material. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Avoid contact with heat, sparks and flame. Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Hazards Identification
Ingestion
May cause gastrointestinal irritation with nausea, vomiting and diarrhea. The toxicological properties of this substance have not been fully investigated.
May cause gastrointestinal irritation with nausea, vomiting and diarrhea. The toxicological properties of this substance have not been fully investigated.
Inhalation
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated. Vapors may cause dizziness or suffocation.
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated. Vapors may cause dizziness or suffocation.
Skin
May cause skin irritation. The toxicological properties of this material have not been fully investigated.
May cause skin irritation. The toxicological properties of this material have not been fully investigated.
Eyes
May cause eye irritation. The toxicological properties of this material have not been fully investigated.
May cause eye irritation. The toxicological properties of this material have not been fully investigated.
Hazards
Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers.
Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers.
EC Risk Phrase
R 11 34
R 11 34
EC Safety Phrase
S 16 23 26 36/37/39 45
S 16 23 26 36/37/39 45
UN (DOT)
1993
1993
Exposure Controls/Personal Protection
Personal Protection
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators
Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
Fire Fighting Measures
Flash Point
-1
-1
Fire Fighting
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. Containers may explode in the heat of a fire. Will be easily ignited by heat, sparks or flame. Extinguishing media: For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam. For large fires, use water spray, fog, or alcohol-resistant foam. Use water spray to cool fire-exposed containers. Water may be ineffective. Do NOT use straight streams of water.
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. Containers may explode in the heat of a fire. Will be easily ignited by heat, sparks or flame. Extinguishing media: For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam. For large fires, use water spray, fog, or alcohol-resistant foam. Use water spray to cool fire-exposed containers. Water may be ineffective. Do NOT use straight streams of water.
Fire Potential
HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames.
HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames.
Accidental Release Measures
Small spills/leaks
Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Clean up spills immediately, using the appropriate protective equipment. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation. A vapor suppressing foam may be used to reduce vapors.
Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Clean up spills immediately, using the appropriate protective equipment. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation. A vapor suppressing foam may be used to reduce vapors.
Stability and Reactivity
Disposal Code
2
2
Incompatibilities
Oxidizing agents.
Oxidizing agents.
Stability
Stable under normal temperatures and pressures.
Stable under normal temperatures and pressures.
Decomposition
Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, hydrogen fluoride.
Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, hydrogen fluoride.
Combustion Products
Fire may produce irritating, corrosive and/or toxic gases.
Fire may produce irritating, corrosive and/or toxic gases.
Transport Information
UN Number
1993
1993
Hazard Class
3
3
Packing Group
I; II; III
I; II; III
HS Code
2915 90 80
2915 90 80
Contact
More
- Company Name:SHANGHAI BANGCHENG CHEMICAL Co.,Ltd.
- Tel:021-69106960 13701823733
- Fax:021-69106780
- WebSite:http://www.bangchengchem.com/
- Company Name:XIANJU DOEASTCHEM Co., Ltd.
- Tel:0576-87788985 13586230158
- Fax:
- WebSite:http://www.doeastpharm.com/
- Company Name:Shandong Zhanhua Yonghao Pharmaceutical Technology Co., Ltd
- Tel:0576-88685096 13989620089
- Fax:0086-576-88685099
- WebSite:http://www.yongfengchemical.com/
- Company Name:Shanghai Kaisai Chemical Co., Ltd
- Tel:021-33516722 13701817765
- Fax:021-33516776
- WebSite:http://www.kaisaichem.com
- Company Name:Energy Chemical
- Tel:021-021-58432009 400-005-6266
- Fax:021-58436166
- WebSite:http://www.energy-chemical.com