Supplier Product Identification Physical and Chemical Properties First Aid Measures Handling and Storage Hazards Identification Exposure Controls/Personal Protection Fire Fighting Measures Accidental Release Measures Stability and Reactivity Transport Information
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Tetrabutyl titanate(5593-70-4)

Supplier Product Identification Physical and Chemical Properties First Aid Measures Handling and Storage Hazards Identification Exposure Controls/Personal Protection Fire Fighting Measures Accidental Release Measures Stability and Reactivity Transport Information

Product Identification

Product Name
Tetrabutyl titanate
Synonyms
Butyl orthotitanate
Butyl titanate monomer
Butyl titanate(IV)
Butyl titanate(Iv) ((Buo)4ti)
NSC 220232
Tetrabutoxytitanium
CAS
5593-70-4
Formula
C16H36O4Ti
Molecular Weight
340.36
EINECS
227-006-8
RTECS
XR1585000
RTECS Class
Other
Beilstein/Gmelin
4148236
Beilstein Reference
4-01-00-01514
EC Class
flammable, irritant

Physical and Chemical Properties

Appearance
Clorless to light-yellow liquid. Weak, alcohol-like odor.
Solubility in water
Slow decomposition
Melting Point
-55
Boiling Point
310
Vapor Pressure
11 (20 C)
Density
0.993 g/cm3 (20 C)
Heat Of Vaporization
112.4 kJ/mol
Heat Of Combustion
-11524 kJ/mol
Usage
Ester exchange reactions, heat-resistant paints (up to 500 deg c), improving adhesion of paints, rubber, and plastics to metal surfaces, cross linking agent, condensation catalyst.
Vapor Density
11.7
Refractive Index
1.4921 (20 C)

First Aid Measures

Ingestion
If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation
Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Skin
Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.
Eyes
Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.

Handling and Storage

Storage
Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
Handling
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Avoid contact with heat, sparks and flame. Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.

Hazards Identification

Inhalation
Causes respiratory tract irritation.
Skin
Causes skin irritation.
Eyes
Causes eye irritation. Contact with the eyes may cause corneal damage.
Ingestion
May cause central nervous system effects. Causes digestive tract irritation.
Hazards
Containers may explode in fire. May give off dense white smoke. Containers may explode.
EC Risk Phrase
R 36/38
EC Safety Phrase
S 26 36
UN (DOT)
1830

Exposure Controls/Personal Protection

Personal Protection
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators
Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
Exposure Effects
Headache, dizziness, giddiness, ataxia, sedation and coma may occur.
Poison Class
-

Fire Fighting Measures

Flash Point
47
Fire Fighting
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. Combustible Liquid. Containers may explode when heated. Extinguishing media: Do NOT use water directly on fire. Use water spray to cool fire-exposed containers. Use carbon dioxide or dry chemical.
Fire Potential
This material is combustible.

Accidental Release Measures

Small spills/leaks
Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Clean up spills immediately, using the appropriate protective equipment. Remove all sources of ignition. Provide ventilation.

Stability and Reactivity

Disposal Code
13
Stability
Stable under normal temperatures and pressures.
Incompatibilities
Strong oxidizing agents - strong acids.
Decomposition
Carbon monoxide, carbon dioxide, titanium/titanium oxides.
Combustion Products
Fire will produce irritating, corrosive and/or toxic gases. Reaction with water may generate much heat which will increase the concentration of fumes in the air.

Transport Information

UN Number
1830
Hazard Class
8
Packing Group
II
HS Code
2905 19 00
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