Home > 4-Nitrophenol sodium salt > 4-Nitrophenol sodium salt(824-78-2)
4-Nitrophenol sodium salt(824-78-2)
Product Identification
Physical and Chemical Properties
First Aid Measures
Handling and Storage
Hazards Identification
Exposure Controls/Personal Protection
Fire Fighting Measures
Accidental Release Measures
Stability and Reactivity
Product Identification
Product Name
4-Nitrophenol sodium salt
4-Nitrophenol sodium salt
Synonyms
para-Nitro sodium phenolate
Sodium 4-Nitrophenolate
Sodium nitrophenate
Sodium p-Nitrophenol
Sodium p-Nitrophenolate
Sodium p-Nitrophenoxide
para-Nitro sodium phenolate
Sodium 4-Nitrophenolate
Sodium nitrophenate
Sodium p-Nitrophenol
Sodium p-Nitrophenolate
Sodium p-Nitrophenoxide
CAS
824-78-2
824-78-2
Formula
C6H4NNaO3
C6H4NNaO3
Molecular Weight
161.09
161.09
EINECS
212-536-4
212-536-4
RTECS
SM4800000
SM4800000
RTECS Class
Other
Other
Beilstein/Gmelin
3598721
3598721
Beilstein Reference
4-06-00-01279
4-06-00-01279
Physical and Chemical Properties
Appearance
Yellow crystalline solid.
Yellow crystalline solid.
Solubility in water
soluble
soluble
Melting Point
300
300
Usage
Parathion & methylparathion are made by chlorinating the appropriate dialkyl dithiophosphate and subsequent reaction of the intermediate dialkyl thiophosphoric chloride with sodium p-nitrophenolate.
Parathion & methylparathion are made by chlorinating the appropriate dialkyl dithiophosphate and subsequent reaction of the intermediate dialkyl thiophosphoric chloride with sodium p-nitrophenolate.
Odor threshold
Odor threshold:2.3 mg/m3
Odor threshold:2.3 mg/m3
First Aid Measures
Ingestion
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation
Remove from exposure to fresh air immediately. If breathing is difficult, give oxygen. Get medical aid. DO NOT use mouth-to-mouth respiration. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
Remove from exposure to fresh air immediately. If breathing is difficult, give oxygen. Get medical aid. DO NOT use mouth-to-mouth respiration. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
Skin
Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Eyes
Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Handling and Storage
Storage
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Store protected from moisture.
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Store protected from moisture.
Handling
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use with adequate ventilation. Do not allow contact with water. Wash clothing before reuse. Keep from contact with moist air and steam.
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use with adequate ventilation. Do not allow contact with water. Wash clothing before reuse. Keep from contact with moist air and steam.
Hazards Identification
Inhalation
Causes respiratory tract irritation. Can produce delayed pulmonary edema.
Causes respiratory tract irritation. Can produce delayed pulmonary edema.
Skin
Causes skin irritation.
Causes skin irritation.
Eyes
Causes eye irritation. May cause chemical conjunctivitis.
Causes eye irritation. May cause chemical conjunctivitis.
Ingestion
Harmful if swallowed. May cause gastrointestinal irritation with nausea, vomiting and diarrhea.
Harmful if swallowed. May cause gastrointestinal irritation with nausea, vomiting and diarrhea.
Exposure Controls/Personal Protection
Personal Protection
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators
Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
Exposure Effects
Effects may be delayed.
Effects may be delayed.
Fire Fighting Measures
Flash Point
90
90
Fire Fighting
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Dusts may be combustible when exposed to heat, flame, or oxidizing agents. Runoff from fire control or dilution water may cause pollution. Extinguishing media: Use agent most appropriate to extinguish fire. Do NOT get water inside containers. In case of fire use water spray, dry chemical, carbon dioxide, or appropriate foam.
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Dusts may be combustible when exposed to heat, flame, or oxidizing agents. Runoff from fire control or dilution water may cause pollution. Extinguishing media: Use agent most appropriate to extinguish fire. Do NOT get water inside containers. In case of fire use water spray, dry chemical, carbon dioxide, or appropriate foam.
Fire Potential
Will burn even in absence of air. 4-Nitrophenol nitrophenol is combustible though it may take some effort to ignite.
Will burn even in absence of air. 4-Nitrophenol nitrophenol is combustible though it may take some effort to ignite.
Accidental Release Measures
Small spills/leaks
Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, using the appropriate protective equipment. Avoid generating dusty conditions. Provide ventilation. Do not get water inside containers.
Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, using the appropriate protective equipment. Avoid generating dusty conditions. Provide ventilation. Do not get water inside containers.
Stability and Reactivity
Incompatibilities
Oxidizing agents, strong acids, moisture.
Oxidizing agents, strong acids, moisture.
Stability
Stable at room temperature in closed containers under normal storage and handling conditions.
Stable at room temperature in closed containers under normal storage and handling conditions.
Decomposition
Nitrogen oxides, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, nitrogen.
Nitrogen oxides, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, nitrogen.
Combustion Products
Toxic gases and vapors (such as oxides of nitrogen and carbon monoxide) may be released in a fire involving nitrotoluene.
Toxic gases and vapors (such as oxides of nitrogen and carbon monoxide) may be released in a fire involving nitrotoluene.