Supplier Product Identification Physical and Chemical Properties First Aid Measures Handling and Storage Hazards Identification Exposure Controls/Personal Protection Fire Fighting Measures Accidental Release Measures Stability and Reactivity Transport Information
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2-Aminophenetole(94-70-2)

Supplier Product Identification Physical and Chemical Properties First Aid Measures Handling and Storage Hazards Identification Exposure Controls/Personal Protection Fire Fighting Measures Accidental Release Measures Stability and Reactivity Transport Information

Product Identification

Product Name
2-Aminophenetole
Synonyms
2-Ethoxybenzenamine
o-Phenetidine
CAS
94-70-2
Formula
C8H11NO
Molecular Weight
137.18
EINECS
202-356-4
RTECS
SI6465300
RTECS Class
Other
Merck
12,7372
Beilstein/Gmelin
637069
Beilstein Reference
4-13-00-00807
EC Index Number
612-039-00-6
EC Class
Toxic; Danger of cumulative effects

Physical and Chemical Properties

Appearance
Reddish brown oily liquid.
Solubility in water
Insoluble
Melting Point
-4
Boiling Point
229
Vapor Pressure
0.061 (25 C)
Density
1.0508 g/cm3 (20 C)
pKa/pKb
4.43(at 28℃) (pKa)
Partition Coefficient
1.62
Heat Of Vaporization
46.9 kJ/mol
Usage
Production of dyes.
Vapor Density
4.73
Refractive Index
1.5545 (20 C)

First Aid Measures

Ingestion
If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation
Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Skin
Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Eyes
Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.

Handling and Storage

Storage
Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
Handling
Wash thoroughly after handling. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Avoid contact with heat, sparks and flame. Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.

Hazards Identification

Ingestion
May cause irritation of the digestive tract.
Inhalation
Inhalation of vapors may cause irritation.
Skin
May cause skin irritation. Absorbed through the skin.
Eyes
May cause eye irritation.
Hazards
When heated, vapors may form explosive mixtures with air: indoors, outdoors, and sewers explosion hazards.
EC Risk Phrase
R 23/24/25 33
EC Safety Phrase
S 28 36/37 45
UN (DOT)
2311

Exposure Controls/Personal Protection

Personal Protection
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use.

Fire Fighting Measures

Flash Point
80
Fire Fighting
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Use water spray to keep fire-exposed containers cool. Combustible Liquid. Containers may explode when heated. To extinguish fire, use water, dry chemical, chemical foam, or alcohol-resistant foam. Use water spray to cool fire-exposed containers.
Fire Potential
This chemical is probably combustible.

Accidental Release Measures

Small spills/leaks
Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Clean up spills immediately, using the appropriate protective equipment. Remove all sources of ignition. Provide ventilation.

Stability and Reactivity

Disposal Code
9
Incompatibilities
Oxidizing agents
Stability
Stable under normal temperatures and pressures. Substance may undergo color change upon exposure to light and air.
Decomposition
Nitrogen oxides, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
Combustion Products
Fire may produce irritating, corrosive and/or toxic gases.

Transport Information

UN Number
2311
Hazard Class
6.1
Packing Group
III
HS Code
2922 22 00
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