Supplier Product Identification Physical and Chemical Properties First Aid Measures Handling and Storage Hazards Identification Exposure Controls/Personal Protection Fire Fighting Measures Accidental Release Measures Stability and Reactivity Transport Information
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a-Brom-4-nitrotoluol(100-11-8)

Supplier Product Identification Physical and Chemical Properties First Aid Measures Handling and Storage Hazards Identification Exposure Controls/Personal Protection Fire Fighting Measures Accidental Release Measures Stability and Reactivity Transport Information

Product Identification

Product Name
a-Brom-4-nitrotoluol
Synonyms
4-(Bromomethyl)nitrobenzene
4-Nitrobenzyl bromide
Benzene, 1-(bromomethyl)-4-nitro-
p-(Bromomethyl)nitrobenzene
p-Nitrobenzyl bromide
CAS
100-11-8
Formula
C7H6BrNO2
Molecular Weight
216.04
EINECS
202-820-6
RTECS
XS7967000
RTECS Class
Mutagen
Beilstein/Gmelin
742796
Beilstein Reference
4-05-00-00861
EC Class
irritant, sensitizing

Physical and Chemical Properties

Appearance
Beige crystals.
Solubility in water
Insoluble
Melting Point
94 - 96
Boiling Point
304
Vapor Pressure
0.0016 (25 C)
Partition Coefficient
2.65
Heat Of Vaporization
52.3 kJ/mol

First Aid Measures

Ingestion
If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation
Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Skin
Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.
Eyes
Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.

Handling and Storage

Storage
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
Handling
Wash thoroughly after handling. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.

Hazards Identification

Ingestion
The toxicological properties of this substance have not been fully investigated.
Inhalation
The toxicological properties of this substance have not been fully investigated.
Skin
No information regarding skin irritation and other potential effects was found.
Eyes
No information regarding eye irritation and other potential effects was found.
Hazards
Contact with metals may evolve flammable hydrogen gas.
EC Risk Phrase
R 34 36
EC Safety Phrase
S 26 36/37/39 45
UN (DOT)
2811

Exposure Controls/Personal Protection

Personal Protection
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators
Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.

Fire Fighting Measures

Flash Point
138
Fire Fighting
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Combustion generates toxic fumes. Extinguishing media: Do NOT use water directly on fire. Use dry chemical or carbon dioxide.
Fire Potential
Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes.

Accidental Release Measures

Small spills/leaks
Sweep up or absorb material, then place into a suitable clean, dry, closed container for disposal. Avoid generating dusty conditions.

Stability and Reactivity

Disposal Code
3
Incompatibilities
Oxidizing agents.
Stability
Stable under normal temperatures and pressures.
Decomposition
Nitrogen oxides, carbon monoxide, carbon dioxide, hydrogen bromide, nitrogen.
Combustion Products
Fire may produce irritating, corrosive and/or toxic gases.

Transport Information

UN Number
2811
Hazard Class
6.1
Packing Group
I; II; III
HS Code
2904 90 85
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