Supplier Product Identification Physical and Chemical Properties First Aid Measures Handling and Storage Hazards Identification Exposure Controls/Personal Protection Fire Fighting Measures Accidental Release Measures Stability and Reactivity Transport Information
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Glyphosine(2439-99-8)

Supplier Product Identification Physical and Chemical Properties First Aid Measures Handling and Storage Hazards Identification Exposure Controls/Personal Protection Fire Fighting Measures Accidental Release Measures Stability and Reactivity Transport Information

Product Identification

Product Name
Glyphosine
Synonyms
2-(Bis(phosphonomethyl)amino)acetic acid
N-(Carboxymethyl)iminodi(methylphosphinic acid)
N,N-Bis(phosphonomethyl)glycine
N,N-Di(phosphonomethyl)glycine
Nitrilomonomethylcarbonyldimethylphosphonic acid
CAS
2439-99-8
Formula
C4H11NO8P2
Molecular Weight
263.08
EINECS
219-468-4
RTECS
MB9120000
RTECS Class
Agricultural Chemical and Pesticide
Merck
12,4523
Beilstein/Gmelin
1884944
Beilstein Reference
6-04
EC Index Number
015-125-00-6

Physical and Chemical Properties

Solubility in water
Soluble
Melting Point
203
Vapor Pressure
1E-19 (25 C)
pKa/pKb
0.61 (pKa)
Heat Of Vaporization
107.1 kJ/mol
Usage
Chemical ripener.

First Aid Measures

Ingestion
If swallowed, wash out mouth with water provided person is conscious. Call a physician.
Inhalation
If inhaled, remove to fresh air. If not breathing give artificial respiration. If breathing is difficult, give oxygen.
Skin
In case of contact, immediately wash skin with soap and copious amounts of water.
Eyes
In case of contact, immediately flush eyes with copious amounts of water for at least 15 minutes.

Handling and Storage

Storage
Keep tightly closed.

Hazards Identification

Inhalation
May be harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract.
Skin
Causes skin irritation. May be harmful if absorbed through the skin.
Eyes
Causes severe eye irritation.
Ingestion
May be harmful if swallowed.
Hazards
Emits toxic fumes under fire conditions.
EC Risk Phrase
41
EC Safety Phrase
26
UN (DOT)
3261

Exposure Controls/Personal Protection

Personal Protection
Compatible chemical-resistant gloves. Chemical safety goggles.
Respirators
Government approved respirator.
Exposure Effects
Irritant. Risk of serious damage to eyes.

Fire Fighting Measures

Fire Fighting
Extinguish using Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes.
Fire Potential
Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes.

Accidental Release Measures

Small spills/leaks
Sweep up, place in a bag and hold for waste disposal. Avoid raising dust. Ventilate area and wash spill site after material pickup is complete.

Stability and Reactivity

Incompatibilities
Slightly corrosive to metals., Strong oxidizing agents
Stability
Stable at normal temperatures and pressures.
Decomposition
Carbon monoxide, Carbon dioxide, Phosphorous oxides.
Combustion Products
Fire may produce irritating, corrosive and/or toxic gases.

Transport Information

UN Number
3261
Hazard Class
8
Packing Group
III
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