5-Allyl-1,3-benzodioxole(94-59-7)

Product Name
5-Allyl-1,3-benzodioxole

Synonyms
3-(3,4-Methylenedioxyphenyl)prop-1-ene
4-Allyl-1,2-(methylenedioxy)benzene
5-(2-Propenyl)-1,3-benzodioxole
5-Allyl-1,3-benzodioxole
Allyldioxybenzene methylene ether
Allylpyrocatechol methylene ether

CAS
94-59-7

Formula
C10H10O2

Molecular Weight
162.19

EINECS
202-345-4

RTECS
CY2800000

RTECS Class
Tumorigen; Mutagen; Reproductive Effector; Natural Product; Primary Irritant

Merck
12,8468

Beilstein/Gmelin
136380

Beilstein Reference
5-19-01-00553

EC Index Number
605-020-00-9

EC Class
Carcinogenic Category 2; Mutagenic Category 3; Harmful

Appearance
Clear colorless or slightly yellow liquid with the odor of sassafras.

Solubility in water
Insoluble

Melting Point
11.2

Boiling Point
232

Vapor Pressure
0.9 (25 C)

Density
1.104 g/cm3

Partition Coefficient
3.1

Heat Of Vaporization
45.1 kJ/mol

Usage
Constituent of several essential oils, notably sassafras. It has been used as a topical antiseptic but is carcinogenic to the liver so it is no longer used as a flavoring agent in foods.

Vapor Density
5.6

Refractive Index
1.53

Ingestion
Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.

Inhalation
Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.

Skin
Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.

Eyes
Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.

Storage
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.

Handling
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.

Inhalation
May cause respiratory tract irritation. May cause effects similar to those described for ingestion.

Skin
May cause skin irritation.

Eyes
May cause eye irritation.

Ingestion
May cause irritation of the digestive tract. May cause liver damage. May cause cyanosis, weakness, acidosis, and shock. May be harmful if swallowed.

UN (DOT)
1851

Personal Protection
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.

Respirators
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use.

Exposure Effects
May cause cancer according to animal studies. May cause reproductive and fetal effects. Chronic exposure may cause liver damage.

Exposure limit(s)
OSHA: Possible Select carcinogen.

Poison Class
1*

Flash Point
97

Fire Fighting
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Will burn if involved in a fire. Use water spray to keep fire-exposed containers cool. Extinguishing media: Use agent most appropriate to extinguish fire. Cool containers with flooding quantities of water until well after fire is out. In case of fire use water spray, dry chemical, carbon dioxide, or appropriate foam.

Fire Potential
This chemical is combustible.

Small spills/leaks
Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, using the appropriate protective equipment. Remove all sources of ignition. Provide ventilation.

Incompatibilities
Oxidizing agents.

Stability
Stable under normal temperatures and pressures.

Decomposition
Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.

UN Number
1851