Home > 3-Nitro-4-chlorobenzotrifluoride > 3-Nitro-4-chlorobenzotrifluoride(121-17-5)
3-Nitro-4-chlorobenzotrifluoride(121-17-5)
Product Identification
Physical and Chemical Properties
First Aid Measures
Handling and Storage
Hazards Identification
Exposure Controls/Personal Protection
Fire Fighting Measures
Accidental Release Measures
Stability and Reactivity
Transport Information
Product Identification
Product Name
3-Nitro-4-chlorobenzotrifluoride
3-Nitro-4-chlorobenzotrifluoride
Synonyms
1,4-Diformylpiperazine
1,4-Piperazine dialdehyde
1,4-Piperazinedicarboxaldehyde
1-Chloro-2-nitro-4-(trifluoromethyl)benzene
2-Chloro-5-(trifluoromethyl)nitrobenzene
3-Nitro-4-chloro-1-(trifluoromethyl)benzene
4-Chloro-3-nitro-alpha,alpha,alpha-trifluorotoluene
4-Trifluoromethyl-2-nitrochlorobenzene
Benzene, 1-chloro-2-nitro-4-(trifluoromethyl)
1,4-Diformylpiperazine
1,4-Piperazine dialdehyde
1,4-Piperazinedicarboxaldehyde
1-Chloro-2-nitro-4-(trifluoromethyl)benzene
2-Chloro-5-(trifluoromethyl)nitrobenzene
3-Nitro-4-chloro-1-(trifluoromethyl)benzene
4-Chloro-3-nitro-alpha,alpha,alpha-trifluorotoluene
4-Trifluoromethyl-2-nitrochlorobenzene
Benzene, 1-chloro-2-nitro-4-(trifluoromethyl)
CAS
121-17-5
121-17-5
CAS
4164-39-0
4164-39-0
Formula
C6H10N2O2
C6H10N2O2
Formula
C7H3ClF3NO2
C7H3ClF3NO2
Molecular Weight
225.55
225.55
Molecular Weight
142.15
142.15
EINECS
204-451-6
204-451-6
EINECS
224-011-7
224-011-7
RTECS
XS9140000
XS9140000
RTECS Class
Mutagen; Primary Irritant
Mutagen; Primary Irritant
Beilstein/Gmelin
523986
523986
Beilstein/Gmelin
121175
121175
Beilstein Reference
4-05-00-00857
4-05-00-00857
Beilstein Reference
5-23-01-00044
5-23-01-00044
EC Class
harmful, irritant
harmful, irritant
Physical and Chemical Properties
Appearance
A colorless to dark-colored liquid.
A colorless to dark-colored liquid.
Appearance
Light yellow tinted powder.
Light yellow tinted powder.
Solubility in water
660 mg/L
660 mg/L
Melting Point
-3
-3
Melting Point
127.5
127.5
Boiling Point
154 - 158 (0.2 - 0.3 torr)
154 - 158 (0.2 - 0.3 torr)
Boiling Point
223
223
Vapor Pressure
.04
.04
Density
1.391 g/cm3
1.391 g/cm3
Density
1.5421 g/cm3 (21 C)
1.5421 g/cm3 (21 C)
Usage
Chemical intermediate for herbicides, eg, fluorodifen.
Chemical intermediate for herbicides, eg, fluorodifen.
Refractive Index
1.4905 (20 C)
1.4905 (20 C)
First Aid Measures
Ingestion
Get medical aid. Wash mouth out with water.
Get medical aid. Wash mouth out with water.
Ingestion
If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
Inhalation
Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Inhalation
Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Skin
May cause skin irritation.
May cause skin irritation.
Skin
Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.
Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.
Skin
Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Eyes
May cause eye irritation.
May cause eye irritation.
Eyes
Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids.
Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids.
Eyes
Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Handling and Storage
Storage
Keep container closed when not in use. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
Keep container closed when not in use. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
Storage
Store in a cool, dry place. Store in a tightly closed container.
Store in a cool, dry place. Store in a tightly closed container.
Handling
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
Handling
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Use only in a chemical fume hood.
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Use only in a chemical fume hood.
Hazards Identification
Ingestion
May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated.
May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated.
Inhalation
Harmful if inhaled. May cause cyanosis, characterized by bluish-colored skin.
Harmful if inhaled. May cause cyanosis, characterized by bluish-colored skin.
Skin
Harmful if absorbed through the skin.
Harmful if absorbed through the skin.
Eyes
May cause eye irritation.
May cause eye irritation.
Ingestion
Harmful if swallowed. May cause nausea and vomiting. May cause unconsciousness.
Harmful if swallowed. May cause nausea and vomiting. May cause unconsciousness.
Hazards
Containers may explode when heated. Runoff may pollute waterways. Substance may be transported in a molten form.
Containers may explode when heated. Runoff may pollute waterways. Substance may be transported in a molten form.
EC Risk Phrase
R 20/21/22 36/38
R 20/21/22 36/38
EC Risk Phrase
R 36/37/38
R 36/37/38
EC Safety Phrase
S 26 36
S 26 36
EC Safety Phrase
S 26 36/37/39
S 26 36/37/39
UN (DOT)
2307
2307
Exposure Controls/Personal Protection
Personal Protection
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
Personal Protection
Eyes: Wear chemical goggles. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear a chemical apron.
Eyes: Wear chemical goggles. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear a chemical apron.
Respirators
Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
Exposure Effects
The toxological properties of this substance have not been fully investigated.
The toxological properties of this substance have not been fully investigated.
Exposure limit(s)
2.5 mg/m3 as F (ACGIH)
2.5 mg/m3 as F (ACGIH)
Fire Fighting Measures
Flash Point
101
101
Autoignition
>450
>450
Fire Fighting
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. To extinguish fire use water spray, dry chemical, carbon dioxide, or appropriate foam.
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. To extinguish fire use water spray, dry chemical, carbon dioxide, or appropriate foam.
Fire Fighting
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. To extinguish fire use water spray, dry chemical, carbon dioxide, or chemical foam.
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. To extinguish fire use water spray, dry chemical, carbon dioxide, or chemical foam.
Fire Potential
May burn but does not ignite readily.
May burn but does not ignite readily.
Accidental Release Measures
Small spills/leaks
Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container.
Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container.
Small spills/leaks
Clean up spills immediately, using the appropriate protective equipment. Sweep up or absorb material, then place into a suitable clean, dry, closed container for disposal. Avoid generating dusty conditions. Provide ventilation.
Clean up spills immediately, using the appropriate protective equipment. Sweep up or absorb material, then place into a suitable clean, dry, closed container for disposal. Avoid generating dusty conditions. Provide ventilation.
Stability and Reactivity
Stability
No data.
No data.
Stability
Stable under normal temperatures and pressures.
Stable under normal temperatures and pressures.
Incompatibilities
Strong bases, strong oxidizing agents.
Strong bases, strong oxidizing agents.
Incompatibilities
Strong oxidizing agents.
Strong oxidizing agents.
Decomposition
Carbon monoxide, oxides of nitrogen, irritating and toxic fumes and gases, carbon dioxide.
Carbon monoxide, oxides of nitrogen, irritating and toxic fumes and gases, carbon dioxide.
Decomposition
Hydrogen chloride, nitrogen oxides, carbon monoxide, carbon dioxide, hydrogen fluoride.
Hydrogen chloride, nitrogen oxides, carbon monoxide, carbon dioxide, hydrogen fluoride.
Combustion Products
Fire may produce irritating, corrosive and/or toxic gases.
Fire may produce irritating, corrosive and/or toxic gases.
Transport Information
UN Number
2307
2307
Hazard Class
6.1
6.1
Packing Group
II
II
HS Code
2904 90 85
2904 90 85