Supplier Product Identification Physical and Chemical Properties First Aid Measures Handling and Storage Hazards Identification Exposure Controls/Personal Protection Fire Fighting Measures Accidental Release Measures Stability and Reactivity Transport Information
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DL-1-Phenethylalcohol(98-85-1)

Supplier Product Identification Physical and Chemical Properties First Aid Measures Handling and Storage Hazards Identification Exposure Controls/Personal Protection Fire Fighting Measures Accidental Release Measures Stability and Reactivity Transport Information

Product Identification

Product Name
DL-1-Phenethylalcohol
Synonyms
[(2S,3R,5R,6R)-2,3,5-Triacetyloxy-6-(acetyloxymethyl)oxan-4-yl] acetate
1-Phenylethanol
2-Amino-3,5-dibromopyridine
2-Pyridinamine, 3,5-dibromo-
3,5-Dibromopyridin-2-amine
beta-D-Glucopyranose, pentaacetate
DL-sec-Phenethyl alcohol
CAS
35486-42-1
CAS
98-85-1
CAS
604-69-3
Formula
C16H22O11
Formula
C5H4Br2N2
Formula
C8H10O
Molecular Weight
390.34
Molecular Weight
122.18
Molecular Weight
251.91
EINECS
252-590-6
EINECS
202-707-1
EINECS
210-074-8
RTECS
DO9275000
RTECS Class
Tumorigen; Mutagen; Primary Irritant
Beilstein/Gmelin
98851
Beilstein/Gmelin
1905149
Beilstein/Gmelin
119390
Beilstein Reference
2-06-00-00444
Beilstein Reference
5-17-07-00319
Beilstein Reference
5-22-08-00481

Physical and Chemical Properties

Appearance
A colorless liquid.
Appearance
White to off-white powder.
Appearance
Yellow powder.
Solubility in water
Insoluble
Solubility in water
< 1 mg/ml
Melting Point
104
Melting Point
130 - 132
Melting Point
20
Boiling Point
254
Boiling Point
401
Boiling Point
452
Vapor Pressure
2E-8 (25 C)
Vapor Pressure
.1
Vapor Pressure
0.02 (25 C)
Density
1.015 g/cm3 (20 C)
Density
1.274 g/cm3
pKa/pKb
12.10 (pKb)
Partition Coefficient
1.71
Partition Coefficient
1.78
Partition Coefficient
3.45
Heat Of Vaporization
49.1
Heat Of Vaporization
71.1 kJ/mol
Heat Of Combustion
-7212 kJ/mol
Usage
Perfumery, flavoring, dyes, laboratory reagent.
Vapor Density
4.21
Refractive Index
1.5265 (20 C)

First Aid Measures

Ingestion
If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Ingestion
May cause gastrointestinal irritation with nausea, vomiting and diarrhea. The toxicological properties of this substance have not been fully investigated.
Ingestion
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation
Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Inhalation
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
Inhalation
Causes respiratory tract irritation. The toxicological properties of this substance have not been fully investigated. Can produce delayed pulmonary edema.
Skin
Causes skin irritation.
Skin
Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.
Skin
Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Skin
May cause skin irritation.
Eyes
Causes eye irritation. May cause chemical conjunctivitis.
Eyes
May cause eye irritation.
Eyes
Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Eyes
First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.
Eyes
Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.

Handling and Storage

Storage
Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
Storage
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
Handling
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
Handling
Wash thoroughly after handling. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Avoid contact with heat, sparks and flame. Do not ingest or inhale. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Handling
Wash thoroughly after handling. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid breathing dust, vapor, mist, or gas. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.

Hazards Identification

Ingestion
May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated. May be harmful if swallowed.
Inhalation
May cause respiratory tract irritation.
Skin
Causes skin irritation.
Eyes
Causes severe eye irritation.
Ingestion
Harmful if swallowed. May cause irritation of the digestive tract.
Hazards
When heated, vapors may form explosive mixtures with air: indoors, outdoors, and sewers explosion hazards. May polymerize explosively when heated or involved in a fire. Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated. Runoff may pollute waterways. Substance may be transported in a molten form.
EC Risk Phrase
R 36/37/38
EC Safety Phrase
S 26 36
UN (DOT)
2937

Exposure Controls/Personal Protection

Personal Protection
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
Personal Protection
Wear appropriate protective gloves, clothing and goggles.
Respirators
Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
Respirators
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use.
Exposure Effects
Effects may be delayed.
Exposure Effects
Headache, dizziness, giddiness, ataxia, sedation and coma may occur.
Poison Class
3

Fire Fighting Measures

Flash Point
107
Flash Point
196
Flash Point
85
Autoignition
480
Fire Fighting
Extinguish fire using agent suitable for type of surrounding fire. (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog. Use foam, dry chemical, or carbon dioxide. Keep run-off water out of sewers and water sources.
Fire Fighting
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Extinguishing media: Use agent most appropriate to extinguish fire. In case of fire use water spray, dry chemical, carbon dioxide, or appropriate foam.
Upper exp. limit
4.9
Lower exp. limit
1.8
Fire Potential
May burn but does not ignite readily.

Accidental Release Measures

Small spills/leaks
Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Avoid runoff into storm sewers and ditches which lead to waterways. Remove all sources of ignition. Provide ventilation.
Small spills/leaks
Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, using the appropriate protective equipment. Avoid generating dusty conditions. Provide ventilation.

Stability and Reactivity

Disposal Code
3
Incompatibilities
Oxidizing agents
Incompatibilities
Oxidizing agents.
Stability
Stable at room temperature in closed containers under normal storage and handling conditions.
Stability
Stable under normal temperatures and pressures.
Incompatibilities
Strong oxidizing agents.
Decomposition
Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
Decomposition
Carbon monoxide, oxides of nitrogen, irritating and toxic fumes and gases, carbon dioxide, hydrogen bromide.
Combustion Products
Fire may produce irritating, corrosive and/or toxic gases.

Transport Information

UN Number
2937
Hazard Class
6.1
Packing Group
III
HS Code
2940 00 90
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