Supplier Product Identification Physical and Chemical Properties First Aid Measures Handling and Storage Hazards Identification Exposure Controls/Personal Protection Fire Fighting Measures Accidental Release Measures Stability and Reactivity Transport Information
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2,4,6-Tribromoaniline(147-82-0)

Supplier Product Identification Physical and Chemical Properties First Aid Measures Handling and Storage Hazards Identification Exposure Controls/Personal Protection Fire Fighting Measures Accidental Release Measures Stability and Reactivity Transport Information

Product Identification

Product Name
2,4,6-Tribromoaniline
Synonyms
2,4,6-Tribromobenzenamine
sym-Tribromoaniline
CAS
147-82-0
Formula
C6H4Br3N
Molecular Weight
329.82
EINECS
205-700-1
RTECS
BZ0175000
RTECS Class
Other
Merck
12,9740
Beilstein/Gmelin
2209258
Beilstein Reference
4-12-00-01538

Physical and Chemical Properties

Appearance
Needles from alcohol, benzene.
Solubility in water
Insoluble
Melting Point
118
Boiling Point
300
Vapor Pressure
0.0012 (25 C)
Density
2.578 g/cm3
Partition Coefficient
4.42
Heat Of Vaporization
54.0 kJ/mol
Heat Of Combustion
-2989 kJ/mol

First Aid Measures

Ingestion
Emesis: ipecac-induced vomiting is not recommended because of the potential for cns depression and seizures. Activated charcoal: administer charcoal as a slurry (240 ml water/30 g charcoal). Usual dose: 25 to 100 g in adults/adolescents. Consider after ingestion of a potentially life-threatening amount of poison if it can be performed soon after ingestion (generally within 1 hour). Oxygen - administer oxygen to all cyanotic or symptomatic patients. Methemoglobinemia: administer 1 to 2 mg/kg of 1% methylene blue slowly iv in symptomatic patients. Additional doses may be required. Shock and cardiac arrest - treat routinely. Adjunctive therapy - exchange transfusions and hyperbaric oxygen may be useful in severe cases.
Inhalation
Move victim to fresh air. Apply artificial respiration if victim is not breathing. Do not use mouth-to-mouth method if victim ingested or inhaled the substance; induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Administer oxygen if breathing is difficult.
Skin
Remove and isolate contaminated clothing and shoes. Immediately flush with running water for at least 20 minutes. For minor skin contact, avoid spreading material on unaffected skin.
Eyes
Immediately flush with running water for at least 20 minutes.

Handling and Storage

Storage
Keep in a cool, dry, dark location in a tightly sealed container or cylinder. Keep away from incompatible materials, ignition sources and untrained individuals. Secure and label area. Protect containers/cylinders from physical damage.
Handling
All chemicals should be considered hazardous. Avoid direct physical contact. Use appropriate, approved safety equipment. Untrained individuals should not handle this chemical or its container. Handling should occur in a chemical fume hood.

Hazards Identification

Ingestion
Nausea and vomiting may occur.
Inhalation
Dyspnea and tachypnea may occur.
Skin
Central cyanosis unresponsive to oxygen therapy is classic.
Eyes
See Inhalation.
Hazards
When heated, vapors may form explosive mixtures with air: indoors, outdoors, and sewers explosion hazards.
EC Risk Phrase
R 20/21/22 33
EC Safety Phrase
S 22 36/37
UN (DOT)
2810

Exposure Controls/Personal Protection

Personal Protection
Wear appropriate protective gloves, clothing and goggles.
Respirators
Not available.

Fire Fighting Measures

Flash Point
133
Fire Fighting
Small Fires: Dry chemical, carbon dioxide or water spray. Large Fires: Dry chemical, carbon dioxide, alcohol-resistant foam or water spray.
Fire Potential
Combustible material: may burn but does not ignite readily.

Accidental Release Measures

Small spills/leaks
ELIMINATE all ignition sources. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Stop leak if you can do it without risk. Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. DO NOT GET WATER INSIDE CONTAINERS.

Stability and Reactivity

Stability
No data.
Combustion Products
Fire may produce irritating, corrosive and/or toxic gases.

Transport Information

UN Number
2810
Hazard Class
6.1
Packing Group
I; II; III
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