Supplier Product Identification Physical and Chemical Properties First Aid Measures Handling and Storage Hazards Identification Exposure Controls/Personal Protection Fire Fighting Measures Accidental Release Measures Stability and Reactivity Transport Information
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Titanocene dichloride(1271-19-8)

Supplier Product Identification Physical and Chemical Properties First Aid Measures Handling and Storage Hazards Identification Exposure Controls/Personal Protection Fire Fighting Measures Accidental Release Measures Stability and Reactivity Transport Information

Product Identification

Product Name
Titanocene dichloride
Synonyms
bis(Cyclopentadienyl)titanium dichloride
Bis(eta(5)-cyclopentadienyl)titanium dichloride
bis(Pi-Cyclopentadienyl)titanium dichloride
Biscyclopentadienyltitanium(Iv) dichloride
Dichlorobis(Cyclopentadienyl)titanium
Dichlorobis(Eta(5)-Cyclopentadienyl)titanium
CAS
1271-19-8
Formula
C10H10Cl2Ti
Molecular Weight
249
EINECS
215-035-9
RTECS
XR2050000
RTECS Class
Tumorigen; Mutagen; Reproductive Effector
Merck
12,9621
Beilstein/Gmelin
3997 (G)
EC Class
irritant

Physical and Chemical Properties

Appearance
Red to red-orange crystals.
Solubility in water
Insoluble
Melting Point
289 - 291
Density
1.600 g/cm3 (20 C)
Usage
Research chemical.

First Aid Measures

Ingestion
Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation
Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid if cough or other symptoms appear.
Skin
Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists.
Eyes
Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.

Handling and Storage

Storage
Store in a cool, dry place. Store in a tightly closed container.
Handling
Wash thoroughly after handling. Wash hands before eating. Use with adequate ventilation. Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Avoid ingestion and inhalation.

Hazards Identification

Ingestion
Causes gastrointestinal irritation with nausea, vomiting and diarrhea.
Inhalation
Causes respiratory tract irritation.
Skin
Causes skin irritation.
Eyes
Causes eye irritation.
EC Risk Phrase
R 20/22 36/37/38 40
EC Safety Phrase
S 26 36/37/39
UN (DOT)
3282

Exposure Controls/Personal Protection

Personal Protection
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators
Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.

Fire Fighting Measures

Fire Fighting
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. To extinguish fire use water spray, dry chemical, carbon dioxide, or chemical foam.
Fire Potential
This material is probably combustible.

Accidental Release Measures

Small spills/leaks
Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, using the appropriate protective equipment.

Stability and Reactivity

Disposal Code
24
Stability
Stable under normal temperatures and pressures.
Incompatibilities
Strong oxidizing agents, moist air or water.
Decomposition
Hydrogen chloride, carbon monoxide, carbon dioxide, titanium/titanium oxides.

Transport Information

UN Number
3282
HS Code
2931 00 95
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