Supplier Product Identification Physical and Chemical Properties First Aid Measures Handling and Storage Hazards Identification Exposure Controls/Personal Protection Fire Fighting Measures Accidental Release Measures Stability and Reactivity Transport Information
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Diethyl 2-bromo-2-methylmalonate(29263-94-3)

Supplier Product Identification Physical and Chemical Properties First Aid Measures Handling and Storage Hazards Identification Exposure Controls/Personal Protection Fire Fighting Measures Accidental Release Measures Stability and Reactivity Transport Information

Product Identification

Product Name
Diethyl 2-bromo-2-methylmalonate
Synonyms
Diethyl 2-bromo-2-methylmalonate
Diethyl 2-bromo-2-methylpropanedioate
Diethyl a-bromo-a-methylmalonate
Diethyl methylbromomalonate
Malonic acid, bromomethyl-, diethyl ester
Propanedioic acid, bromomethyl-, diethyl ester
CAS
29263-94-3
Formula
C8H13BrO4
Molecular Weight
253.09
EINECS
249-541-6
Beilstein/Gmelin
1779673
Beilstein Reference
3-02-00-01684

Physical and Chemical Properties

Appearance
Clear, colorless liquid.
Solubility in water
Insoluble
Boiling Point
56 - 59 (0.2 torr)
Density
1.337 g/cm3 (12 C)
Refractive Index
1.45 (20 C)

First Aid Measures

Ingestion
If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation
Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Skin
Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.
Eyes
Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.

Handling and Storage

Storage
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
Handling
Wash thoroughly after handling. Use only in a well ventilated area. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.

Hazards Identification

Ingestion
The toxicological properties of this substance have not been fully investigated.
Inhalation
The toxicological properties of this substance have not been fully investigated.
Skin
No information regarding skin irritation and other potential effects was found.
Eyes
No information regarding eye irritation and other potential effects was found.
Hazards
Contact with metals may evolve flammable hydrogen gas.
EC Risk Phrase
R 34
EC Safety Phrase
S 26 36/37/39 45
UN (DOT)
1760

Exposure Controls/Personal Protection

Personal Protection
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators
Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.

Fire Fighting Measures

Flash Point
>110
Fire Fighting
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing media: Use agent most appropriate to extinguish fire.
Fire Potential
Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes.

Accidental Release Measures

Small spills/leaks
Sweep up or absorb material, then place into a suitable clean, dry, closed container for disposal.

Stability and Reactivity

Stability
No data.
Incompatibilities
Oxidizing agents.
Decomposition
Carbon monoxide, carbon dioxide, hydrogen bromide.
Combustion Products
Fire may produce irritating, corrosive and/or toxic gases.

Transport Information

UN Number
1760
Hazard Class
8
Packing Group
I; II; III
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