Supplier Product Identification Physical and Chemical Properties First Aid Measures Handling and Storage Hazards Identification Exposure Controls/Personal Protection Fire Fighting Measures Accidental Release Measures Stability and Reactivity Transport Information
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3-Amino-4-chlorobenzotrifluoride(121-50-6)

Supplier Product Identification Physical and Chemical Properties First Aid Measures Handling and Storage Hazards Identification Exposure Controls/Personal Protection Fire Fighting Measures Accidental Release Measures Stability and Reactivity Transport Information

Product Identification

Product Name
3-Amino-4-chlorobenzotrifluoride
Synonyms
2-Chloro-5-(trifluoromethyl)aniline
2-Chloro-5-(trifluoromethyl)benzenamine
3-Amino-4-chloro-a,a,a-trifluorotoluene
4-Chloro-3-aminobenzotrifluoride
Azoene Fast Orange RD
Sanyo Fast Orange Salt RD
CAS
121-50-6
Formula
C7H5ClF3N
Molecular Weight
195.57
EINECS
204-475-7
RTECS
XU5775000
RTECS Class
Other
Beilstein/Gmelin
879910
Beilstein Reference
4-12-00-01852
EC Class
irritant

Physical and Chemical Properties

Appearance
Clear faint yellow to yellow liquid. Penetrating odor.
Solubility in water
Insoluble
Melting Point
10
Boiling Point
208
Vapor Pressure
0.22 (25 C)
Density
1.42 g/cm3
pKa/pKb
12.57 (pKb)
Partition Coefficient
3.76
Heat Of Vaporization
44.4 kJ/mol
Refractive Index
1.50 (20 C)

First Aid Measures

Ingestion
If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid. Induce vomiting by giving one teaspoon of Syrup of Ipecac.
Inhalation
Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Skin
Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.
Eyes
Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.

Handling and Storage

Storage
Keep away from sources of ignition. Store in a cool, dry place. Do not store in direct sunlight. Store in a tightly closed container.
Handling
Wash thoroughly after handling. Wash hands before eating. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Do not get in eyes, on skin, or on clothing. Do not ingest or inhale.

Hazards Identification

Inhalation
May cause cyanosis, characterized by bluish-colored skin. Causes respiratory tract irritation.
Skin
Causes skin irritation. May be absorbed through the skin in harmful amounts.
Eyes
Causes eye irritation.
Ingestion
Causes gastrointestinal irritation with nausea, vomiting and diarrhea.
Hazards
Containers may explode when heated.
EC Risk Phrase
R 23/24/25 36/38
EC Safety Phrase
S 26 36/37/39 45
UN (DOT)
3082

Exposure Controls/Personal Protection

Personal Protection
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear a chemical apron. Wear appropriate protective clothing to prevent skin exposure.
Respirators
Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
Exposure Effects
Prolonged exposure may produce a narcotic effect. Prolonged or repeated exposure may cause nausea, dizziness, and headache.

Fire Fighting Measures

Flash Point
80
Autoignition
>560
Fire Fighting
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Will burn if involved in a fire. To extinguish fire use water spray, dry chemical, carbon dioxide, or chemical foam.
Fire Potential
May burn but does not ignite readily.

Accidental Release Measures

Small spills/leaks
Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Clean up spills immediately, using the appropriate protective equipment. Scoop up with a nonsparking tool, then place into a suitable container for disposal.

Stability and Reactivity

Incompatibilities
Acids and oxidizing agents.
Stability
Stable under normal temperatures and pressures.
Decomposition
Hydrogen chloride, nitrogen oxides, carbon monoxide, carbon dioxide, hydrogen fluoride.
Combustion Products
Fire may produce irritating, corrosive and/or toxic gases.

Transport Information

UN Number
3082
Hazard Class
9
Packing Group
III
HS Code
2921 43 00
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