Supplier Product Identification Physical and Chemical Properties First Aid Measures Handling and Storage Hazards Identification Exposure Controls/Personal Protection Fire Fighting Measures Accidental Release Measures Stability and Reactivity Transport Information
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4-Butylaniline(104-13-2)

Supplier Product Identification Physical and Chemical Properties First Aid Measures Handling and Storage Hazards Identification Exposure Controls/Personal Protection Fire Fighting Measures Accidental Release Measures Stability and Reactivity Transport Information

Product Identification

Product Name
4-Butylaniline
Synonyms
1,2-Epoxydecane
2-Octyloxirane
4-Butylbenzenamine
4-n-Butylaniline
Benzenamine, 4-butyl-
p-Aminobutylbenzene
p-Butylaminobenzene
p-Butylaniline
CAS
104-13-2
CAS
2404-44-6
Formula
C10H15N
Formula
C10H20O
Molecular Weight
149.24
Molecular Weight
156.26
EINECS
203-177-4
EINECS
219-295-4
RTECS
BW9470000
RTECS Class
Other
Beilstein/Gmelin
1447268
Beilstein/Gmelin
104132
Beilstein Reference
4-12-00-02807
Beilstein Reference
5-17-01-00158
EC Class
irritant

Physical and Chemical Properties

Appearance
Clear colorless mobile liquid with a ethereal odor.
Appearance
Liquid.
Solubility in water
Insoluble
Melting Point
-14
Boiling Point
242
Boiling Point
112
Density
0.8401 g/cm3 (20 C)
Density
0.945 g/cm3 (20 C)
pKa/pKb
9.10 (pKb)
Refractive Index
1.43 (20 C)
Refractive Index
1.5361 (23 C)

First Aid Measures

Ingestion
Get medical aid. Wash mouth out with water.
Ingestion
Seek medical assistance.
Inhalation
Move victim to fresh air. Apply artificial respiration if victim is not breathing. Do not use mouth-to-mouth method if victim ingested or inhaled the substance; induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Administer oxygen if breathing is difficult.
Inhalation
Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Inhalation
Causes respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
Skin
Causes skin irritation.
Skin
Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.
Skin
Remove and isolate contaminated clothing and shoes. Immediately flush with running water for at least 20 minutes. For minor skin contact, avoid spreading material on unaffected skin.
Eyes
Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Eyes
Immediately flush with running water for at least 20 minutes.
Eyes
Causes eye irritation.

Handling and Storage

Storage
Keep away from sources of ignition. Store in a cool, dry place. Store in a tightly closed container.
Storage
Keep in a cool, dry, dark location in a tightly sealed container or cylinder. Keep away from incompatible materials, ignition sources and untrained individuals. Secure and label area. Protect containers/cylinders from physical damage.
Handling
All chemicals should be considered hazardous. Avoid direct physical contact. Use appropriate, approved safety equipment. Untrained individuals should not handle this chemical or its container. Handling should occur in a chemical fume hood.
Handling
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.

Hazards Identification

Ingestion
May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated.
Ingestion
See Inhalation.
Inhalation
TOXIC; inhalation, ingestion, or skin contact with material may cause severe injury or death. Effects of contact or inhalation may be delayed.
Skin
Contact with molten substance may cause severe burns to skin and eyes. See Inhalation.
Eyes
See Inhalation.
Hazards
When heated, vapors may form explosive mixtures with air: indoors, outdoors, and sewers explosion hazards.
EC Risk Phrase
R 20/21/22
EC Risk Phrase
R 36/38
EC Safety Phrase
S 26 36
EC Safety Phrase
S 28 36/37
UN (DOT)
2738

Exposure Controls/Personal Protection

Personal Protection
Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
Personal Protection
Wear appropriate protective gloves, clothing and goggles.
Respirators
Wear positive pressure self-contained breathing apparatus (SCBA).
Respirators
Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
Poison Class
4

Fire Fighting Measures

Flash Point
101
Flash Point
78
Fire Fighting
Small Fires: Dry chemical, carbon dioxide or water spray. Large Fires: Dry chemical, carbon dioxide, alcohol-resistant foam or water spray.
Fire Fighting
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Combustible Liquid. To extinguish fire use water spray, dry chemical, carbon dioxide, or chemical foam.
Fire Potential
This chemical is flammable.
Fire Potential
Combustible material: may burn but does not ignite readily.

Accidental Release Measures

Small spills/leaks
Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container.
Small spills/leaks
ELIMINATE all ignition sources. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Stop leak if you can do it without risk. Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. DO NOT GET WATER INSIDE CONTAINERS.

Stability and Reactivity

Disposal Code
9
Stability
No data.
Stability
Stable under normal temperatures and pressures.
Incompatibilities
Water, strong oxidizing agents, strong acids, strong bases, alkali metals, metallic salts.
Decomposition
Carbon monoxide, carbon dioxide.
Combustion Products
Fire may produce irritating, corrosive and/or toxic gases.

Transport Information

UN Number
2738
Hazard Class
6.1
Packing Group
II
HS Code
2921 49 80
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