Home > 2-Bromo-3'-nitroacetophenone > 2-Bromo-3'-nitroacetophenone(2227-64-7)
2-Bromo-3'-nitroacetophenone(2227-64-7)
Supplier Product Identification
Physical and Chemical Properties
First Aid Measures
Handling and Storage
Hazards Identification
Exposure Controls/Personal Protection
Fire Fighting Measures
Accidental Release Measures
Stability and Reactivity
Transport Information
Product Identification
Product Name
2-Bromo-3'-nitroacetophenone
2-Bromo-3'-nitroacetophenone
Synonyms
2-Bromo-3'-nitroacetophenone
3'-Nitrophenacyl bromide
3-Nitrophenacyl bromide
Ethanone, 2-bromo-1-(3-nitrophenyl)-
2-Bromo-3'-nitroacetophenone
3'-Nitrophenacyl bromide
3-Nitrophenacyl bromide
Ethanone, 2-bromo-1-(3-nitrophenyl)-
CAS
2227-64-7
2227-64-7
Formula
C8H6BrNO3
C8H6BrNO3
Molecular Weight
244.04
244.04
EINECS
218-764-0
218-764-0
Beilstein/Gmelin
610594
610594
Beilstein Reference
4-07-00-00661
4-07-00-00661
Physical and Chemical Properties
Appearance
Beige orange solid.
Beige orange solid.
Melting Point
90-94
90-94
Partition Coefficient
1.73
1.73
First Aid Measures
Ingestion
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation
Remove from exposure to fresh air immediately. If breathing is difficult, give oxygen. Get medical aid. DO NOT use mouth-to-mouth respiration. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
Remove from exposure to fresh air immediately. If breathing is difficult, give oxygen. Get medical aid. DO NOT use mouth-to-mouth respiration. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
Skin
Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Eyes
Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Do NOT allow victim to rub or keep eyes closed.
Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Do NOT allow victim to rub or keep eyes closed.
Handling and Storage
Storage
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
Handling
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use with adequate ventilation.
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use with adequate ventilation.
Hazards Identification
Inhalation
Causes respiratory tract irritation. Can produce delayed pulmonary edema.
Causes respiratory tract irritation. Can produce delayed pulmonary edema.
Skin
Causes skin irritation.
Causes skin irritation.
Eyes
Produces irritation, characterized by a burning sensation, redness, tearing, inflammation, and possible corneal injury. Lachrymator. May cause chemical conjunctivitis.
Produces irritation, characterized by a burning sensation, redness, tearing, inflammation, and possible corneal injury. Lachrymator. May cause chemical conjunctivitis.
Ingestion
May cause gastrointestinal irritation with nausea, vomiting and diarrhea.
May cause gastrointestinal irritation with nausea, vomiting and diarrhea.
EC Risk Phrase
R 34
R 34
EC Safety Phrase
S 26 36/37/39 45
S 26 36/37/39 45
UN (DOT)
3261
3261
Exposure Controls/Personal Protection
Personal Protection
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators
Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
Exposure Effects
Effects may be delayed.
Effects may be delayed.
Fire Fighting Measures
Fire Fighting
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Extinguishing media: Use agent most appropriate to extinguish fire. In case of fire use water spray, dry chemical, carbon dioxide, or appropriate foam.
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Extinguishing media: Use agent most appropriate to extinguish fire. In case of fire use water spray, dry chemical, carbon dioxide, or appropriate foam.
Accidental Release Measures
Small spills/leaks
Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, using the appropriate protective equipment. Avoid generating dusty conditions. Provide ventilation.
Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, using the appropriate protective equipment. Avoid generating dusty conditions. Provide ventilation.
Stability and Reactivity
Incompatibilities
Oxidizing agents.
Oxidizing agents.
Stability
Stable at room temperature in closed containers under normal storage and handling conditions.
Stable at room temperature in closed containers under normal storage and handling conditions.
Decomposition
Nitrogen oxides, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, hydrogen bromide, nitrogen.
Nitrogen oxides, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, hydrogen bromide, nitrogen.
Transport Information
UN Number
3261
3261
Contact
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- Company Name:Shangqiu Ladybug Network Technology Co., LTD
- Tel:0370-2070160 17550096163
- Fax:18736733639
- WebSite:http://www.beicaichem.com
- Company Name:J & K SCIENTIFIC LTD.
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- WebSite:http://www.jkchemical.com
- Company Name:Meryer (Shanghai) Chemical Technology Co., Ltd.
- Tel:021-61259108 18621169109
- Fax:86-21-61259102
- WebSite:https://www.meryer.com/cn/index/
- Company Name:3B Pharmachem (Wuhan) International Co.,Ltd.
- Tel:821-50328103-801 18930552037
- Fax:86-21-50328109
- WebSite:https://www.chemicalbook.com/ShowSupplierProductsList13285/0.htm
- Company Name:Alfa Aesar
- Tel:400-6106006
- Fax:021-67582001/03/05
- WebSite:http://chemicals.thermofisher.cn