Home > 1-Chloro-3-isocyanato-benzene > 1-Chloro-3-isocyanato-benzene(2909-38-8)
1-Chloro-3-isocyanato-benzene(2909-38-8)
Supplier Product Identification
Physical and Chemical Properties
First Aid Measures
Handling and Storage
Hazards Identification
Exposure Controls/Personal Protection
Fire Fighting Measures
Accidental Release Measures
Stability and Reactivity
Transport Information
Product Identification
Product Name
1-Chloro-3-isocyanato-benzene
1-Chloro-3-isocyanato-benzene
Synonyms
3-Chloroisocyanatobenzene
Benzene, 1-chloro-3-isocyanato-
Isocyanic acid, m-chlorophenyl ester
m-Chlorophenyl isocyanate
3-Chloroisocyanatobenzene
Benzene, 1-chloro-3-isocyanato-
Isocyanic acid, m-chlorophenyl ester
m-Chlorophenyl isocyanate
CAS
2909-38-8
2909-38-8
Formula
C7H4ClNO
C7H4ClNO
Molecular Weight
153.57
153.57
EINECS
220-822-5
220-822-5
RTECS
NQ8560000
NQ8560000
RTECS Class
Other
Other
Beilstein/Gmelin
742445
742445
Beilstein Reference
4-12-00-01156
4-12-00-01156
Physical and Chemical Properties
Appearance
Colorless liquid with an irritating odor.
Colorless liquid with an irritating odor.
Solubility in water
Insoluble
Insoluble
Melting Point
-4.4
-4.4
Boiling Point
202
202
Vapor Pressure
0.3 (25 C)
0.3 (25 C)
Density
1.260 g/cm3 (20 C)
1.260 g/cm3 (20 C)
Partition Coefficient
3.3
3.3
Heat Of Vaporization
43.9 kJ/mol
43.9 kJ/mol
Vapor Density
5.3
5.3
Refractive Index
1.5578 (20 C)
1.5578 (20 C)
First Aid Measures
Ingestion
If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation
Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Skin
Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Remove contaminated clothing and shoes.
Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Remove contaminated clothing and shoes.
Eyes
Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Do NOT allow victim to rub or keep eyes closed.
Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Do NOT allow victim to rub or keep eyes closed.
Handling and Storage
Storage
Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a cool, dry place. Keep container closed when not in use. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a cool, dry place. Keep container closed when not in use. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
Handling
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use only in a well ventilated area. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Avoid contact with heat, sparks and flame. Avoid ingestion and inhalation. Wash clothing before reuse. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use only in a well ventilated area. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Avoid contact with heat, sparks and flame. Avoid ingestion and inhalation. Wash clothing before reuse. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Hazards Identification
Inhalation
Causes respiratory tract irritation. Aspiration may lead to pulmonary edema. Can produce delayed pulmonary edema. Inhalation at high concentrations may cause CNS depression and asphixiation.
Causes respiratory tract irritation. Aspiration may lead to pulmonary edema. Can produce delayed pulmonary edema. Inhalation at high concentrations may cause CNS depression and asphixiation.
Skin
Causes skin irritation. May cause irritation and dermatitis. May cause cyanosis of the extremities.
Causes skin irritation. May cause irritation and dermatitis. May cause cyanosis of the extremities.
Eyes
Causes eye irritation. Lachrymator. May cause chemical conjunctivitis and corneal damage. May cause chemical conjunctivitis.
Causes eye irritation. Lachrymator. May cause chemical conjunctivitis and corneal damage. May cause chemical conjunctivitis.
Ingestion
May cause gastrointestinal irritation with nausea, vomiting and diarrhea.
May cause gastrointestinal irritation with nausea, vomiting and diarrhea.
Hazards
Vapors form explosive mixtures with air: indoors, outdoors, and sewers explosion hazards. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapors may travel to source of ignition and flash back. Substance will react with water (some violently) releasing flammable, toxic or corrosive gases and runoff.
Vapors form explosive mixtures with air: indoors, outdoors, and sewers explosion hazards. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapors may travel to source of ignition and flash back. Substance will react with water (some violently) releasing flammable, toxic or corrosive gases and runoff.
EC Risk Phrase
R 26 36/37/38 42
R 26 36/37/38 42
EC Safety Phrase
S 23 26 36/37/39 45
S 23 26 36/37/39 45
UN (DOT)
2206
2206
Exposure Controls/Personal Protection
Personal Protection
Eyes: Wear chemical goggles. Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to minimize contact with skin. Wear appropriate protective clothing to prevent skin exposure.
Eyes: Wear chemical goggles. Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to minimize contact with skin. Wear appropriate protective clothing to prevent skin exposure.
Respirators
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use. Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use. Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
Exposure Effects
Effects may be delayed.
Effects may be delayed.
Poison Class
2
2
Fire Fighting Measures
Flash Point
86
86
Fire Fighting
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. Combustible Liquid. Extinguishing media: Use water spray to cool fire-exposed containers. Use agent most appropriate to extinguish fire. In case of fire, use carbon dioxide or dry chemical.
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. Combustible Liquid. Extinguishing media: Use water spray to cool fire-exposed containers. Use agent most appropriate to extinguish fire. In case of fire, use carbon dioxide or dry chemical.
Fire Potential
HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames.
HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames.
Accidental Release Measures
Small spills/leaks
Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Clean up spills immediately, using the appropriate protective equipment. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation.
Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Clean up spills immediately, using the appropriate protective equipment. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation.
Stability and Reactivity
Stability
Stable under normal temperatures and pressures. Stable at room temperature in closed containers under normal storage and handling conditions.
Stable under normal temperatures and pressures. Stable at room temperature in closed containers under normal storage and handling conditions.
Incompatibilities
Strong oxidizing agents, alcohols, amines, strong bases, acids, heat.
Strong oxidizing agents, alcohols, amines, strong bases, acids, heat.
Decomposition
Hydrogen chloride, hydrogen cyanide, carbon monoxide, oxides of nitrogen, irritating and toxic fumes and gases, carbon dioxide.
Hydrogen chloride, hydrogen cyanide, carbon monoxide, oxides of nitrogen, irritating and toxic fumes and gases, carbon dioxide.
Combustion Products
Fire will produce irritating, corrosive and/or toxic gases.
Fire will produce irritating, corrosive and/or toxic gases.
Transport Information
UN Number
2206
2206
Hazard Class
6.1
6.1
Packing Group
II; III
II; III
Contact
More
- Company Name:Henan Evonik Biotechnology Co. LTD
- Tel: 17837010661
- Fax:
- WebSite:http://hnyingchuang.com/
- Company Name:J & K SCIENTIFIC LTD.
- Tel:010-82848833 400-666-7788
- Fax:86-10-82849933
- WebSite:http://www.jkchemical.com
- Company Name:Meryer (Shanghai) Chemical Technology Co., Ltd.
- Tel:021-61259108 18621169109
- Fax:86-21-61259102
- WebSite:https://www.meryer.com/cn/index/
- Company Name:3B Pharmachem (Wuhan) International Co.,Ltd.
- Tel:821-50328103-801 18930552037
- Fax:86-21-50328109
- WebSite:https://www.chemicalbook.com/ShowSupplierProductsList13285/0.htm
- Company Name:Alfa Aesar
- Tel:400-6106006
- Fax:021-67582001/03/05
- WebSite:http://chemicals.thermofisher.cn