Supplier Product Identification Physical and Chemical Properties First Aid Measures Handling and Storage Hazards Identification Exposure Controls/Personal Protection Fire Fighting Measures Accidental Release Measures Stability and Reactivity Transport Information
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1,4-Benzodioxan-6-amine(22013-33-8)

Supplier Product Identification Physical and Chemical Properties First Aid Measures Handling and Storage Hazards Identification Exposure Controls/Personal Protection Fire Fighting Measures Accidental Release Measures Stability and Reactivity Transport Information

Product Identification

Product Name
1,4-Benzodioxan-6-amine
Synonyms
1,4-Benzodioxin-6-amine, 2,3-dihydro-
2,3-Dihydro-1,4-benzodioxin-7-amine
3,4-Ethylenedioxyaniline
CAS
22013-33-8
Formula
C8H9NO2
Molecular Weight
151.16999999999999
EINECS
244-718-4
Beilstein/Gmelin
6447
Beilstein Reference
4-19-00-04062
EC Class
irritant

Physical and Chemical Properties

Appearance
Black liquid.
Solubility in water
Soluble
Melting Point
29-31
Boiling Point
294
Vapor Pressure
0.002 (25 C)
Density
1.23 g/cm3
Partition Coefficient
.48
Heat Of Vaporization
53.3 kJ/mol
Refractive Index
1.60 (20 C)

First Aid Measures

Ingestion
Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation
Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Skin
Get medical aid. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.
Eyes
Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.

Handling and Storage

Storage
Store in a cool, dry place. Do not store in direct sunlight. Store in a tightly closed container.
Handling
Wash thoroughly after handling. Wash hands before eating. Use only in a well ventilated area. Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Avoid ingestion and inhalation.

Hazards Identification

Ingestion
Causes gastrointestinal irritation with nausea, vomiting and diarrhea.
Inhalation
Dust is irritating to the respiratory tract.
Skin
Causes skin irritation.
Eyes
Causes eye irritation.
Hazards
When heated, vapors may form explosive mixtures with air: indoors, outdoors, and sewers explosion hazards.
EC Risk Phrase
R 20/21/22
EC Safety Phrase
S 28 36/37
UN (DOT)
2810

Exposure Controls/Personal Protection

Personal Protection
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators
Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.

Fire Fighting Measures

Flash Point
143
Fire Fighting
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing media: For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam.
Fire Potential
Combustible material: may burn but does not ignite readily.

Accidental Release Measures

Small spills/leaks
Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, using the appropriate protective equipment.

Stability and Reactivity

Disposal Code
5
Stability
Stable under normal temperatures and pressures.
Incompatibilities
Strong oxidizing agents and acids
Decomposition
Nitrogen oxides, carbon monoxide, carbon dioxide, ammonia.
Combustion Products
Fire may produce irritating, corrosive and/or toxic gases.

Transport Information

UN Number
2810
Hazard Class
6.1
Packing Group
I; II; III
HS Code
2932 99 95
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