Supplier Product Identification Physical and Chemical Properties First Aid Measures Handling and Storage Hazards Identification Exposure Controls/Personal Protection Fire Fighting Measures Accidental Release Measures Stability and Reactivity Transport Information
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Bis(2,4-pentanediono)nickel(3264-82-2)

Supplier Product Identification Physical and Chemical Properties First Aid Measures Handling and Storage Hazards Identification Exposure Controls/Personal Protection Fire Fighting Measures Accidental Release Measures Stability and Reactivity Transport Information

Product Identification

Product Name
Bis(2,4-pentanediono)nickel
Synonyms
Bis(2,4-pentanedionato)nickel
Bis(acetylacetonate)nickel
Nickel bis(2,4-pentanedionate)
Nickel bis(acetylacetonate)
Nickel, bis(2,4-pentanedionato-kO,kO')-, (SP-4-1)-
Nickelous acetylacetonate
CAS
3264-82-2
Formula
C10H14NiO4
Molecular Weight
256.91000000000003
EINECS
221-875-7
RTECS
SA2100000
RTECS Class
Other
Merck
12,6584
Beilstein/Gmelin
4157970
EC Class
harmful, sensitizing

Physical and Chemical Properties

Appearance
Light green solid.
Solubility in water
4.8 g/L (20 C)
Boiling Point
220
Vapor Pressure
20 (110 C)
Density
1.455 g/cm3 (20 C)
Usage
This material is used as a catalyst.

First Aid Measures

Ingestion
Never give anything by mouth to an unconscious person. Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation
Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Skin
Get medical aid immediately. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.
Eyes
Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.

Handling and Storage

Storage
Store in a cool, dry, well-ventilated area away from incompatible substances. Keep containers tightly closed.
Handling
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use only in a well ventilated area. Do not get in eyes, on skin, or on clothing. Do not ingest or inhale. Keep from contact with moist air and steam. Do not breathe dust.

Hazards Identification

Inhalation
May cause allergic respiratory reaction. Inhalation of high concentrations may cause coughing and shortness of breath. Can produce delayed pulmonary edema.
Skin
May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material. May cause severe dermatitis and urticaria(hives).
Eyes
May cause eye irritation.
Ingestion
May cause irritation of the digestive tract. May cause central nervous system effects.
EC Risk Phrase
R 45 20/21/22 43
EC Safety Phrase
S 53 45
UN (DOT)
3282

Exposure Controls/Personal Protection

Personal Protection
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use.
Exposure Effects
May cause cancer according to animal studies. Prolonged or repeated exposure may cause lung irritation, chest pain, and pulmonary edema. May cause reproductive effects.
Exposure limit(s)
0.1 mg/m3 TLV
Poison Class
2

Fire Fighting Measures

Fire Fighting
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. To extinguish fire use water spray, dry chemical, carbon dioxide, or chemical foam.

Accidental Release Measures

Small spills/leaks
Sweep up, then place into a suitable container for disposal. Provide ventilation.

Stability and Reactivity

Disposal Code
15
Stability
Stable under normal temperatures and pressures.
Incompatibilities
Strong oxidizing agents, moisture.
Decomposition
Carbon monoxide, carbon dioxide, 2,4-pentanedione, nickel oxide, acrid smoke and fumes, nickel.

Transport Information

UN Number
3282
HS Code
2942 00 00
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